气相色谱法测定萜烯树脂中有机溶剂残留量的研究与应用

生物质化学工程 ›› 2012, Vol. 46 ›› Issue (5): 7-11.

气相色谱法测定萜烯树脂中有机溶剂残留量的研究与应用

王婧¹, 赵振东^1,2, 李冬梅^1,2, 卢言菊¹, 陈玉湘^1,2, 毕良武^1,2

1. 中国林业科学研究院林产化学工业研究所;生物质化学利用国家工程实验室;国家林业局林产化学工程重点开放性实验室;江苏省生物质能源与材料重点实验室, 江苏南京 210042;2. 中国林业科学研究院林业新技术研究所, 北京 100091

收稿日期:2012-05-25 修回日期:1900-01-01 出版日期:2012-09-30 发布日期:2012-09-30
通讯作者: 赵振东,男,研究员,博士生导师,主要从事萜类化学、天然产物化学、应用化学等方面的研究与利用;E-mail:zdzhao@189.cn。

Determination of Organic Solvents Remained in Terpene Resin with Gas Chromatography and Its Application

WANG Jing¹, ZHAO Zhen-dong^1,2, LI Dong-mei^1,2, LU Yan-ju¹, CHEN Yu-xiang^1,2, BI Liang-wu^1,2

1. Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab.for Biomass Chemical Utilization; Key and Open Lab.of Forest Chemical Engineering, SFA;Key Lab.of Biomass Energy and Material, Jaingsu Province, Nanjing 210042, China;2. Institute of New Technology of Forestry, CAF, Beijing 100091, China

Received:2012-05-25 Revised:1900-01-01 Online:2012-09-30 Published:2012-09-30

摘要/Abstract

摘要： 研究了气相色谱法用于测定萜烯树脂中的有机溶剂残留量的技术,从标准工作曲线绘制、最低检出限、精密度、重复性、回收率等方面验证了方法的可行性,并进行了实际应用效果考察。结果表明,毛细管气相色谱法在测定树脂产品中的甲苯、1,2-二氯乙烷、苯等有机溶剂含量时,甲苯的最低检出限为 0.2 mg/L、1,2-二氯乙烷的最低检出限为 1.7 mg/L、苯的最低检出限为 0.3 mg/L。测定甲苯时的精密度标准偏差为0.04;平均回收率为 104.1%,标准偏差为1.99。该方法应用于测定自制的萜烯树脂样品时,未检测到产品中有苯和1,2-二氯乙烷残留,测得甲苯溶剂的残留量小于 25 mg/kg。

关键词: 萜烯树脂, 有机溶剂残留, 气相色谱法

Abstract: The determination technique and method of organic solvents remained in terpene resin was studied by gas chromatography. According to drawing standard curve, testing the precision and repeatability, calculating the lowest detection limit and determining recovery ratio, its feasibility was confirmed. Its practical application effect was further investigated. The results indicated that, the lowest detection limits determined by capillary gas chromatography for toluene, 1,2-dichlorethane and benzene were 0.2 mg/L, 1.7 mg/L, and 0.3 mg/L, respectively. For toluene determination, the standard deviation of determining precision is 0.04; recovery ratio and its standard deviation are 104.1% and 1.99, respectively. While applying the method to determine samples of terpene resin prepared in laboratory, it showed that there was only toluene as organic solvent in the resins and its residual contents was less than 25 mg/kg. No benzene and 1,2-dichloroethane were indicated in the resins.

Key words: terpene resin, organic solvent residue, gas chromatography

中图分类号:

TQ35

王婧;赵振东;李冬梅;卢言菊;陈玉湘;毕良武;. 气相色谱法测定萜烯树脂中有机溶剂残留量的研究与应用[J]. 生物质化学工程, 2012, 46(5): 7-11.

WANG Jing;ZHAO Zhen-dong;LI Dong-mei;LU Yan-ju;CHEN Yu-xiang;BI Liang-wu;. Determination of Organic Solvents Remained in Terpene Resin with Gas Chromatography and Its Application[J]. , 2012, 46(5): 7-11.

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