Biomass Chemical Engineering ›› 2022, Vol. 56 ›› Issue (4): 49-57.doi: 10.3969/j.issn.1673-5854.2022.04.007
• Review Comment • Previous Articles Next Articles
Linshan WEI1,2(), Jun YE1,2, Kui WANG1,2, Jianchun JIANG1,2,*()
Received:
2021-03-22
Online:
2022-07-30
Published:
2022-07-23
Contact:
Jianchun JIANG
E-mail:1076321913@qq.com;jiangic@icifp.cn
CLC Number:
Linshan WEI, Jun YE, Kui WANG, Jianchun JIANG. Research Progress on Preparation of Levulinic Acid and Esters from Lignocellulose by Sulfate Catalyst[J]. Biomass Chemical Engineering, 2022, 56(4): 49-57.
Table 1
Physical properties of levulinic acid and methyl levulinate"
化合物 chemical compound | 相对分子质量 relative molecular weight | 折射率 refractive index | 密度/(kg·m-3) density | 熔点/℃ melting point | 沸点/℃ boiling point |
乙酰丙酸levulinic acid | 116.12 | 1.4796/20 ℃ | 1140/20 ℃ | 33~35 | 245~246 |
乙酰丙酸甲酯methyl levulinate | 130.14 | 1.422/20 ℃ | 1051/20 ℃ | -24 | 196 |
Table 2
Catalytic preparation of LA or levulinic esters with Al2(SO4)3 catalysts"
溶剂 solvent | 原料 substrate | 时间/min time | 温度/℃ temp. | 产物(质量分数) product(mass fraction) | 加热方式 heating mode | 文献 ref. |
甲醇/水methanol/water | 纤维素cellulose | 40 | 180 | ML(70.6%) | 微波加热microwave | [ |
甲醇/水methanol/water | 纤维素cellulose | 720 | 180 | ML(60.8%) | 油浴oil | [ |
甲醇/水methanol/water | 纤维素cellulose | 80 | 170 | ML(68.4%) | 微波microwave | [ |
甲醇methanol | 葡萄糖glucose | 150 | 160 | ML(64%) | 油浴oil | [ |
甲醇methanol | 葡萄糖glucose | 120 | 200 | ML(54%) | 油浴oil | [ |
甲醇methanol | 果糖fructose | 150 | 160 | ML(49%) | 油浴oil | [ |
甲醇methanol | 纤维素cellulose | 300 | 180 | ML(44%) | 油浴oil | [ |
乙醇ethanol | 糠醇furfural alcohol | 5 | 150 | ML(80.6%) | 微波microwave | [ |
正丁醇n-butanol | 果糖fructose | 120 | 200 | BL(43.7%) | 油浴oil | [ |
水water | 木薯cassava | 360 | 200 | LA(14.53%) | 油浴oil | [ |
乙醇/水ethanol/water | 木薯cassava | 360 | 200 | EL(37.05%) LA(10.0%)* | 油浴oil | [ |
水water | 纤维素cellulose | 120 | 250 | LA(18.4%) | 油浴oil | [ |
水water | 纤维素cellulose | 360 | 140 | LA(5%) | 油浴oil | [ |
水water | 葡萄糖glucose | 160 | 140 | LA(5.0%) | 油浴oil | [ |
甲醇methanol | 小麦秸秆wheat straw | 180 | 180 | ML(10.2%)* | 油浴oil | [ |
正丁醇n-butanol | 纤维素cellulose | 120 | 200 | BL(13.6%) | 油浴oil | [ |
Table 3
Catalytic preparation of LA or levulinic esters with Fe2(SO4)3 or FeSO4 catalysts"
催化剂 catalyst | 溶剂 solvent | 原料 substrate | 时间/min time | 温度/℃ temp. | 产物 product | 加热方式 heating mode | 文献 ref. |
