生物质多孔碳材料的水热合成及应用研究进展

doi:10.3969/j.issn.1673-5854.2023.02.010

Abstract

Abstract:

Biomass had negative carbon properties and met the requirements of green development as a typical renewable energy. Under relatively mild conditions, hydrothermal carbonization was the process of converting biomass into various functional carbon materials. This paper discussed recent advances of biomass-based porous carbon materials by the hydrothermal transformation from biomass, such as monosaccharides(glucose, fructose, and xylose), lignocellulosic fibers(cellulose, hemicellulose, and lignin) and chitosan. The effects of temperature, reaction time and raw material concentration on its structure and properties were mainly discussed, as well as its applications in gas adsorption, dye adsorption and heavy metal ion adsorption. The authors proposed future research directions for the hydrothermal synthesis of high performance and environmentally friendly porous carbon materials from biomass.

Key words: hydrothermal carbonization, biomass, porous carbon materials, adsorption

CLC Number:

TQ35
TQ424

Mengjie CAI, Jun RAO, Yajie HU, Dan SUN, Feng PENG. Research Progress on Hydrothermal Synthesisand and Application of Biomass Porous Carbon Materials[J]. Biomass Chemical Engineering, 2023, 57(2): 79-88.

Figures/Tables 8

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References 69

1	AHMED K T , KIM H J , GUPTA A , et al. Synthesis and characterization of carbon microspheres from rubber wood by hydrothermal carbonization[J]. Journal of Chemical Technology and Biotechnology, 2018, 94 (5): 1374- 1383.
2	LU X , JIANG C , HU Y , et al. Preparation of hierarchically porous carbon spheres by hydrothermal carbonization process for high-performance electrochemical capacitors[J]. Journal of Applied Electrochemistry, 2018, 48 (2): 233- 241. doi: 10.1007/s10800-018-1146-x
3	SHEN F , WANG Y , LI L , et al. Porous carbonaceous materials from hydrothermal carbonization and KOH activation of corn stover for highly efficient CO₂ capture[J]. Chemical Engineering Communications, 2018, 205 (4): 423- 431. doi: 10.1080/00986445.2017.1367671
4	WANG Q , LI H , CHEN L Q , et al. Monodispersed hard carbon spherules with uniform nanopores[J]. Carbon, 2001, 39, 2211- 2214. doi: 10.1016/S0008-6223(01)00040-9
5	JOO J B , KIM Y J , KIM W , et al. Simple synthesis of graphitic porous carbon by hydrothermal method for use as a catalyst support in methanol electro-oxidation[J]. Catalysis Communications, 2008, 10 (3): 267- 271. doi: 10.1016/j.catcom.2008.08.031
6	WANG Y , YANG R , LI M , et al. Hydrothermal preparation of highly porous carbon spheres from hemp(Cannabis sativa L.) stem hemicellulose for use in energy-related applications[J]. Industrial Crops and Products, 2015, 65, 216- 226. doi: 10.1016/j.indcrop.2014.12.008
7	LI K , LIU S , SHU T , et al. Fabrication of carbon microspheres with controllable porous structure by using waste Camellia oleifera shells[J]. Materials Chemistry and Physics, 2016, 181, 518- 528. doi: 10.1016/j.matchemphys.2016.06.089
8	HONG S M, YOON H J, CHOI Y, et al. Solving two environmental problems simultaneously: Scalable production of carbon microsheets from structured packing peanuts with tailored microporosity for efficient CO₂ capture[J/OL]. Chemical Engineering Journal, 2020, 379: 122219[2021-12-10]. https://doi.org/10.1016/j.cej.2019.122219.
