有机溶剂自催化和协同预处理促进木质纤维原料酶解研究进展

doi:10.3969/j.issn.1673-5854.2020.06.012

Abstract

Abstract:

The lignocellulosic materials are renewable and abundant in resource, and the natural anti-degradation barrier of the cell wall of lignocellulosic materials could be broken through appropriate pretreatment, which promote its effective conversion to oligosaccharides or fermentable sugars in subsequent processing, and then efficiently preparing bioethanol. Organic solvent pretreatment is considered to be one of the effective pretreatment methods. It can not only improve the enzymatic hydrolysis efficiency but also effectively separate the lignin, which provides the efficient utilization of the components in the lignocellulose. Organic solvent pretreatment can be divided into autocatalytic pretreatment and catalyst-organic solvent synergistic pretreatment, according to adding catalyst or not. Lignin is one of the important factors that limiting the enzymatic hydrolysis of lignocellulosic materials. This paper reviewed the effects of type of organic solvents and catalysts on the removal of lignin. The reaction mechanism of catalyst-organic solvent co-pretreatment also was reviewed.

Key words: lignocellulose, organic solvent, pretreatment, catalyst, enzymatic hydrolysis

CLC Number:

TQ352

Yuna KAN, Bingwei CHEN, Shengcheng ZHAI, Mingzhu PAN, Changtong MEI. Progress in Organic Solvent Autocatalytic and Synergistic Pretreatment to Promote the Enzymatic Hydrolysis of Lignocellulosic Materials[J]. Biomass Chemical Engineering, 2020, 54(6): 74-82.

Figures/Tables 2

References 62

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预处理方式 pretreatment methods	原料 raw material	有机溶剂 organic solvent		温度/℃ temperature	酶解效率/% enzymatic digestibility	参考文献 references
预处理方式 pretreatment methods	原料 raw material	类型 type	用量/% dosage	温度/℃ temperature	酶解效率/% enzymatic digestibility	参考文献 references
自催化 auto-catalyzed	麦草wheat straw	甘油glycerinum	70	220	90	^[8]
	麦草wheat straw	丙酮acetone	50	205	87	^[9]
	麦草wheat straw	乙醇ethanol	50	210	85	^[10]
	毛竹Moso bamboo	丁二醇butanediol	20	200	82.3	^[11]
	蔗渣bagasse	甘油glycerinum	70	220	67	^[12]
酸催化 acid-catalyzed	麦草wheat straw	乙醇ethanol	50	190	89.5	^[10]
	玉米秸秆corn stover	乙醇ethanol	50	200	80.2	^[13]
	鹅掌楸yellow poplar	乙醇ethanol	50	130	77.3	^[14]
	松木pine	乙醇ethanol	50	180	57	^[15]
	椰壳Coir	丁二醇butanediol	80	200	79.4	^[16]
碱催化 alkali-catalyzed	玉米秸秆corn stover	乙醇ethanol	60	110	83.7	^[7]
	鹅掌楸yellow poplar	乙醇ethanol	50	160	65	^[14]
	松木pine	乙醇ethanol	50	210	85.4	^[15]
	芦竹giant reed	乙醇ethanol	70	90	49.4	^[17]
	玉米秸秆corn stover	甲醇methanol	60	50	83.7	^[18]
	稻草straw	丙酮acetone	80	80	93	^[19]
	蔗渣bagasse	甘油glycerinum	70	240	90	^[12]

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Progress in Organic Solvent Autocatalytic and Synergistic Pretreatment to Promote the Enzymatic Hydrolysis of Lignocellulosic Materials

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