生物质合成气催化甲烷化技术研究进展

doi:10.3969/j.issn.1673-5854.2019.05.009

Abstract

Abstract:

Natural gas is becoming more and more advantageous than other kinds of fossil energy because it is clean, efficient and convenient to use. With the increasing demand of natural gas, the conflict between supply and demand of natural gas has gradually become increasingly prominent. The catalytic synthesis of synthetic natural gas from biomass synthesis gas has become one of the major technologies to solve the conflict.In allusion to the methanation of biomass synthesis gas, the research status of biomass synthesis gas methanation was explained from the aspects such as reaction process, catalyst and the reactor. Through comparing with the catalytic performance of different catalysts, it was analyzed that Ni-based catalyst was the most suitable for methanation catalyst for industrialization. Some cases of fixed and fluidized bed industrialization from abroad were showed and analyzed their production processes, advantages and disadvantages, it proved that the fluidized bed was very promising in the methanation reactor. Finally, the orientation of developing of biosynthesis gas catalytic synthesis of synthetic natural gas technology was outlooked.

Key words: synthetic natural gas, reactor, catalyst

CLC Number:

TQ35

Hang YIN,Wei XU,Yunjuan SUN,Yu XU,Hao YING,Siyun NING. Research Advances in Catalytic Methanation of Bio-syngas[J]. Biomass Chemical Engineering, 2019, 53(5): 49-56.

Figures/Tables 5

Table 1

Table 2

Fig.1

Fig.2

Fig.3

References 64

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催化剂 catalyst	制备方法 preparation method	活性组分/% active component	温度/℃ temperature	压力/MPa pressure	CO转化率/% CO conversion	CH₄选择率/% CH₄ selectivity	测试时长/h stability test time	参考文献 reference
Ni- α-Al₂O₃	I	10	450	0.1	96.0	90.0	50	[12]
Ni-Al₂O₃	CP	15	400	0.1	98.2	84.7	120	[13]
Ni/MCM-41	HT	10	350	0.1	97.9	88.2	100	[14]
Ni/MWNTs	I	13	350	0.1	95.0	85.0	240	[15]
Ni-membrane	I	99.9	350	0.2	95.0	96.0	—	[16]
Ni-SBA-15	pH	3.6	350	0.3	100.0	98.6	100	[17]
Ni/CeO₂-Al₂O₃	I	10	350	—	—	80.0	—	[5]
Ni-Fe/Al₂O₃	I	15	262	0.1	95.0	90.0	24	[18]
Ni-SBA-16-NH₂	I	10	350	0.3	100.0	99.9	100	[19]
Ni-AlOOH-Al₂O₃	I	28	550	0.3	98.0	92.0	—	[20]
Co₃O₄	CP	—	300	2.0	100.0	—	—	[21]
Ru/ABC	I	0.3	350	—	97.0	92.0	—	[3]
Si-Ni/SiO₂	SI	20	350	0.1	70.0	60.0	42	[22]

催化剂 catalyst	制备方法¹⁾ preparation method	活性组分/% active component	温度/℃ temperature	压力/MPa pressure	CO₂转化率/% CO₂ conversion	CH₄选择率/% CH₄ selectivity	测试时长/h stability test time	参考文献 reference
Ni/MCM-41	HT	10	400	0.1	56.5	96.0	—	[23]
Ni-CeO₂	I	5	300	0.1	55.0	100.0	—	[24]
Ni/ γ-Al₂O₃	I	3	350	0.1	83.6	100.0	10	[25]
Ni/MSN	I	15	300	0.1	64.1	99.9	200	[26]
Ni-TiO₂	CP	5	218	0.1	96.0	99.0	—	[27]
Ni/CeO₂-ZrO₃	SG	20	350	0.1	79.7	97.3	90	[28]
Co/KIT-6	I	0.8	260	0.1	48.9	100.0	—	[29]
Ru-TiO₂	BS	20	180	0.1	—	100.0	170	[30]
Ru/ γ-Al₂O₃	I	3	350	0.1	85.0	85.0	2	[31]

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Research Advances in Catalytic Methanation of Bio-syngas

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