9	SUN R Q , SUN L B , CHUN Y , et al. Catalytic performance of porous carbons obtained by chemical activation[J]. Carbon, 2008, 46 (13): 1757- 1764. doi: 10.1016/j.carbon.2008.07.029
10	LIN H, LIU Y, CHANG Z, et al. A new method of synthesizing hemicellulose-derived porous activated carbon for high-performance supercapacitors[J/OL]. Microporous and Mesoporous Materials, 2020, 292: 109707[2021-12-10]. https://doi.org/10.1016/j.micromeso.2019.109707.
11	WANG Z , SUN L , XU F , et al. Nitrogen-doped porous carbons with high performance for hydrogen storage[J]. International Journal of Hydrogen Energy, 2016, 41 (20): 8489- 8497. doi: 10.1016/j.ijhydene.2016.03.023
12	王嫚. 添加表面活性剂制备浒苔活性炭及对Ni²⁺和环丙沙星吸附特性的研究[D]. 济南: 山东大学, 2014.
13	LIANG H X, SUN R R, SONG B, et al. Preparation of nitrogen-doped porous carbon material by a hydrothermal-activation two-step method and its high-efficiency adsorption of Cr(Ⅵ)[J/OL]. Journal of Hazardous Materials, 2020, 387: 121987[2021-12-10]. https://doi.org/10.1016/j.jhazmat.2019.121987.
14	SHI J , YAN N , CUI H , et al. Nitrogen doped hierarchically porous carbon derived from glucosamine hydrochloride for CO₂ adsorption[J]. Journal of CO₂ Utilization, 2017, 21, 444- 449. doi: 10.1016/j.jcou.2017.08.010
15	LIU S , CAI Y , ZHAO X , et al. Sulfur-doped nanoporous carbon spheres with ultrahigh specific surface area and high electrochemical activity for supercapacitor[J]. Journal of Power Sources, 2017, 360, 373- 382. doi: 10.1016/j.jpowsour.2017.06.029
16	LAURA R , MARCO Y , GARCÍA-BORDEJÉ E . Bio-sourced mesoporous carbon doped with heteroatoms(N, S) synthesised using one-step hydrothermal process for water remediation[J]. Microporous and Mesoporous Materials, 2016, 222, 55- 62. doi: 10.1016/j.micromeso.2015.10.008
17	ZHAO X , WANG S , WU Q . Nitrogen and phosphorus dual-doped hierarchical porous carbon with excellent supercapacitance performance[J]. Electrochimica Acta, 2017, 247, 1140- 1146. doi: 10.1016/j.electacta.2017.07.077
18	YI Y , WANG P , FAN G , et al. Hierarchically porous carbon microsphere doped with phosphorus as a high conductive electrocatalyst for oxidase-like sensors and supercapacitors[J]. ACS Sustainable Chemistry & Engineering, 2020, 8 (26): 9937- 9946.
19	YU H , SHANG L , BIAN T , et al. Nitrogen-doped porous carbon nanosheets templated from g-C₃N₄ as metal-free electrocatalysts for efficient oxygen reduction reaction[J]. Advanced Materials, 2016, 28 (25): 5080- 5086. doi: 10.1002/adma.201600398
20	LIU X , LI L , ZHOU W , et al. High-performance electrocatalysts for oxygen reduction based on nitrogen-doped porous carbon from hydrothermal treatment of glucose and dicyandiamide[J]. ChemElectroChem, 2015, 2 (6): 803- 810. doi: 10.1002/celc.201500002
21	HEKMAT F , HOSSEINI H , SHAHROKHIAN S , et al. Hybrid energy storage device from binder-free zinc-cobalt sulfide decorated biomass-derived carbon microspheres and pyrolyzed polyaniline nanotube-iron oxide[J]. Energy Storage Materials, 2020, 25, 621- 635. doi: 10.1016/j.ensm.2019.09.022
22	NA W , JUN J , PARK J W , et al. Highly porous carbon nanofibers co-doped with fluorine and nitrogen for outstanding supercapacitor performance[J]. Journal of Materials Chemistry A, 2017, 5 (33): 17379- 17387. doi: 10.1039/C7TA04406B
