Biomass Chemical Engineering ›› 2019, Vol. 53 ›› Issue (3): 46-58.doi: 10.3969/j.issn.1673-5854.2019.03.007
• Review Comment • Previous Articles Next Articles
Wenxin JI1,2(),Ming ZENG1,Hongbin CONG2,Zonglu YAO2,Haibo MENG2,Lixin ZHAO2,*()
Received:
2018-07-26
Online:
2019-05-30
Published:
2019-06-04
Contact:
Lixin ZHAO
E-mail:jiwenixn@aliyun.com;zhaolixin5092@163.com
Supported by:
CLC Number:
Wenxin JI,Ming ZENG,Hongbin CONG,Zonglu YAO,Haibo MENG,Lixin ZHAO. Research Status and Prospects of Biomass Pyrolysis Reactor[J]. Biomass Chemical Engineering, 2019, 53(3): 46-58.
Table 1
The types of pyrolysis reactors"
区分方式 differentiation method | 热解反应器种类 type of pyrolysis reactor | 热解反应器举例 example of pyrolysis reactor |
生物质原料颗粒及热载体受热方式 heating method of biomass raw material granules and heat carrier | 机械接触式 mechnical contact-type | 旋转锥反应器、烧蚀式反应器 rotating cone reactor, ablative reactor |
间接式 indirect type | 热辐射式反应器 heat radiation reactor | |
复合加热式 composite heating | 循环流化床反应器、喷射床反应器 circulating fluidized bed reactor, spouted bed reactor | |
生物质原料颗粒及载热体运动方式 movement mode of biomass material particles and heat carrier | 固定床 fixed bed | 真空管式炉 vacuum tube furnace |
移动床 moving bed | 旋转床反应器 rotating bed reactor | |
流化床 fluidized bed | 鼓泡/循环流化床 bubbling/circulating fluidized bed |
Table 2
The characteristics of several common biomass pyrolysis reactors"
反应器类型 type of reactor | 优点 advantage | 缺点 disadvantage |
流化床反应器 fluidized bed reactor | 装置体积小,反应过程气相停留时间短,可有效降低二次反应,效率高,容易推广 the device has small volume and short residence time in the reaction process, which can effectively reduce the secondary reaction, has high efficiency, and is easy to popularize | 原料颗粒尺寸要求严格,粉碎物料成本大,处理量大时热效率低 the size of raw material is strict, the cost of crushing material is large, and the heat efficiency is low when the amount of processing is large |
引流床反应器 drainage bed reactor | 生物质焦油产量大,可达60% biomass tar production is large, up to 60% | 设备运行过程中,需要消耗大量的高热值燃气,所得热解气热值低,应用面窄 during the operation of the equipment, a large amount of high calorific value gas is consumed, and the obtained pyrolysis gas has a low calorific value and a narrow application surface |
烧蚀反应器 ablative reactor | 对原料粒度要求相对较宽,可利用2~6.35 mm的大颗粒生物质作为原料 the granularity of raw materials is relatively wide, and large particle biomass of 2 to 6.35 mm can be used as raw material | 所产生物质焦油中氧含量较高,热值较低 the produced material tar has high oxygen content and low calorific value |
旋转锥反应器 rotating cone reactor | 物料紧密度较高,升温速率高,固相、气相产物停留时间短,无需载气,生产成本低 the material has high tightness, high heating rate, short residence time of solid phase and gas phase product, no need of carrier gas, and low production cost | 生产规模小,对原料粒度要求高,装置中的有些结构设计不够成熟 the production scale is small, the granularity of raw materials is high, and some structural design of the device are not mature enough |
移动床反应器 moving bed | 结构简单,投资少,入料粒度大,气相停留时间短,二次反应减少 the structure is simple, the investment is small, the feed size is large, the gas phase residence time is short, and the secondary reaction is reduced | 传热效率低,能耗较大,处理量小,装置运行稳定性差 low heat transfer efficiency, high energy consumption, small processing capacity, poor operation stability of the device |
1 |
朱锡锋, 李明. 生物质快速热解液化技术研究进展[J]. 石油化工, 2013, 42 (8): 833- 837.
doi: 10.3969/j.issn.1000-8144.2013.08.001 |
2 | 周勇. 清洁生物质秸秆能源研究进展[J]. 应用化工, 2005, (10): 8- 10, 19. |
3 | 姚娜.生物质快速热解特性试验研究[D].哈尔滨:哈尔滨工业大学, 2008. |
4 |
王伟文, 吴国鑫, 张自生. 生物质热解研究进展[J]. 当代化工, 2017, 46 (11): 2300- 2302, 2315.
