过渡金属催化5-羟甲基糠醛合成2, 5-呋喃二甲酸研究进展

doi:10.3969/j.issn.1673-5854.2022.02.008

Abstract

Abstract:

With the continuous improvement of the concept of green synthesis, transition metal catalysts with high catalytic activity, stability and low price replacing strong oxidizers and precious metal catalysts to catalyze the oxidation of 5-hydroxymethyl furfural(HMF) to prepare fine chemicals gradually become the focus of the researchers. This article reviewed recent researches on the use of cheap transition metal-based catalysts to catalyze the oxidation of 5-hydroxymethylfurfural(HMF) to 2, 5-furandicarbaldehyde(FDCA). The latest research in this field was described, with emphasis on introducing. The application of manganese-based, copper-based, iron/cobalt-based, nickel-based and other catalytic systems, such as manganese-based metal oxide, CuCl₂ catalytic system, Fe₃O₄-CoO_x magnetic catalyst, etc, in the HMF oxidation reaction were discussed. In addition, on the basis of the introduction of the above-mentioned catalysts, the development prospects of cheap transition metal-based catalysts catalyzed by HMF oxidation to prepare FDCA were also prospected.

Key words: 5-hydroxymethylfurfural, 2, 5-furandicarboxylic acid, catalytic oxidation, reaction mechanism

CLC Number:

TQ35

Jifeng BAI, Hongzhu LU, Yu YANG, Manfang CHENG, Jingyun WANG. Research Progress in the Synthesis of 2, 5-Furandicarboxylic Acid from 5-Hydroxymethylfural Catalyzed by Transition Metals[J]. Biomass Chemical Engineering, 2022, 56(2): 49-59.

Figures/Tables 6

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Table 1

Comparison of different transition metal catalysts"

催化剂种类 catalyst type		优点 merit	缺点 demerit	活性 activity	选择性 selectivity	使用寿命 life	成本 cost
锰基催化剂 Mn-based catalyst	金属/溴化物 metal/bromide	反应条件温和 mild reaction conditions	催化效率低，反应不可控，易污染环境以及难分离low catalytic efficiency, uncontrollable reaction, easy to pollute the environment and difficult to separate	低 low	一般 ordinary	低 low	低廉 cheap
锰基催化剂 Mn-based catalyst	金属氧化物 metallic oxide	易分离，价格低廉 easy to separate, low price	碱用量高，易产生大量工业废水alkali consumption high, easy to produce a large amount of industrial wastewater	较高 higher	较好 good	大多数可回收 most recyclable	低廉 cheap
铜基催化剂 Cu-based catalyst	CuCl₂催化体系CuCl₂ catalytic system	利用其溶解性，使催化剂与反应物达到分子层面的接触，提高了选择性using its solubility, reaching the molecular level contact of the catalyst and the reactants and improving the selectivity	不易分离，催化剂不易重复使用，且易产生环境污染物not easy to separate, not easy to reuse, and easy to produce environmental pollutants	一般 ordinary	较高 higher	低 low	低廉 cheap
铜基催化剂 Cu-based catalyst	负载型催化剂supported catalyst	载体有孔道结构，高比表面积，催化活性高the carrier has pore structure, high specific surface area and high catalytic activity	活性组分易流失，活性组分易分布不均the active component is easy to be lost and unevenly distributed	较高 higher	一般 ordinary	低 low	较高 higher
铁、钴基催化剂 Fe/Co-based catalyst	卟啉配合物催化剂porphyrin complex catalyst	回收简单方便simple and convenient recycling	合成步骤繁琐 complex synthesis steps	较高 higher	较好 good	循环使用 6次recycle 6 times	较高 higher
	氧化物催化剂oxide catalyst	易分离，合成方式简单easy separation and simple synthesis	气体为氧化剂，操作不便 gas as oxidant, inconvenient to operate	较高higher	较好 good	大多数可回收 most recyclable	较低 lower
	光催化剂 photocatalyst	反应过程中不会产生污染no contamination occurs during the reaction	反应条件苛刻 harsh reaction conditions	较高 higher	较好 good	一般不回收 generally not recycled	较高 higher
镍基催化剂 Ni-based catalyst		可提高贵金属催化剂活性the activity of precious metal catalyst can be improved	反应时间较长 the reaction time long	较高 higher	较好 good	较低 lower	较低 lower
其他基催化剂 other catalyst	Zr和Fe双金属氧化物催化剂 Zr and Fe bimetallic oxide catalysts	不使用碱，不会污染环境no use of alkali, no envi-ronmental pollution	离子液体生产成本较高，合成工工艺复杂the production cost of ionic liquid is high and the synthesis process is complicated	较高 higher	较好 good	一般 ordinary	较高 higher
其他基催化剂 other catalyst	Mo基催化剂 Mo-based catalyst	溶剂使用水，无毒solvent using water, no toxicity	反应过程使用碱，易污染环境the reaction process uses alkali, easy to pollute the environment	较高 higher	较好 good	一般 ordinary	较高 higher

Table 1

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Research Progress in the Synthesis of 2, 5-Furandicarboxylic Acid from 5-Hydroxymethylfural Catalyzed by Transition Metals

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