23	DEMIR M , TESSEMA T D , FARGHALY A A , et al. Lignin-derived heteroatom-doped porous carbons for supercapacitor and CO₂ capture applications[J]. International Journal of Energy Research, 2018, 42 (8): 2686- 2700. doi: 10.1002/er.4058
24	罗路, 罗凌聪, 邓剑平, 等. 硼/氮共掺杂刀豆壳基多孔炭材料的制备及其电化学性能研究[J]. 林产化学与工业, 2021, 41 (6): 43- 50.
25	YANG G , SONG S , LI J , et al. Preparation and CO₂ adsorption properties of porous carbon by hydrothermal carbonization of tree leaves[J]. Journal of Materials Science & Technology, 2019, 35 (5): 875- 884.
26	GUANGZHI Y , JINYU Y , YUHUA Y , et al. Preparation and CO₂ adsorption properties of porous carbon from camphor leaves by hydrothermal carbonization and sequential potassium hydroxide activation[J]. RSC Advances, 2017, 7 (7): 4152- 4160. doi: 10.1039/C6RA25303B
27	FALCO C , MARCO-LOZAR J P , SALINAS-TORRES D , et al. Tailoring the porosity of chemically activated hydrothermal carbons: Influence of the precursor and hydrothermal carbonization temperature[J]. Carbon, 2013, 62, 346- 355. doi: 10.1016/j.carbon.2013.06.017
28	TONG X , CHEN Z , ZHUO H , et al. Tailoring the physicochemical properties of chitosan-derived N-doped carbon by controlling hydrothermal carbonization time for high-performance supercapacitor application[J]. Carbohydratr Polymers, 2019, 207, 764- 774. doi: 10.1016/j.carbpol.2018.12.048
29	LI M , LI W , LIU S . Hydrothermal synthesis, characterization, and KOH activation of carbon spheres from glucose[J]. Carbohydrate Research, 2011, 346 (8): 999- 1004. doi: 10.1016/j.carres.2011.03.020
30	ZHAO C H , PENG B J , HU Z B . Hierarchical porous carbon/selenium composite derived from hydrothermal treated peanut shell as high-performance lithium ion battery cathode[J]. Chemical Papers, 2019, 74 (4): 1289- 1299.
31	DE S , BALU A M , VAN DER WAAL J C , et al. Biomass-derived porous carbon materials: Synthesis and catalytic applications[J]. ChemCatChem, 2015, 7 (11): 1608- 1629. doi: 10.1002/cctc.201500081
32	李鑫, 王秋芬, 田会芳, 等. 活化剂对大豆壳制备的多孔碳材料储锂性能的影响[J]. 复合材料学报, 2021, 39, 1- 10.
33	李敏. 炭微球的水热制备、表征及活化[D]. 哈尔滨: 东北林业大学, 2011.
34	LIU G , LIU Y , ZHANG X , et al. Characterization and catalytic performance of porous carbon prepared using in situ-formed aluminophosphate framework as template[J]. Journal of Colloid and Interface Science, 2010, 342 (2): 467- 473. doi: 10.1016/j.jcis.2009.10.036
35	XIAO K, LIU H, LI Y, et al. Excellent performance of porous carbon from urea-assisted hydrochar of orange peel for toluene and iodine adsorption[J/OL]. Chemical Engineering Journal, 2020, 382: 122997[2021-12-10]. https://doi.org/10.1016/j.cej.2019.122997.
36	LIU Z , ZHANG F S . Removal of copper(Ⅱ) and phenol from aqueous solution using porous carbons derived from hydrothermal chars[J]. Desalination, 2011, 267 (1): 101- 106. doi: 10.1016/j.desal.2010.09.013
37	WANG Y, JIANG H, YE S, et al. N-doped porous carbon derived from walnut shells with enhanced electrochemical performance for supercapacitor[J/OL]. Functional Materials Letters, 2019, 12(3): 1950042[2021-12-10]. https://doi.org/10.1142/S1793604719500425.
38	TITIRICI M M , ANTONIETTI M , BACCILE N . Hydrothermal carbon from biomass: A comparison of the local structure from poly- to monosaccharides and pentoses/hexoses[J]. Green Chemistry, 2008, 10 (11): 1204- 1212. doi: 10.1039/b807009a