doi: 10.3969/j.issn.1671-0460.2017.11.033 |
5 | 黄鹏, 郭军志, 杨涛, 等. 预处理催化法对生物质热解的影响研究进展[J]. 化工生产与技术, 2015, 22 (3): 9- 46.42-46, 9-10 |
6 | 隋春平, 王雷, 黄洪风. 基于红外加热的生物质热解技术及关键参数[J]. 中国科学院大学学报, 2016, 33 (3): 398- 402. |
7 | 袁振宏, 吴创之, 马隆龙, 等. 生物质能利用原理与技术[M]. 北京: 化学工业出版社, 2005: 289- 293. |
8 | 杨昌炎, 姚建中, 林伟刚, 等. 秸秆蒸汽汽爆、固态发酵处理结合快速热解制液体燃料[J]. 现代化工, 2006, (S1): 126- 130. |
9 | 任天宝, 马孝琴, 徐桂转, 等. 蒸汽爆破玉米秸秆热解特性及其动力学分析[J]. 农业工程学报, 2011, 27 (S1): 32- 36. |
10 |
陈杰, 张秋翔, 蔡纪宁, 等. 螺杆挤压连续汽爆装置预处理秸秆试验研究[J]. 纤维素科学与技术, 2011, 19 (4): 56- 61.
doi: 10.3969/j.issn.1004-8405.2011.04.010 |
11 | BAKER C G J.食品工业化干燥[M],张敏,译.北京:中国轻工业出版社, 2003, 6: 24. |
12 | 崔保林.秸秆输送干燥系统的研究与设计[D].沈阳:东北大学, 2013. |
13 |
陈勇, 陈登宇, 孙琰, 等. 烘焙脱氧预处理对生物质秸秆燃料品质的影响[J]. 科学技术与工程, 2015, 15 (11): 205- 209.
doi: 10.3969/j.issn.1671-1815.2015.11.038 |
14 | 郝宏蒙.烘焙生物质疏水性能及热解特性研究[D].武汉:华中科技大学, 2013. |
15 | 江洋, 张会岩, 邵珊珊, 等. 烘焙预处理对生物质热解的影响[J]. 燃烧科学与技术, 2015, 21 (3): 229- 235. |
16 |
BRIDGWATER A V . Review of fast pyrolysis of biomass and product upgrading[J]. Biomass and Bioenergy, 2012, 38, 68- 94.
doi: 10.1016/j.biombioe.2011.01.048 |
17 | 高新源, 徐庆, 李占勇, 等. 生物质快速热解装置研究进展[J]. 化工进展, 2016, 35 (10): 3032- 3041. |
18 | 杨瑛.棉秆直接热解炭化工艺参数试验研究[D].武汉:华中农业大学, 2014. |
19 | 石海波.固定床生物质热解炭化系统设计与实验研究[D].天津:河北工业大学, 2013. |
20 |
常杰. 生物质液化技术的研究进展[J]. 现代化工, 2003, 23 (9): 13- 16.
doi: 10.3321/j.issn:0253-4320.2003.09.004 |
21 | PEACOCKE G V C , BRIDGWATER A V . Ablative plate pyrolysis of biomass for liquids[J]. Biomass Bioenergy, 1995, (7): 147- 154. |
22 | 张长森,张瑞琴.生物质流化床汽化及热解实验研究[D].郑州:郑州大学, 2006. |
23 | SCOTT D S , MAJERSKI P , PISKORZ J , et al. A second look at fast pyrolysis of biomass-the RTI process[J]. Journal of Analytical and Applied Pyrolysis, 1999, (51): 23- 37. |
24 | VELDEN M V , BAEYENS J , BOUKIS I . Modeling CFB biomass pyrolysis reactors[J]. Biomass and Bioenergy, 2008, (32): 128- 139. |
25 | 武文琴. 生物质热解反应器的研究进展[J]. 企业技术开发, 2016, 35 (20): 6- 7. |
26 | 刘姗, 杨雪银, 任学勇, 等. 生物质热解油基绿色化学品与化工产品研究进展[J]. 化工新型材料, 2017, 45 (11): 17- 20, 24. |
27 |
李亚丽, 廖传华, 刘状. 生物质微粉霾化热解制油技术初探[J]. 应用化工, 2017, 46 (11): 2252- 2256.
doi: 10.3969/j.issn.1671-3206.2017.11.044 |
28 |
赵忠祥, 廖传华, 李广鹏, 等. 生物质微粉霾化快速热解装置的开发[J]. 化工机械, 2018, 45 (3): 297- 300.
doi: 10.3969/j.issn.0254-6094.2018.03.006 |
29 |
GONZALEZ-QUIROQA A , REYNIERS P A , KULKARNI S R , et al. Design and cold flow testing of a gas-solid vortex reactor demonstration unit for biomass fast pyrolysis[J]. Chemical Engineering Journal, 2017, 329, 198- 210.
doi: 10.1016/j.cej.2017.06.003 |
30 | 邓旭升.搅拌床快速热解反应器设计及其实验研究[D].北京:北京林业大学, 2013. |
31 |
ZHANG J , QUAN C , QIU Y , et al. Effect of char on co-pyrolysis of biomass and coal in a free fall reactor[J]. Fuel Processing Technology, 2015, 135, 73- 79.
