UV光-暗双重固化体系的研究进展

doi:10.3969/j.issn.1673-5854.2016.05.011

生物质化学工程 ›› 2016, Vol. 50 ›› Issue (5): 60-66.doi: 10.3969/j.issn.1673-5854.2016.05.011

• 综述评论 • 上一篇

UV光-暗双重固化体系的研究进展

毛伟^1,2, 李守海^1,2, 黄坤^1,2, 李梅¹, 夏建陵^1,2

1. 中国林业科学研究院林业新技术研究所, 北京 100091;
2. 中国林业科学研究院林产化学工业研究所;生物质化学利用国家工程实验室;国家林业局林产化学工程重点开放性实验室;江苏省生物质能源与材料重点实验室, 江苏南京 210042

收稿日期:2016-01-19 出版日期:2016-09-30 发布日期:2016-12-03
通讯作者: 夏建陵(1958-),女,研究员,硕士生导师,主要从事天然资源化学利用的研究;E-mail:xiajianling@126.com。 E-mail:xiajianling@126.com
作者简介:毛伟(1990-),女,河南信阳人,硕士生,主要从事生物基高分子材料的研究;E-mail:maowei507@126.com
基金资助:
中国林科院基本科研专项资金项目（CAFINT2014C08）

Development of UV Light-dark Dual Curing System

MAO Wei^1,2, LI Shou-hai^1,2, HUANG Kun^1,2, LI Mei¹, XIA Jian-ling^1,2

1. Research Institute Forestry New Technology, CAF, Beijing 100091, China;
2. Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab. for Biomass Chemical Utilization;Key and Open Lab. of Forest Chemical Engineering, SFA;Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China

Received:2016-01-19 Online:2016-09-30 Published:2016-12-03

摘要/Abstract

摘要： 综述了UV光-暗双重固化体系的研究现状，总结了UV光-暗双重固化中的UV光固化反应和暗聚合反应类型，并重点介绍了UV光-湿气、UV光-热、UV光-空气和复合型4种双重固化方式。与单一的UV光固化技术相比，UV光-暗双重固化能够很好地解决单一UV光固化体系存在的固化不完全等问题，且UV光-暗双重固化技术制得的固化膜普遍具有化学稳定性好、耐侯性优异、环境污染小等优点。

关键词: 紫外光固化, UV光-暗双重固化, 双固化反应类型, 固化体系

Abstract: Firstly,the research status of UV light-dark dual curing was reviewed.Then the UV light curing reaction,the curing reaction types of dark polymerization reaction and UV-moisture,UV-thermal,UV-air and compound type dual curing ways of the UV light-dark dual curing system were emphatically introduced.Compared with single UV light curing technology,UV light-dark dual curing had a very good solution to solve the problems of undercured system and so on induced by single UV light curing system.Moreover,the curing membrane produced by UV light-dark dual curing technology generally had some advantages,such as good chemical stability,excellent corrosion resistance and less environmental pollution.

Key words: UV light curing, UV light-dark dual curing, reaction types of dual curing, curing system

中图分类号:

毛伟, 李守海, 黄坤, 李梅, 夏建陵. UV光-暗双重固化体系的研究进展[J]. 生物质化学工程, 2016, 50(5): 60-66.

MAO Wei, LI Shou-hai, HUANG Kun, LI Mei, XIA Jian-ling. Development of UV Light-dark Dual Curing System[J]. bce, 2016, 50(5): 60-66.

