环氧植物油脂的制备及应用研究进展

doi:10.3969/j.issn.1673-5854.2014.04.009

生物质化学工程 ›› 2014, Vol. 48 ›› Issue (4): 45-50.doi: 10.3969/j.issn.1673-5854.2014.04.009

环氧植物油脂的制备及应用研究进展

黄旭娟¹, 刘鹤¹, 商士斌^1,2, 齐帆¹

1. 中国林业科学研究院林产化学工业研究所; 生物质化学利用国家工程实验室; 国家林业局林产化学工程重点开放性实验室; 江苏省生物质能源与材料重点实验室, 江苏南京 210042;
2. 中国林业科学研究院林业新技术研究所, 北京 100091

收稿日期:2014-04-29 出版日期:2014-07-30 发布日期:2014-07-29
通讯作者: 商士斌（1964-），男，研究员，博士生导师，从事生物质资源的化学研究与利用；E-mail：shangsb@hotmail.com。 E-mail:shangsb@hotmail.com
作者简介:黄旭娟（1991-），女，江苏常熟人，硕士生；研究方向为松脂化学利用
基金资助:
中央级公益性科研院所基本科研业务费专项资金（CAFINT2012C05）；国家自然科学基金青年基金项目（31200446）；江苏省自然科学基金青年基金项目（BK2012063）

Research Progress on Preparation and Application of Epoxidized Vegetable Oils

HUANG Xu-juan¹, LIU He¹, SHANG Shi-bin^1,2, QI Fan¹

1. Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab. for Biomass Chemical Utilization; Key and Open Lab. of Forest Chemical Engineering, SFA;Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China;
2. Research Institute of Forestry New Technology, CAF, Beijing 100091, China

Received:2014-04-29 Online:2014-07-30 Published:2014-07-29

摘要/Abstract

摘要： 对植物油脂的环氧化方法进行了综述，介绍了液体酸催化、固体酸催化、相转移催化及酶催化等制备环氧植物油脂的方法，并指出了各种方法的优点以及存在的问题。同时对环氧植物油脂在聚氨酯、环氧树脂、润滑剂等高分子领域的重要应用进行了总结，并对环氧植物油脂的发展进行了展望。

关键词: 植物油脂, 环氧化, 聚氨酯, 环氧树脂, 润滑剂

Abstract: Several epoxidation methods of vegetable oil including liquid acid, solid acid, phase transfer catalysis and enzyme as catalyst are reviewed in this paper. The advantages and problems existing in each method were pointed out. Applications of epoxidized vegetable oils in polymer areas, such as in polyurethane, epoxy, and lubricants were summarized and its prospects for future development were also presented.

Key words: vegetable oils, epoxidation, polyurethane, epoxy, lubricants

中图分类号:

TQ35
TQ645

黄旭娟, 刘鹤, 商士斌, 齐帆. 环氧植物油脂的制备及应用研究进展[J]. 生物质化学工程, 2014, 48(4): 45-50.

HUANG Xu-juan, LIU He, SHANG Shi-bin, QI Fan. Research Progress on Preparation and Application of Epoxidized Vegetable Oils[J]. bce, 2014, 48(4): 45-50.

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环氧植物油脂的制备及应用研究进展

Research Progress on Preparation and Application of Epoxidized Vegetable Oils

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