水混合溶剂在生物质液化中的应用研究进展

doi:10.3969/j.issn.1673-5854.2023.06.007

Abstract

Abstract:

Solvent liquefaction was an effective process which could utilize biomass raw materials efficiently and comprehensively. Compared with water as a single solvent, the mixed solvent system could reduce the reaction temperature and pressure, improve the conversion of biomass, reduce the oxygen content in bio-oil, and increase the yield of the target product. This paper reviewed the common water mixed solvent systems in recent years, including the role of alcohol-water cosolvent, polar aprotic solvent-water system and ionic liquid-water system in the degradation process of lignocellulosic biomass, especially the application characteristics of ethanol-water cosolvent, tetrahydrofuran (THF)-water cosolvent and γ-valerolactone (GVL)-water cosolvent in biomass liquefaction. This paper also gave the shortage and suggestions of these solvents in biomass liquefaction field. Finally, based on the consideration of the economic value, recovery and safety performance of the solvent itself, it is pointed out that the development of low-cost, environment-friendly and sustainable liquefying solvents would be the key development direction in the future.

Key words: biomass, liquefaction, mixed solvent system, bio-oil

CLC Number:

TQ35

Yan MA, Hongxiao WANG, Guodong FENG, Ziyang WU, Weihong TAN. A Review on Recent Advances in Biomass Liquefaction in Water Mixed Solvent Systems[J]. Biomass Chemical Engineering, 2023, 57(6): 47-55.

Figures/Tables 4

Table 1

Fig.1

Fig.2

Fig.3

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原料 material	温度/℃ temp.	时间/min time	V(EtOH): V(H₂O)	催化剂 catalyst	产油率/% bio-oil yield	主要成分 main components	热值/(MJ·kg^-1) heat value	文献 ref.
小球藻 microalgae	280	120	5:2	无no	57.3	酮类、酯类、含氮杂环化合物和烃类ketones, esters, nitrogenous heterocyclic and hydrocarbons	32.2	^[9]
稻壳 rice husk	260	20	5:5	无no	21.2	酚类, 长链烷烃, 酯类、有机酸和酮phenols, long chain alkanes, esters, organic acids and ketones	27.0	^[12]
互米花 spartina alterniflora	340	—	5:5	无no	44.2	酚类和酯类 aromatics, esters	30.8	^[13]
玉米秸秆 corn stover	340	60	1:1	NiMoS/Al₂O₃	29.57	酚类、酯类和酮类 aromatics, esters, ketones	33.8	^[14]
低脂微藻 microalgae	300	45	5:5	无no	59.5	酯类ketones	33.9	^[15]
稻壳 rice husk	260	20	5:5	无no	21.2	酚类、长链烷烃、糖类、酮类和酯类aromatics, long-chain alkanes, carbohydrates, ketones and esters	27.6	^[16]
蛋白核小球藻 chlorella pyrenoidosa	300	60	3:2	无no	—	碳氢化合物, 酯类 hydrocarbons, esters	—	^[17]
甘蔗渣与聚乙烯 sugarcane bagasse and polyethylene	280	90	2:3	无no	39.0	酯、糠醛及其衍生物esters, furfural and their derivatives	37.0	^[18]
污泥 sewage sludge	220	30	3:4	Na₂CO₃	37.5	酯类, 机酸和含氮化合物esters, organic acids and nitrogenous compounds	—	^[19]
玉米秸秆 corn stalk	320	180	1:1	磺化碳, 固体酸sulfonated carbon, solid acid	52.1	—	—	^[20]

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A Review on Recent Advances in Biomass Liquefaction in Water Mixed Solvent Systems

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