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生物质化学工程 ›› 2018, Vol. 52 ›› Issue (3): 59-64.doi: 10.3969/j.issn.1673-5854.2018.03.010

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萜烯基高分子材料的合成及应用研究进展

郭佳雯1, 陈莉晶1, 王俊1, 徐徐1,2   

  1. 1. 南京林业大学 化学工程学院, 江苏 南京 210037;
    2. 江苏省生物质绿色燃料与化学品重点实验室, 江苏 南京 210037
  • 收稿日期:2017-03-09 出版日期:2018-05-30 发布日期:2018-05-31
  • 通讯作者: 徐徐(1983-),女,副教授,硕士生导师,主要从事天然产物化学利用等方面的研究;E-mail:xuxu200121@163.com。 E-mail:xuxu200121@163.com
  • 作者简介:郭佳雯(1993-),女,江苏泰州人,硕士生,主要从事萜烯高分子合成方面的工作;E-mail:810394059@qq.com
  • 基金资助:
    国家自然科学基金资助项目(31600462)

Synthesis and Application Progress of Terpene-based Polymer Materials

GUO Jiawen1, CHEN Lijing1, WANG Jun1, XU Xu1,2   

  1. 1. College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China;
    2. Jiangsu Key Lab. of Biomass-based Green Fuels and Chemicals, Nanjing 210037, China
  • Received:2017-03-09 Online:2018-05-30 Published:2018-05-31

摘要: 萜类化合物是广泛存在于自然界中的可再生生物质资源,分子结构中含有不饱和碳-碳双键和其他活性官能团,经过加成、氧化、聚合和异构等反应可合成萜烯基高分子材料,广泛应用于表面活性剂、涂料涂膜、黏合剂和复合材料等领域。针对萜烯基环氧树脂、萜烯基环碳酸酯、萜烯基聚氨酯以及其他萜烯基高分子的合成及应用进行了综述,并展望了未来萜烯基高分子材料的合成及应用研究方向。

关键词: 萜烯基环氧树脂, 萜烯基环碳酸酯, 萜烯基聚氨酯, 表面活性剂, 涂料, 复合材料

Abstract: As a renewable biomass resource, terpene compounds are widely found in the nature. Its molecular structure includes unsaturated carbon-carbon double bond and other active functional groups. The terpene-based polymer materials can be synthesized through addition, oxidation, polymerization, isomerism and other reactions. They can be used in the fields of surface active agents, paint coating, adhesives, composites and so on. The synthesis and application of terpene-based epoxy resin, terpenyl-cyclic carbonate, terpene-based polyurethane and other terpene-based polymers are reviewed. Moreover, the prospective direction of terpene-based polymer materials in the future is given as well.

Key words: terpene-based epoxy resin, terpenyl-based cyclic carbonate, terpene-based polyurethane, surface active agents, paint coating, composites

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