生物质热解制生物油及其提质研究现状

doi:10.3969/j.issn.1673-5854.2018.05.010

Abstract

Abstract: As an important part of renewable energy, biomass energy shows strategic importance in the substitution and supplementation of energy and protection of environment. Biomass pyrolysis oil is the liquid product obtained by biomass pyrolysis and has the advantages of high energy density, environmental friendliness, renewable utilization and convenient transportation, making it possible for replacing fossil fuels and solving energy shortage and environmental pollution. The development and utilization of biomass pyrolysis oil technology has become one of the most important topics of sustainable energy research in this century. In this study, the main research of biomass pyrolysis oil production in recent years were reviewed, focusing on the improvement of pyrolysis reactor, catalytic pyrolysis and the upgrading of bio-oil. Three kinds of biomass pyrolysis catalysts including alkali metal, oxide and molecular sieve were introduced and five kinds of biomass upgrading methods including emulsification,catalytic hydrogenation,catalytic cracking,catalytic esterification and reforming hydrogen production were presented.The current status and development trend of biomass pyrolysis technology were summarized.

Key words: biomass, bio-oil, pyrolysis, reactor, upgrading, catalyze

CLC Number:

TK6
TQ35

NIU Miaomiao, YANG Jiayao, LI Shang, SUN Ke, CAO Jian, LI Xinyang. Review on Biomass Pyrolysis for Bio-oil and Upgrading Research[J]. bce, 2018, 52(5): 55-61.

