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生物质化学工程 ›› 2013, Vol. 47 ›› Issue (2): 19-22.doi: 10.3969/j.issn.1673-5854.2013.02.005

• 研究报告 • 上一篇    下一篇

山楂核制备活性炭工艺的优化

龚建平, 陈超, 戴伟娣, 张燕萍, 邓先伦   

  1. 中国林业科学研究院 林产化学工业研究所;生物质化学利用国家工程实验室;国家林业局 林产化学工程重点开放性实验室;江苏省生物质能源与材料重点实验室, 江苏 南京 210042
  • 收稿日期:2012-09-25 修回日期:1900-01-01 出版日期:2013-03-30 发布日期:2013-03-30
  • 通讯作者: 邓先伦(1956-),男,四川成都人,研究员,硕士生导师;从事活性炭研究与开发;E-mail:dengxianlun_483@163.com。

Technology Optimization of Preparing Activated Carbon from Hawthorn Kernel

GONG Jian-ping, CHEN Chao, DAI Wei-di, ZHANG Yan-ping, DENG Xian-lun   

  1. Institute of Chemical Industry of Forest Products, CAF; National Engineering Lab. for Biomass Chemical Utilization;Key and Open Lab. of Forest Chemical Engineering, SAF; Key Lab. of Biomass Energy and Materials, Jiangsu Province, Nanjing 210042, China
  • Received:2012-09-25 Revised:1900-01-01 Online:2013-03-30 Published:2013-03-30

摘要: 利用废弃的山楂核为原料生产木质颗粒活性炭,并对活性炭生产过程中炭化、活化及精制步骤的工艺条件进行了优化。实验结果表明在炭化过程中,采用2 h内缓慢升温至300 ℃,并维持1 h,而后在3 h内升温至600 ℃的炭化方式有利于保证炭化料的得率和强度;活化温度900~950 ℃,活化时间6 h为宜;精制过程中盐酸用量是炭质量的10%为宜。在优化条件下经过炭化和活化制成的活性炭碘值可达1 100 mg/g,亚甲基蓝吸附值可达180 mg/g,强度可达94%,能够满足一般用户的需求。产品通过酸洗和漂洗之后可使铁盐的含量由0.25%降至0.02%,灰分由6%降至2%。

关键词: 山楂核, 活性炭, 炭化, 活化, 精制

Abstract: Abandoned hawthorn kernel was utilized for producing woody activated carbon in this work. The process conditions, including carbonization, activation and refine, were optimized. Results showed that, the condition,i.e., heating to 300 ℃ in 2 h, temperature kept for 1 h, and then heating to 600 ℃ in 3 h, was beneficial for ensuring the yield rate and strength of the carbonized material during carbonization process. The suitable carbonization condition was heated at 900-950 ℃ for 6h, and HCl amount was controlled at 10 % of the carbon during refining process. The activated carbon produced through carbonization and activation processes under the optimal condition had adsorption capacity of 1 100 mg/g for iodine, 180mg/g for methyl blue (MB), and strength 94%. It is able to meet the demand of general customers. Iron content decreased dramatically from 0.25% to 0.02% and ash content declined from 6% to 2% after washing with acid and water.

Key words: hawthorn kernel, activated carbon, carbonization, activation, refine

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