生物质基固体材料中生物基含量测定方法的研究进展

doi:10.3969/j.issn.1673-5854.2016.05.010

生物质化学工程 ›› 2016, Vol. 50 ›› Issue (5): 53-59.doi: 10.3969/j.issn.1673-5854.2016.05.010

生物质基固体材料中生物基含量测定方法的研究进展

邓坤明, 王鹏飞, 马艳, 王宏晓, 沈娟章, 谭卫红

中国林业科学研究院林产化学工业研究所;生物质化学利用国家工程实验室;国家林业局林产化学工程重点开放性实验室;江苏省生物质能源与材料重点实验室, 江苏南京 210042

收稿日期:2016-02-29 出版日期:2016-09-30 发布日期:2016-12-03
通讯作者: 谭卫红,副研究员,博士,硕士生导师,研究领域:生物质材料的研究;E-mail:tanweihong71@163.com。 E-mail:tanweihong71@163.com
作者简介:邓坤明(1988-),男,江西南康人,硕士生,从事生物质材料研究与开发;E-mail:writeread@126.com
基金资助:
公益性行业科研专项（2012104006-5）；江苏省大型科学仪器设备共享服务平台分析测试技术及方法研究课题（无编号）

Research Progress of Determination Method of Bio-based Content in Bio-based Solid Material

DENG Kun-ming, WANG Peng-fei, MA Yan, WANG Hong-xiao, SHEN Juan-zhang, TAN Wei-hong

Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab. for Biomass Chemical Utilization;Key and Open Lab. of Forest Chemical Engineering, SFA;Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China

Received:2016-02-29 Online:2016-09-30 Published:2016-12-03

摘要/Abstract

摘要： 对固体材料中生物基含量的测定方法进行了综述，介绍了选择性溶解法（SDM）和¹⁴C法这两种测定方法。选择性溶解法准确性相对要低，样品前处理也比较复杂且费时。¹⁴C包括液体闪烁计数法和加速器质谱法，液体闪烁计数法又包括CO₂吸收法、直接液体闪烁计数法和苯合成法。CO₂吸收法简单、快速且花费低廉，但是精度较低，适用于对精度要求不高的样品；直接液体闪烁计数法样品前处理过程最简单，但对样品的要求很高，溶解于闪烁液后的溶液干扰因素多且难以消除；苯合成法具有很高的精度，但是样品前处理费时，且测定周期长。加速器质谱法快速且测定精度高，但设备费用极昂贵，在一定程度上限制了其应用。最后，对固体材料中生物基含量测定方法的各种技术发展进行了展望。

关键词: 固体材料, 生物基含量, 选择性溶解法, ¹⁴C法

Abstract: The determination methods of bio-based content in bio-based solid material,including the selective dissolution method(SDM) and ¹⁴C method,were reviewed.The precision of SDM was relatively lower,and its sample preparation was more complex and time consuming.¹⁴C method contained liquid scintillation counting(LSC) method,which included CO₂ absorption method,direct LSC method and benzene synthesis,and accelerator mass spectrometry(AMS) method.CO₂ absorption method was simple,fast and low cost,but it was also low precision.This method was suitable for the sample requirement for not high precision.The sample preparation of direct LSC method was the simplest in all methods,but it had a high requirement on the samples.This method had a lot of interference factors which were difficult to be eliminated.Benzene synthesis method had high precision,but the sample pretreatment took time,and the measuring period was long.Accelerator mass spectrometry was a rapid detection method and also had high precision,but the equipment was extremely expensive.These all limited its application.Finally,the prospects for their future development were also presented.

Key words: solid material, bio-based content, selective dissolution, ¹⁴C method

中图分类号:

TQ35

邓坤明, 王鹏飞, 马艳, 王宏晓, 沈娟章, 谭卫红. 生物质基固体材料中生物基含量测定方法的研究进展[J]. 生物质化学工程, 2016, 50(5): 53-59.

DENG Kun-ming, WANG Peng-fei, MA Yan, WANG Hong-xiao, SHEN Juan-zhang, TAN Wei-hong. Research Progress of Determination Method of Bio-based Content in Bio-based Solid Material[J]. bce, 2016, 50(5): 53-59.

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生物质基固体材料中生物基含量测定方法的研究进展

Research Progress of Determination Method of Bio-based Content in Bio-based Solid Material

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