39	NIU H , MIN Q , TAO Z , et al. One-pot facile synthesis and optical properties of porous La₂O₂CO₃ hollow microspheres[J]. Journal of Alloys and Compounds, 2011, 509 (3): 744- 747. doi: 10.1016/j.jallcom.2010.09.056
40	LIANG H , SONG B , PENG P , et al. Preparation of three-dimensional honeycomb carbon materials and their adsorption of Cr(Ⅵ)[J]. Chemical Engineering Journal, 2019, 367, 9- 16. doi: 10.1016/j.cej.2019.02.121
41	RAO L , MA R , LIU S , et al. Nitrogen enriched porous carbons from D-glucose with excellent CO₂ capture performance[J]. Chemical Engineering Journal, 2019, 362, 794- 801. doi: 10.1016/j.cej.2019.01.093
42	YAO C H , SHIN Y , WANG L Q , et al. Hydrothermal dehydration of aqueous fructose solutions in a closed system[J]. American Chemical Society, 2007, 111, 15141- 15145.
43	ZHANG M , YANG H , LIU Y , et al. Hydrophobic precipitation of carbonaceous spheres from fructose by a hydrothermal process[J]. Carbon, 2012, 50 (6): 2155- 2161. doi: 10.1016/j.carbon.2012.01.024
44	CHENG Y , YANG M , FANG C , et al. Controllable morphologies of carbon microspheres via green hydrothermal method using fructose and xylose[J]. Chemistry Letters, 2017, 46 (9): 1400- 1402. doi: 10.1246/cl.170592
45	SU J , FANG C , YANG M , et al. A controllable soft-templating approach to synthesize mesoporous carbon microspheres derived from D-xylose via hydrothermal method[J]. Journal of Materials Science & Technology, 2020, 38, 183- 188.
46	MASSELTER S M , ZEMANN A J , BOBLETER O . Analysis of lignin degradation products by capillary electrophoresis[J]. Chromatographia, 1995, 40 (1): 51- 57.
47	BOBLETER O . Hydrothermal degradation of polymers derived from plants[J]. Progress in Polymer Science, 1994, 19 (5): 797- 841. doi: 10.1016/0079-6700(94)90033-7
48	DENG J , XIONG T , WANG H , et al. Effects of cellulose, hemicellulose, and lignin on the structure and morphology of porous carbons[J]. ACS Sustainable Chemistry & Engineering, 2016, 4 (7): 3750- 3756.
49	SEVILLA M , FUERTES A B . The production of carbon materials by hydrothermal carbonization of cellulose[J]. Carbon, 2009, 47 (9): 2281- 1189. doi: 10.1016/j.carbon.2009.04.026
50	FALCO C , BACCILE N , TITIRICI M M . Morphological and structural differences between glucose, cellulose and lignocellulosic biomass derived hydrothermal carbons[J]. Green Chemistry, 2011, 13 (11): 3273- 3281. doi: 10.1039/c1gc15742f
51	LU X , PELLECHIA P J , FLORA J R , et al. Influence of reaction time and temperature on product formation and characteristics associated with the hydrothermal carbonization of cellulose[J]. Bioresour Technology, 2013, 138, 180- 190. doi: 10.1016/j.biortech.2013.03.163
52	GARCÍA-BORDEJÉ E , PIRES E , FRAILE J M . Parametric study of the hydrothermal carbonization of cellulose and effect of acidic conditions[J]. Carbon, 2017, 123, 421- 432. doi: 10.1016/j.carbon.2017.07.085
53	牛文娟, 黄金芝, 钟菲, 等. 不同水热条件对秸秆微波水热碳化产物组成和结构特性影响[J]. 农业工程学报, 2019, 35 (10): 205- 213. doi: 10.11975/j.issn.1002-6819.2019.10.026
54	WEI Y, CHEN W, LIU C, et al. Facial Synthesis of adsorbent from hemicelluloses for Cr(Ⅵ) adsorption[J/OL]. Molecules, 2021, 26(5): 1443[2021-12-10]. https://doi.org/10.3390/molecules26051443.