doi: 10.1016/j.fuproc.2014.10.022 |
32 |
BOATENG A A , SCHAFFER M A , MULLEN C A , et al. Mobile demonstration unit for fast and catalytic pyrolysis:The combustion reduction integrated pyrolysis system (CRIPS)[J]. Journal of Analytical and Applied Pyrolysis, 2019, 137, 185- 194.
doi: 10.1016/j.jaap.2018.11.024 |
33 |
陈冠益, 颜蓓蓓, 贾佳妮, 等. 生物质二级固定床催化热解制取富氢燃气[J]. 太阳能学报, 2008, (3): 360- 364.
doi: 10.3321/j.issn:0254-0096.2008.03.020 |
34 |
JIANG L , WANG Y , DAI L , et al. Co-pyrolysis of biomass and soapstock in a downdraft reactor using a novel ZSM-5/SiC composite catalyst[J]. Bioresource Technology, 2019, 279, 202- 208.
doi: 10.1016/j.biortech.2019.01.119 |
[1] | Weixing ZENG,Xian CHENG,Zuohui ZHANG,Liangwu BI,Zhendong ZHAO. Application Research Progress of Biological Pretreatment Technology in Extraction of Natural Products [J]. Biomass Chemical Engineering, 2020, 54(5): 45-52. |
[2] | Huashan WANG,Yuren FANG,Tianhang ZHANG,Hua LIU,Chunsheng WANG. Combustion Characteristics and Kinetics Analysis of Rice Husk with Different Pretreatment and Mixing with Poplar Sawdust [J]. Biomass Chemical Engineering, 2020, 54(3): 1-8. |
[3] | Hongliang MA,Jian CHEN,Zhenwu KONG. Progress on Modification of Natural Plant Fiber for Composites [J]. Biomass Chemical Engineering, 2019, 53(4): 50-58. |
[4] | WANG Tipeng, ZHANG Runhe, PENG Li, GUO Haoqiang, LU Qiang, DONG Changqing. Research Progress of Aromatics Production from Catalytic Pyrolysis of Biomass [J]. bce, 2018, 52(4): 53-59. |
[5] | LIN Xing, YANG Xuan, CAI Zhenghan, LIN Guanfeng, LI Yuhua, HUANG Biao. Activated Carbon Prepared with Phosphoric Acid Activation by Mechanical Force Pretreatment Method and Conventional Method [J]. bce, 2018, 52(3): 29-34. |
[6] | ZHENG Yulong, LI Shuying, PANG Diqiong, YANG Fuyu. Research Progress on Microbial Pretreated Conversion of Energy Grass to Bio-energy [J]. bce, 2018, 52(2): 51-58. |
[7] | WEI Wei, CHANG Fuxiang, SUN Jianzhong, WANG Qianqian. Recent Advances in “One-pot” Bioethanol Production from Lignocellulose [J]. bce, 2018, 52(1): 53-59. |
[8] | MA Panpan, HE Shanshan, DI Mingwei. Research Progress on Activation Method of Cellulose [J]. bce, 2017, 51(5): 61-66. |
[9] | LIU Wenwen, LIANG Long, SHEN Kuizhong, FANG Guigan, TIAN Qingwen. Effects of NaOH/AQ Pretreatment on Delignification and Enzymatic Digestibility of Corn Stover [J]. bce, 2017, 51(4): 39-46. |
[10] | ZHANG Xian-bao, ZHANG Teng, XIE Wen-hua, ZHU Ming-jun. Impacts of NaOH Pretreatment on Enzymolysis and Fermentation Performance of Sugarcane Bagasse [J]. bce, 2016, 50(6): 9-16. |
[11] | YANG Shu-juan, YOU Yan-zhi, BU Ling-xi, LI Xiao-li, JIANG Jian-xin. Pretreatment of Waste Paper Pulp and Enzymatic Hydrolysis Properties [J]. bce, 2016, 50(4): 37-41. |
[12] | SI Sheng-li, LI Ming, JIA Jun, LI Qing, HAO Bo, WANG Yan-ting, PENG Liang-cai, TU Yuan-yuan. Effects of Byproducts Obtained from Alkali or Acid Pretreatment of Miscanthus Biomass on Yeast Fermentation [J]. bce, 2016, 50(3): 41-45. |
[13] | BI Shuai-zhu, PENG Lin-cai, CHEN Ke-li. Advances in Pretreatment Technology of Sugarcane Bagasse for Bioethanol Production [J]. bce, 2016, 50(2): 53-60. |
[14] | WU Shu-ping, JI Yu-cheng, MA Bao-jun, XIE Hao, LIU Wan-yi. Liquefaction of Pretreated Furfural Residues [J]. bce, 2014, 48(6): 11-17. |
[15] | FANG Gui-gan, LIU Shan-shan, SHEN Kui-zhong. Optimization of Dilute-sulfuric Acid Pretreatment of Poplar Residues by Using Response Surface Design [J]. bce, 2014, 48(6): 18-24. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||