Fe2(SO4)3 | 甲醇/水methanol/water | 纤维素cellulose | 40 | 180 | ML(48.2%) | 微波microwave | [ |
Fe2(SO4)3 | 水water | 纤维素cellulose | 30 | 200 | LA(1.2 g/L) | 油浴oil | [ |
Fe2(SO4)3 | 甲醇methanol | 葡萄糖glucose | 150 | 160 | ML(5.0%) | 油浴oil | [ |
Fe2(SO4)3 | 甲醇methanol | 葡萄糖glucose | 120 | 200 | ML(43.0%) | 油浴oil | [ |
FeSO4 | 水water | 纤维素cellulose | 30 | 200 | LA(0.1 g/L) | 油浴oil | [ |
Fe2(SO4)3 | 乙醇alcohol | 糠醇furfural alcohol | 5 | 150 | ML(31.4%) | 微波microwave | [ |
Fe2(SO4)3 | 正丁醇n-butanol | 果糖fructose | 120 | 200 | BL(59.2%) | 油浴oil | [ |
Fe2(SO4)3 | 水water | 木薯cassava | 360 | 200 | LA(1.22%) | 油浴oil | [ |
Fe2(SO4)3 | 乙醇ethanol | 木薯cassava | 360 | 200 | EL(9.28%) LA(4.01%) | 油浴oil | [ |
Fe2(SO4)3 | 水water | 纤维素cellulose | 120 | 250 | LA(4.7%) | 油浴oil | [ |
Fe2(SO4)3 | 正丁醇n-butanol | 纤维素cellulose | 180 | 209 | BL(37.2%) | 油浴oil | [ |
Table 4
Catalytic preparation of LA or levulinic esters with CuSO4 catalysts"
溶剂 solvent | 原料 substrate | 时间/min time | 温度/℃ temp. | 产物 product | 加热方式 heating mode | 文献 ref. |
甲醇/水methanol/water | 纤维素cellulose | 40 | 180 | ML(4.4%) | 微波microwave | [ |
甲醇methanol | 葡萄糖glucose | 150 | 160 | ML(12%) | 油浴oil | [ |
水water | 纤维素cellulose | 30 | 200 | LA(3.2 g/L) | 油浴oil | [ |
水water | 葡萄糖glucose | 30 | 200 | LA(5.0 g/L) | 油浴oil | [ |
正丁醇n-butanol | 果糖fructose | 120 | 200 | BL(54.1%) | 油浴oil | [ |
甲醇methanol | 小麦秸秆wheat straw | 234 | 183 | ML(20.1%) | 油浴oil | [ |
正丁醇n-butanol | 纤维素cellulose | 120 | 200 | BL(29.1%) | 油浴oil | [ |
Table 5
Catalytic preparation of LA or levulinic esters with ZnSO4 catalysts"
溶剂 solvent | 原料 substrate | 时间/min time | 温度/℃ temp. | 产物 product | 加热方式 heating mode | 文献 ref. |
甲醇/水methanol/water | 纤维素cellulose | 40 | 180 | ML(4.4%)* | 微波microwave | [ |
甲醇methanol | 葡萄糖glucose | 150 | 160 | ML(2.0%)* | 油浴oil | [ |
水water | 葡萄糖glucose | 30 | 200 | LA(0.1 g/L) | 油浴oil | [ |
水water | 纤维素cellulose | 30 | 200 | LA(0.3 g/L) | 油浴oil | [ |
乙醇alcohol | 糠醇furfural alcohol | 5 | 150 | ML(9.7%) | 微波microwave | [ |
正丁醇n-butanol | 果糖fructose | 120 | 200 | BL(14.3%)* | 油浴oil | [ |
水water | 木薯cassava | 360 | 200 | LA(0.92%) | 油浴oil | [ |
乙醇ethanol | 木薯cassava | 360 | 200 | EL(0.16%) LA(0.25%) | 油浴oil | [ |
Table 6
Catalytic preparation of LA or levulinate esters with sulfate catalysts"
催化剂 catalyst | 溶剂 solvent | 原料 substrate | 时间/min time | 温度/℃ temp. | 产物 product | 加热方式 heating mode | 文献 ref. |
