橡胶籽油基多元醇的制备与表征

doi:10.3969/j.issn.1673-5854.2017.03.004

Abstract

Abstract: Rubber seed oil based polyol was prepared by using epoxidized rubber seed oil(ERSO) as raw materials,methanol and isopropanol as ring-opening reagents,and fluoboric acid as catalyst,the preparation conditions were investigated with the hydroxyl value of product as index,and the characterization of product was also studied. The results showed that the optimum reaction conditions were reaction time 30min,reaction temperature 70℃,the mass ratio of to alcohol to ERSO 4:1,the amount of fluoboric acid 1%(based on the mass of ERSO),the mass ratio of isopropanol to methanol 1:1. The results of verification experiment showed that the acid value,hydroxyl value,average molecular weight,moisture content and viscosity of rubber seed oil based polyol prepared under the optimum reaction conditions were 2.68mg/g,219.32mg/g,870.21,0.08% and 4791mPa·s,respectively. Furthermore,the chemical structure of rubber seed oil based polyol was characterized by FT-IR,¹H NMR and ¹³C NMR,the results showed that the polyol was formed by the ring-opening reaction of epoxy group of ERSO.

Key words: rubber seed oil based polyol, epoxidation-hydroxylation method, epoxidized rubber seed oil

CLC Number:

TQ35

HUANG Yuanbo, ZHENG Zhifeng, MA Huan, ZHENG Yunwu, LIU Can, GONG Huiying, YANG Xiaoqin. Preparation and Characterization of Rubber Seed Oil Based Polyol[J]. bce, 2017, 51(3): 21-26.

References

[1] 郑云武,黄元波,郑志锋,等. 正交试验法优化橡胶籽油的提取工艺[J]. 生物质化学工程,2012,46(2):21-24.
[2] 陈茜文. 橡胶籽的化学成分与综合利用初探[J]. 中南林学院学报,1999,19(4):58-60.
[3] 王小李,詹琳. 橡胶籽油的精炼研究[J]. 中国油脂,2000,25(4):10-11.
[4] 李雪梅,刘守庆,徐娟,等. 硫酸催化制备橡胶籽油生物柴油工艺及脱色研究[J]. 中国油脂,2013,38(5):56-59.
[5] 秦岩,姚志龙,宋昭峥,等. 环保增塑剂环氧脂肪酸甲酯催化合成工艺优化[J]. 工业催化,2013,21(3):50-55.
[6] 潘梅娟,王晓辉,姚成. 植物油基多元醇的合成及其应用[J]. 现代化工,2007,27(增刊2):521-524.
[7] PETROVIC Z S. Polyurethanes from vegetable oils[J]. Polymer Reviews,2008,48(1):109-155.
[8] LU Y S,LAROCK R C. New hybrid latexes from a soybean oil-based waterborne polyurethane and acrylics via emulsion polymerization[J]. Biomacromolecules,2007,24(8):3108-3114.
[9] LU Y S,LAROCK R C. Soybean oil-based,aqueous ealionic polyurethane dispersions:Synthesis and properties[J]. Progress in Organic Coatings,2010,69(8):31-37.
[10] 饶舟,李俊梅,夏会华,等. 环氧大豆油改性水性聚氨酯的制备及性能表征[J]. 化工新型材料,2013,41(8):136-138.
[11] BIERMANN U,BORNSCHEUER U,MEIER M A R,et al. Oils and fats as renewable raw materials in chemistry[J]. Angewandte Chemie International Edition,2011,50(17):3854-3871.
[12] ALAGI P,YE J C,HONG S C. Preparation of vegetable oil-based polyols with controlled hydroxyl functionalities for thermoplastic polyurethane[J]. European Polymer Journal,2016,78:46-60.
[13] LI J,ZHU M. Structural characterization of a vegetable oil-based polyol through liquid chromatography multistage mass spectrometry[J]. Journal of Polymer Science Part A:Polymer Chemistry,2016,55(2). DOI:10.1002/pola.28371
[14] ALAGI P,HONG S C. Vegetable oil-based polyols for sustainable polyurethanes[J]. Macromolecular Research,2015,23(12):1079-1086.
[15] BAUMANN H,BVHLER M,FOCHEM H,et al. Natural fats and oils:Renewable raw materials for the chemical industry[J]. Angewandte Chemie International Edition,1988,27(1):41-62.
[16] CARLSSON A S,YILMAZ J L,GREEN A G,et al. Replacing fossil oil with fresh oil:With what and for what?[J]. European Journal of Lipid Science & Technology,2011,113(7):812-831.
[17] HILL K. Fats and oils as oleochemical raw materials[J]. Pure and Applied Chemistry,2000,72(7):1255-1264.
[18] ULBER R,SELL D,HIRTH T. Renewable Raw Materials:New Feedstock for the Chemical Industry[M]. Chichester:John Wiley & Sons Ltd.,UK,2011.
[19] NI B,YANG L,WANG C,et al. Synthesis and thermal properties of soybean oil-based waterborne polyurethane coatings[J]. Journal of Thermal Analysis and Calorimetry,2010,100(7):239-246.
[20] LIN B,YANG L,DAI H,et al. Thermal analysis of soybean oil based polyols[J]. Journal of Thermal Analysis and Calorimetry,2009,95(3):977-983.
[21] BAKHSHI H,YEGANEH H,MEHDIPOUR ATAEI S,et al. Synthesis and characterization of antibacterial polyurethane coatings from quaternary ammonium salts functionalized soybean oil based polyols[J]. Materials Science and Engineering,2013,42(33):153-164.
[22] KONG X,LIU G,CURTIS J M. Novel polyurethane produced from canola oil based poly(ether ester) polyols:Synthesis,characterization and properties[J]. European Polymer Journal,2012,48(12):2097-2106.
[23] 黄元波. 橡胶籽油的环氧化与羟基化及其应用研究[D]. 哈尔滨:东北林业大学博士学位论文,2016.
[24] 龚慧颖,郑志锋,黄元波,等. Ti-SBA-15介孔分子筛催化制备环氧橡胶籽油的研究[J]. 生物质化学工程,2016,50(2):1-5.