参考文献

[1] TANOUE N,KOISHI Y,ATSUTA M,et al. Properties of dual-curable luting composites polymerized with single and dual curing modes[J]. Journal of Oral Rehabilitation,2003,30(10):1015-1021.
[2] KOISHI Y,TANOUE N,ATSUTA M,et al. Influence of visible-light exposure on colour stability of current dual-curable luting composites[J]. Journal of Oral Rehabilitation,2002,29(4):387-393.
[3] 聂俊,肖鸣,何勇. 光固化涂料研究进展[J]. 涂料工业,2009,39(12):13-16.
[4] 肖思煜. 紫外光固化涂料的发展状况[J]. 广州化工,2005,33(5):31-33.
[5] 廖正福,袁慧雅,庞来兴,等. 光-暗双固化共性覆膜胶研究进展[J]. 绝缘材料,2004(4):52-56.
[6] CHO J D,KIM H K,KIM Y S,et al. Dual curing of cationic UV-curable clear and pigmented coating systems photosensitized by thioxanthone and anthracene[J]. Polymer testing,2003,22(6):633-645.
[7] LIU Hong-bo,YU Lin-liang,CHEN Ming-cai. Preparation of UV-curable long chain dibasic acid modified epoxydiacrylates and their coating properties[J]. Materials Research Bulletin,2003,38(11/12):1607-1612.
[8] 孙芳,黄毓礼,夏兰英. 引发体系对聚氨酯丙烯酸酯混杂光固化体系感光性能的影响[J]. 辐射研究与辐射工艺学报,2004,22(1):19-22.
[9] 陈其道,陈明,洪啸吟. 混杂聚合[J]. 化学通报,2000,63(6):1-5.
[10] LIU Hong-bo,CHEN Ming-cai,HUANG Zhi-tang. The influence of silicon-containing acrylate as active diluenton the properties of UV-cured epoxydiac-rylate films[J]. European Polymer Journal,2004,40(3):609-613.
[11] FOUASSIER J P,RABEK J F. Radiation Curing in Polymer Science and Technology[M]. New York:Elsevier Applied Science,1993,3:177-180.
[12] NATIVI L A. Conformal coating and potting system:US,4415604[P]. 1983-11-15.
[13] 胡玉明. 环氧固化剂及添加剂[M]. 北京:化学工业出版社,2011:1-2.
[14] KAJTNA J,KRAJNC M. UV crosslinkable microsphere pressure sensitive adhesives-influence on adhesive properties[J]. International Journal of Adhesion and Adhesives,2011,31(1):29-35.
[15] DENNIS W E,VAN W B. Ultraviolet curing conformal coating with dual shadow cure:US,5008301[P]. 1991-04-16.
[16] KYLE D R. Dual curing composition based on isocyanate trimer and use thereof:US,5234970[P]. 1993-08-10.
[17] QI Yu-song,YANG Jian-wen,ZENG Zhao-hua,et al. Novel reactive diluents for UV/moisture dual-curable coatings[J]. Journal of Applied Polymer Science,2005,98(4):1500-1504.
[18] NEBIOGLU A,SOUCEK M. Optimization of UV curable acrylated polyester-polyurethane/polysiloxane ceramer coatings using a response surface methodology[J]. Journal of Composites Technology and Research,2006,3(1):61-68.
[19] 甘禄铜,张军营,张光普. 可紫外光/湿气双重固化聚硅氧烷丙烯酸酯树脂的合成与表征[J]. 化工新型材料,2011,39(9):92-95.
[20] CHANG C J,TZENG H Y. Preparation and properties of waterborne dual curable monomers and cured hybrid polymers for ink-jet applications[J]. Polymer,2006,47(26):8536-8547.
[21] CAI Hai-yuan,LIN Xing,ZHU Cheng-wei,et al. Study on preparation and properties of UV/moisture dual curable polyurethane hot melt adhesive[J]. China Adhesives,2012,21(4):994-997.
[22] PARK Y J,KIM H J,PARK D S,et al. Reliability of liquid crystal cell and immiscibility between dual-curable adhesives and liquid crystal[J]. European Polymer Journal,2010,46(7):1642-1648.
[23] 李建雄,柯涛,马银涛,等. α-氨基酮光引发剂促进环氧/丙烯酸酯混杂树脂光-热的双固化[J]. 高分子材料科学与工程,2013,29(1):84-87.
[24] MORANCHO J M,RAMIS X,SERRA A,et al. Photocuring and thermal post-curing of a cycloaliphatic epoxide resin with a trithiol and a vinyl epoxy compound[J]. Journal of Thermal Analysis Calorimetry,2015,121(1):389-395.
[25] SANGERMANO M,VOIT B,SORDO F,et al. High refractive index transparent coatings obtained via UV/thermal dual-cure process[J]. Polymer,2008,49(8):2018-2022.
[26] KIM Y B,KIM H K,HONG J W. Dual-curable acrylic pressure-sensitive adhesives based on UV and thermal processes[J]. Macromolecular Research,2008,16(2):128-133.
[27] YUAN Hui-ya,LU Xue-yi,ZENG Zhao-hua,et al. Allyl ether-modified unsaturated polyesters for UV/air dual-curable coatings. I:Synthesis and characterization of the oligomers and their cured films[J]. Journal of Applied Polymer Science,2004,92(5):2765-2770.
[28] WU Shao-bing,SEARS M T,SOUCEK M D. Synthesis of reactive diluents for cationic cycloaliphatic epoxide UV coatings[J]. Polymer,1999,40(20):5675-5686.
[29] SU W F A,BARRETT A P. UV conformal coatings:US,5213875[P]. 1993-05-25.

UV光-暗双重固化体系的研究进展

Development of UV Light-dark Dual Curing System

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 2

编辑推荐

Metrics

本文评价

关于本刊

投稿指南

在线期刊

相关单位

联系我们

[1]	蒋秋娜;林明涛;王基夫;储富祥;王春鹏;. 紫外光固化纳米SiO₂/改性丙烯酸松香杂化涂料的研究[J]. 生物质化学工程, 2008, 42(6): 10-14.
[2]	蒋秋娜;林明涛;储富祥;王基夫;王春鹏;. 紫外光固化聚合物基 SiO₂ 纳米复合材料的研究进展[J]. 生物质化学工程, 2008, 42(4): 51-56.