References

[1] ZHANG Q,CHANG J,WANG T,et al. Review of biomass pyrolysis oil properties and upgrading research[J]. Energy Conversion and Management,2007,48(1):87-92.
[2] MOHAN D,PITTMAN C U,STEELE P H. Pyrolysis of wood/biomass for bio-oil:A critical review[J]. Energy & Fuels,2006,20(3):848-889.
[3] ARENA U. Process and technological aspects of municipal solid waste gasification:A review[J]. Waste Management,2012,32(4):625-639.
[4] ZHANG M,MOUTSOGLOU A. Catalytic fast pyrolysis of prairie cordgrass lignin and quantification of products by pyrolysis-gas chromatography-mass spectrometry[J]. Energy & Fuels,2014,28(2):1066-1073.
[5] GUEDES R E,LUNA A S,TORRES A R. Operating parameters for bio-oil production in biomass pyrolysis:A review[J]. Journal of Analytical and Applied Pyrolysis,2018,129:134-149.
[6] WANG S,DAI G,YANG H,et al. Lignocellulosic biomass pyrolysis mechanism:A state-of-the-art review[J]. Progress in Energy and Combustion Science,2017,62:33-86.
[7] 白斌,周卫红,丁毅飞,等. 纤维素热解动力学分析方法研究[J]. 生物质化学工程,2017,51(4):8-16.
[8] 顾洁,刘斌,张齐生,等. 油茶壳热解的TG-FT-IR分析及动力学研究[J]. 生物质化学工程,2015,49(4):7-13.
[9] MURILLO J,BIERNACKI J,NORTHRUP S,et al. Biomass pyrolysis kinetics:A review of molecular-scale modeling contributions[J]. Brazilian Journal of Chemical Engineering,2017,34(1):1-18.
[10] BRIDGWATER A,PEACOCKE G. Fast pyrolysis processes for biomass[J]. Renewable and Sustainable Energy Reviews,2000,4(1):1-73.
[11] 胡海涛,李允超,王贤华,等. 生物质预处理技术及其对热解产物的影响综述[J]. 生物质化学工程,2014,48(1):44-50.
[12] BRIDGWATER A,MEIER D,RADLEIN D. An overview of fast pyrolysis of biomass[J]. Organic Geochemistry,1999,30(12):1479-1493.
[13] BRIDGEWATER A V. Biomass fast pyrolysis[J]. Thermal Science,2004,8(2):21-50.
[14] OKEKE J. Pyrolysis of agricultural straw using high temperature steam[D]. Stockholm:Master Degree Thesis of KTH Royal Institute of Technology,2010.
[15] BRIDGWATER A. Fast pyrolysis of biomass for energy and fuels[M]//CROCKER M. Thermochemical Conversion of Biomass to Liquid Fuels and Chemicals.[S.l.]:Royal Society of Chemistry,2010:146-191.
[16] 戴先文,吴创之,周肇秋,等. 循环流化床反应器固体生物质的热解液化[J]. 太阳能学报,2001,22(2):124-130.
[17] 李睿. 生物质热解制备生物油及生物油品质评价研究[D]. 南京:东南大学博士学位论文,2012.
[18] 徐保江. 旋转锥式生物质热解系统及热载体动力学研究[J]. 上海理工大学学报,2000(1):16-20.
[19] ALONSO D M,BOND J Q,DUMESIC J A. Catalytic conversion of biomass to biofuels[J]. Green Chemistry,2010,12(9):1493-1513.
[20] LU K M,LEE W J,CHEN W H,et al. Thermogravimetric analysis and kinetics of co-pyrolysis of raw/torrefied wood and coal blends[J]. Applied Energy,2013,105:57-65.
[21] 张会岩. 生物质催化热解制备液体燃料和化学品的基础与工艺研究[D]. 南京:东南大学博士学位论文,2012.
[22] 李建芬. 生物质催化热解和气化的应用基础研究[D]. 武汉:华中科技大学博士学位论文,2007.
[23] 朱锡锋. 生物质热解液化技术研究与发展趋势[J]. 新能源进展,2013,1(1):32-37.
[24] KRERKKAIWAN S,FUSHIMI C,TSUTSUMI A,et al. Synergetic effect during co-pyrolysis/gasification of biomass and sub-bituminous coal[J]. Fuel Processing Technology,2013,115:11-18.
[25] LI S,CHEN X,LIU A,et al. Co-pyrolysis characteristic of biomass and bituminous coal[J]. Bioresource Technology,2015,179:414-420.
[26] 王震亚. 碱金属和碱土金属催化剂对白松裂解的影响[D]. 上海:华东理工大学硕士学位论文,2009.
[27] DEMIRBAŞ A. Partly chemical analysis of liquid fraction of flash pyrolysis products from biomass in the presence of sodium carbonate[J]. Energy Conversion and Management,2002,43(14):1801-1809.
[28] 蔡建军,王清成,王全. 碱金属离子对生物质的催化热解及气化实验研究[J]. 太阳能学报,2016,37(7):1631-1635.
[29] ZHOU L,YANG H,WU H,et al. Catalytic pyrolysis of rice husk by mixing with zinc oxide:Characterization of bio-oil and its rheological behavior[J]. Fuel Processing Technology,2013,106:385-391.
[30] STEFANIDIS S D,KARAKOULIA S A,KALOGIANNIS K G,et al. Natural magnesium oxide(MgO) catalysts:A cost-effective sustainable alternative to acid zeolites for the in situ upgrading of biomass fast pyrolysis oil[J]. Applied Catalysis B:Environmental,2016,196:155-173.
[31] VESES A,AZNAR M,MARTÍNEZ I,et al. Catalytic pyrolysis of wood biomass in an auger reactor using calcium-based catalysts[J]. Bioresource Technology,2014,162:250-258.
[32] FRENCH R,CZERNIK S. Catalytic pyrolysis of biomass for biofuels production[J]. Fuel Processing Technology,2010,91(1):25-32.
[33] ANTONAKOU E,LAPPAS A,NILSEN M H,et al. Evaluation of various types of Al-MCM-41 materials as catalysts in biomass pyrolysis for the production of bio-fuels and chemicals[J]. Fuel,2006,85(14/15):2202-2212.
[34] 张秀梅,陈冠益,孟祥梅,等. 催化热解生物质制取富氢气体的研究[J]. 燃料化学学报,2004,32(4):446-449.
[35] LIN B J,CHEN W H,BUDZIANOWSKI W M,et al. Emulsification analysis of bio-oil and diesel under various combinations of emulsifiers[J]. Applied Energy,2016,178:746-757.
[36] 阮仁祥. 生物油的精炼提质研究[D]. 合肥:中国科学技术大学硕士学位论文,2011.
[37] 徐国辉,王相宇,郭祚刚,等. 生物油/柴油乳化实验研究[J]. 能源工程,2012(4):36-39.
[38] 王振平. 生物质热解燃油/柴油乳化燃料理化分析和喷雾特性的实验研究[D]. 西安:长安大学硕士学位论文,2012.
[39] 王琦,李信宝,王树荣,等. 生物质热解生物油与柴油乳化的试验研究[J]. 太阳能学报,2010,31(3):380-384.
[40] 魏宏鸽,仲兆平. 生物油催化加氢提质的研究进展[J]. 能源研究与利用,2009(3):1-4.
[41] WANG Y,HE T,LIU K,et al. From biomass to advanced bio-fuel by catalytic pyrolysis/hydro-processing:Hydrodeoxygenation of bio-oil derived from biomass catalytic pyrolysis[J]. Bioresource Technology,2012,108:280-284.
[42] SHAFAGHAT H,REZAEI P S,DAUD W M A W. Catalytic hydrodeoxygenation of simulated phenolic bio-oil to cycloalkanes and aromatic hydrocarbons over bifunctional metal/acid catalysts of Ni/HBeta, Fe/HBeta and NiFe/HBeta[J]. Journal of Industrial and Engineering Chemistry,2016,35:268-276.
[43] 郭晓亚,颜涌捷,李庭琛,等. 生物质裂解油催化裂解精制[J]. 过程工程学报,2003,3(1):91-95.
[44] 俞宁,蔡忆昔,李小华,等. HZSM-5分子筛催化热裂解油菜秸秆制取精制生物油[J]. 农业工程学报,2014,30(15):264-271.
[45] KANAUJIA P K,SHARMA Y K,GARG M O,et al. Review of analytical strategies in the production and upgrading of bio-oils derived from lignocellulosic biomass[J]. Journal of Analytical and Applied Pyrolysis,2014,105:55-74.
[46] ZHANG X,WANG T,MA L,et al. Hydrotreatment of bio-oil over Ni-based catalyst[J]. Bioresource Technology,2013,127:306-311.
[47] 费雯婷,刘荣厚,周维奇,等. 生物油催化酯化及其存储稳定性研究[J]. 太阳能学报,2014,35(11):2177-2184.
[48] 王锦江,常杰,范娟. 离子交换树脂催化酯化生物油的试验研究[J]. 燃料化学学报,2010,38(5):560-564.
[49] 鲁俊祥,郭姝君,常杰,等. 轻馏分生物油催化酯化脱水提质研究[J]. 林产化学与工业,2016,36(3):60-66.
[50] 靳李富,胡建杭,罗凯,等. 铜渣催化生物油重整制氢的实验研究[C]//中国工程热物理学会论文,2015.
[51] 张志凯,周慧珍,李晓阳,等. Co-La-Ni/Al₂O₃催化甘油水蒸气重整制氢[J]. 石油化工,2015,44(6):689-694.

Review on Biomass Pyrolysis for Bio-oil and Upgrading Research

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