竹节硬碳的制备及储钠性能研究

doi:10.3969/j.issn.1673-5854.2023.06.001

Abstract

Abstract:

Bamboo-based hard carbon materials for sodium ion battery anodes were prepared by a two-step method of pre-carbonization combined with high-temperature reforming using bamboo as raw material. The influence of reforming temperature on the structure of hard carbon, and the structure-activity relationship between structure and sodium storage performance were explored. The research results showed that the high refining temperature could shrink the pores to form a closed pore structure and reduce the specific surface area, as well as led to a decrease in the layer spacing. When the refining temperature was 1 400 ℃, the specific surface area of the sample BHC-1400 was 9.2 m²/g, and the layer spacing was 0.375 nm. Its rich closed-pore structure and reasonable interlayer spacing were beneficial to the improvement of sodium storage capacity. BHC-1400 exhibited a reversible sodium storage capacity up to 364.3 mAh/g at a current density of 50 mA/g and an initial Coulomb efficiency of 81.2% as an anode material for sodium-ion batteries. Capacity retention rate keeps at 85% after 5 000 cycles of charging and discharging.

Key words: biomass, hard carbon, sodium ion battery, high temperature refining

CLC Number:

TQ35
TQ424

Gaoyue ZHANG, Ao WANG, Hao YING, Wei XU, Hao SUN, Kang SUN, Jianchun JIANG. Preparation and Sodium Storage Properties of Bamboo Hard Carbon[J]. Biomass Chemical Engineering, 2023, 57(6): 1-7.

Figures/Tables 7

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References 19

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样品 sample	S_BET/(m²·g^-1)	S_mic/(m²·g^-1)	S_mes/(m²·g^-1)	V_total/(m³·g^-1)	层间距(d₀₀₂)/nm layer spacing	I_D/I_G
BHC-1000	40.8	32.4	8.4	0.030 3	0.381	1.54
BHC-1200	22.9	14.6	8.2	0.022 3	0.379	1.48
BHC-1400	9.2	3.2	6.1	0.014 2	0.375	1.45
BHC-1600	4.3	2.5	1.7	0.009 1	0.366	1.29

样品 sample	质量比容量/(mAh·g^-1) gravimetric capacity	首次库仑效率/% initial Coulomb efficiency	斜坡容量/(mAh·g^-1) slope capacity	平台容量/(mAh·g^-1) platform capacity
BHC-1000	230.0	49.4	168.1	61.9
BHC-1200	311.1	68.5	161.9	149.2
BHC-1400	364.3	81.2	104.2	260.1
BHC-1600	324.8	72.7	84.5	240.3

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Preparation and Sodium Storage Properties of Bamboo Hard Carbon

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