CoSO4 | 离子液体IL-1 | 纤维素cellulose | 300 | 150 | LA(8%) | 油浴oil | [ |
CoSO4 | 甲醇methanol | 葡萄糖glucose | 150 | 160 | ML(7.0%) | 油浴oil | [ |
CoSO4 | 水water | 纤维素cellulose | 30 | 200 | LA(0.2 g/L) | 油浴oil | [ |
CoSO4 | 正丁醇n-butanol | 果糖fructose | 120 | 200 | BL(21.9%) | 油浴oil | [ |
Co2(SO4)3 | 离子液体IL-1 | 纤维素cellulose | 300 | 150 | LA(5%) | 油浴oil | [ |
SnSO4 | 甲醇/水methanol/water | 纤维素cellulose | 40 | 180 | ML(10.0%)* | 微波microwave | [ |
SnSO4 | 甲醇methanol | 葡萄糖glucose | 150 | 160 | ML(15%) | 油浴oil | [ |
SnSO4 | 乙醇ethanol | 糠醇furfural alcohol | 5 | 150 | ML(16.1%) | 微波microwave | [ |
NiSO4 | 乙醇ethanol | 木薯cassava | 360 | 200 | EL(1.38%) LA(0.42%) | 油浴oil | [ |
NiSO4 | 甲醇methanol | 葡萄糖glucose | 150 | 160 | ML(4.0%) | 油浴oil | [ |
NiSO4 | 水water | 纤维素cellulose | 30 | 200 | LA(0.2 g/L) | 油浴oil | [ |
Cr2(SO4)3 | 乙醇alcohol | 糠醇furfural alcohol | 5 | 150 | ML(0.6%) | 微波microwave | [ |
Cr2(SO4)3 | 甲醇/水methanol/water | 纤维素cellulose | 40 | 180 | ML(0.0%) | 微波microwave | [ |
MgSO4 | 水water | 木薯cassava | 360 | 200 | LA(0.86%) | 油浴oil | [ |
MgSO4 | 正丁醇n-butanol | 果糖fructose | 120 | 200 | BL(4.6%) | 油浴oil | [ |
MgSO4 | 乙醇ethanol | 木薯cassava | 360 | 200 | EL(0.42%) LA(0.41%) | 油浴oil | [ |
MnSO4 | 甲醇methanol | 葡萄糖glucose | 150 | 160 | ML(0.0%) | 油浴oil | [ |
MnSO4 | 水water | 纤维素cellulose | 30 | 200 | LA(0.1 g/L) | 油浴oil | [ |
K2SO4 | 正丁醇n-butanol | 果糖fructose | 120 | 200 | BL(3.2%) | 油浴oil | [ |
K2SO4 | 甲醇methanol | 葡萄糖glucose | 120 | 200 | ML(0.0%) | 油浴oil | [ |
Na2SO4 | 甲醇methanol | 葡萄糖glucose | 120 | 200 | ML(0.0%) | 油浴oil | [ |
Ti(SO4)2 | 正丁醇n-butanol | 果糖fructose | 120 | 200 | BL(41.1%) | 油浴oil | [ |
Table 7
Catalytic preparation of LA or levulinic esters with sulfate metaloxide catalysts"
催化剂 catalyst | 溶剂 solvent | 原料 substrate | 时间/min time | 温度/℃ temp. | 产物 product | 文献 ref. |
SO42-/TiO2 | 甲醇methanol | 蔗糖sucrose | 120 | 200 | ML(43%) | [ |
SO42-/TiO2 | 甲醇methanol | 葡萄糖glucose | 120 | 200 | ML(33%) | [ |
SO42-/TiO2 | 甲醇methanol | 果糖fructose | 120 | 200 | ML(59%) | [ |
SO42-/ZrO2 | 乙醇ethanol | 葡萄糖glucose | 180 | 200 | EL(30%) | [ |
SO42-/ZrO2 | 乙醇ethanol | 葡萄糖glucose | 120 | 200 | EL(24.5%) | [ |
SO42-/TiO2 | 乙醇ethanol | 葡萄糖glucose | 120 | 200 | EL(26.0%) | [ |
SO42-/ZrO2-TiO2 | 乙醇ethanol | 葡萄糖glucose | 120 | 200 | EL(25.5%) | [ |
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