55	WANG Y Y , CAO X F , SUN S N , et al. Carbon microspheres prepared from the hemicelluloses-rich pre-hydrolysis liquor for contaminant removal[J]. Carbohydrate Polymers, 2019, 213, 296- 303. doi: 10.1016/j.carbpol.2019.02.029
56	FALCO C , SIEBEN J M , BRUN N , et al. Hydrothermal carbons from hemicellulose-derived aqueous hydrolysis products as electrode materials for supercapacitors[J]. ChemSusChem, 2013, 6 (2): 374- 382. doi: 10.1002/cssc.201200817
57	LI H , SHI F , AN Q , et al. Three-dimensional hierarchical porous carbon derived from lignin for supercapacitors: Insight into the hydrothermal carbonization and activation[J]. International Journal of Biological Macromolecules, 2020, 166, 923- 933.
58	WU Y, CAO J P, ZHAO X Y, et al. High-performance electrode material for electric double-layer capacitor based on hydrothermal pre-treatment of lignin by ZnCl₂[J/OL]. Applied Surface Science, 2020, 508: 144536[2021-12-10]. https://doi.org/10.1016/j.apsusc.2019.144536.
59	GAO Y , ZHENG S , FU H , et al. Three-dimensional nitrogen doped hierarchically porous carbon aerogels with ultrahigh specific surface area for high-performance supercapacitors and flexible micro-supercapacitors[J]. Carbon, 2020, 168, 701- 709. doi: 10.1016/j.carbon.2020.06.063
60	WANG J , CHEN S , XU J Y , et al. High-surface-area porous carbons produced by the mild KOH activation of a chitosan hydrochar and their CO₂ capture[J]. New Carbon Materials, 2021, 36 (6): 1081- 1093. doi: 10.1016/S1872-5805(21)60074-4
61	姚建锋, 马爱军, 段博涛, 等. 基于壳聚糖多孔碳的制备及电容性能研究[J]. 化学与生物工程, 2020, 37 (9): 17- 22.17-22, 58
62	SINGH G , LAKHI K S , SIL S , et al. Biomass derived porous carbon for CO₂ capture[J]. Carbon, 2019, 148, 164- 186. doi: 10.1016/j.carbon.2019.03.050
63	PARSHETTI G K , CHOWDHURY S , BALASUBRAMANIAN R . Biomass derived low-cost microporous adsorbents for efficient CO₂ capture[J]. Fuel, 2015, 148, 246- 254. doi: 10.1016/j.fuel.2015.01.032
64	SHI J, CUI H, XU J, et al. Fabrication of nitrogen doped and hierarchically porous carbon flowers for CO₂ adsorption[J/OL]. Journal of CO₂ Utilization, 2021, 51: 101617[2021-12-10]. https://doi.org/10.3390/molecules26051443.
65	朱晓, 张立强, 张梦泽, 等. 水热法制备氮掺杂多孔炭及其在气体吸附/电化学储能中的应用[J]. 燃烧科学与技术, 2020, 26 (5): 413- 422.
66	方慕楠, 宋驰, 罗琦予, 等. 纤维素制备生物炭及其对亚甲基蓝吸附性能的评价[J]. 山东化工, 2017, 46 (22): 163- 165.
67	SANJA K, MILAN K, MAJA P, et al. Hydrothermal synthesized and alkaline activated carbons prepared from glucose and fructose detailed characterization and testing in heavy metals and methylene blue removal[J/OL]. Minerals, 2018, 8(6): 246[2021-12-10]. https://doi.org/10.3390/min8060246.
68	TRAN T H, LE A H, PHAM T H, et al. Adsorption isotherms and kinetic modeling of methylene blue dye onto a carbonaceous hydrochar adsorbent derived from coffee husk waste[J/OL]. Science of the Total Environment, 2020, 725: 138325[2021-12-10]. https://doi.org/10.1016/j.scitotenv.2020.138325.
69	WU Q , LI W , LIU S . Carboxyl-rich carbon microspheres prepared from pentosan with high adsorption capacity for heavy metalions[J]. Materials Research Bulletin, 2014, 60, 516- 523. doi: 10.1016/j.materresbull.2014.09.015

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Research Progress on Hydrothermal Synthesisand and Application of Biomass Porous Carbon Materials

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