云南松热解及其热解产物的研究

doi:10.3969/j.issn.1673-5854.2015.04.003

Abstract

Abstract: The pyrolysis of Yunnan pine was conducted in home-made,fixed-bed reactor.The effects of pyrolysis temperatures,feedstock particle size and nitrogen gas flow rate on characteristic of Yunnan pine pyrolysis were studied.And the compositions of bio-oil were identified by GC-MS.The results showed that:the highest yield of bio-oil was obtained as 50%when the pyrolysis temperature was 500 ℃,particle size was 0.250-0.420 mm,and nitrogen gas flow rate was 150 mL/min.2,6-Di-tert-butyl-p-cresol,2-methoxy-4-methylphenol,isoeugenol,guaiacol composed the main liquid products,and accounted for 39.24%.

Key words: Yunnan pine, pyrolysis, parameters, bio-oil, chemical compositions

CLC Number:

TQ35

WANG Fei, ZHENG Yun-wu, ZHENG Zhi-feng. Yields and Compositions of Products by Pyrolysis of Yunnan Pine[J]. bce, 2015, 49(4): 14-18.

References

[1] GOYAL H B,SEAL D,SAXENA R C.Bio-fuels from thermochemical conversion of renewable resources:A review [J].Renewable & Sustainable Energy Reviews,2008,12(2):504-517.
[2] BASU P.Biomass Gasification and Pyrolysis Practical Design and Theory [M].Beijing:Science Press,2011.
[3] ONAY O.Influence of pyrolysis temperature and heating rate on the production of bio-oil and char from safflower seed by pyrolysis,using a well-swept fixed-bed reactor [J].Fuel Processing Technology,2007,88:523-531.
[4] TENG H,LIN Yu-Chuan,HSU L Y.Production of activated carbons from pyrolysis of waste tires impregnated with potassium hydroxide [J].Journal of the Air & Waste Management Association,2000,50(11):1940-1946.
[5] SHEN Lilly,ZHANG Dong-ke.Low-temperature pyrolysis of sewage sludge and putrescible garbage for fuel oil production [J].Fuel,2005,84(7):809-815.
[6] SEEBAUER V,PETEK J,STAUDINGER G.Effects of particle size,heating rate and pressure on measurement of pyrolysis kinetics by thermogravimetric analysis [J].Fuel,1997,76(13):1277-1282.
[7] COMMANDRÉ J M.Pyrolysis of wood at high temperature:The influence of experimental parameters on gaseous products [J].Fuel Processing Technology,2011,92(5):837-844.
[8] YU Yan-qing,LI Xiang-yu,SU Lu,et al.The role of shape selectivity in catalytic fast pyrolysis of lignin with zeolite catalysts [J].Applied Catalysis A:General,2012,447-448:115-123.
[9] XIAO Rui-rui,YANG Wei.Influence of temperature on organic structure of biomass pyrolysis products [J].Renewable Energy,2013,50:136-141.
[10] STEFANIDIS S D,KALOGIANNIS K G,ILIOPOULOU E F,et al.A study of lignocellulosic biomass pyrolysis via the pyrolysis of cellulose,hemicellulose and lignin [J].Journal of Analytical and Applied Pyrolysis,2014,105:143-150.
[11] YANG Hai-ping,YAN Rong,CHEN Han-ping,et al.Characteristics of hemicellulose,cellulose and lignin pyrolysis [J].Fuel,2007,86(12/13):1782-1788.
[12] 樊永胜,蔡忆昔,李小花,等.真空热解工艺参数对生物油产率的影响研究[J].林产化学与工业,2014,34(1):79-85.
[13] SEN瘙塁OZ S,ANGIN D.Pyrolysis of safflower (Charthamus tinctorius L.) seed press cake:Part 1.The effects of pyrolysis parameters on the product yields [J].Bioresource Technology,2008,99(13):5492-5497.
[14] ÖZBAY N,PVTVN A E,PVTVN E.Bio-oil production from rapid pyrolysis of cottonseed cake:Product yields and compositions [J].International Journal of Energy Research,2006,30(7):501-510.
[15] ÖZBAY N,UZUN B B,VAROL E A,et al.Comparative analysis of pyrolysis oils and its subfractions under different atmospheric conditions [J].Fuel Processing Technology,2006,87(11):1013-1019.
[16] ÖZBAY N,VAROL E A,UZUN B B,et al.Characterization of bio-oil obtained from fruit pulp pyrolysis [J].Energy,2008,33(8):1233-1240.
[17] UZUN B B,PVTVN A E,PVTVN E.Fast pyrolysis of soybean cake:Product yields and compositions [J].Bioresource Technology,2006,97(4):569-576.
[18] ONAY O,KOÇKAR O M.Fixed-bed pyrolysis of rapeseed (Brassica napus L.)[J].Biomass and Bioenergy,2004,26(3):289-299.
[19] AYSU T,KÜÇÜK M M.Biomass pyrolysis in a fixed-bed reactor:Effects of pyrolysis parameters on product yields and characterization of products [J].Energy,2014,64:1002-1025.
[20] WANG Shu-rong,WANG Kai-ge,LIU Qian,et al.Comparison of the pyrolysis behavior of lignins from different tree species [J].Biotechnology Advances,2009,27(5):562-567.

Yields and Compositions of Products by Pyrolysis of Yunnan Pine

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