Preparation and Characterization of Rubber Seed Oil Based Polyol

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Xiaopeng JIAN,Wei XU,Xinglong HOU,Shicai LIU. Research Progress on Activated Carbon Modification Technology [J]. Biomass Chemical Engineering, 2020, 54(5): 66-72.
[2]	Xue LIU,Shujun LI,Shouxin LIU,Jian LI,Zhijun CHEN. Research Progress in Preparation and Functional Application of Lignin-based Nanoparticles [J]. Biomass Chemical Engineering, 2020, 54(5): 53-65.
[3]	Weixing ZENG,Xian CHENG,Zuohui ZHANG,Liangwu BI,Zhendong ZHAO. Application Research Progress of Biological Pretreatment Technology in Extraction of Natural Products [J]. Biomass Chemical Engineering, 2020, 54(5): 45-52.
[4]	Xiaomeng QU,Ge YANG,Zehao ZHANG,Lan ZHANG. Preparation of High Purity Yacon Fructo-oligosaccharides by Nanofiltration and Its Characterization [J]. Biomass Chemical Engineering, 2020, 54(5): 37-44.
[5]	Guoqiang SONG,Huan LI,Yinmei CAO,Long TANG. Industrial Refining Process of MES Surfactant [J]. Biomass Chemical Engineering, 2020, 54(5): 33-36.
[6]	Mengmeng WANG,Lequn LIU,Zhentao LIU,Ying ZHAO. Flame Retardant Modification of Bamboo Liquefied Wall Foam Materials [J]. Biomass Chemical Engineering, 2020, 54(5): 25-32.
[7]	Peng LYU,Guanghui WANG,Bing WANG,Deyu HU. Effect of Pyrolysis Temperature and Biomass Type on Adsorption of U(Ⅵ) by Biochar [J]. Biomass Chemical Engineering, 2020, 54(5): 15-24.
[8]	Chunpo YUE,Zhiling YU,Qianhui YU,Tao WANG,Pengbo WANG,Mingwei DI. Effect of Jet Plasma Discharge in Different Atmosphere on Surface Properties of Wood-plastic Composites [J]. Biomass Chemical Engineering, 2020, 54(5): 8-14.
[9]	Zhaolan ZHAI,Pu LYU,Ping ZHAO,Zhanqian SONG,Shibin SHANG,Xiaoping RAO. Antibacterial Activity of Dehydroabietyl Nitrogen Derivatives [J]. Biomass Chemical Engineering, 2020, 54(5): 1-7.
[10]	Qiqi DAI,Xiaocui WEI,Hongbiao TANG,Jin LI,Jinjing WANG. Optimization of Microwave Assisted Pyrolysis of Coconut Clothes by Response Surface Method and Analysis of Liquid Product Composition [J]. Biomass Chemical Engineering, 2020, 54(4): 42-48.
[11]	Lin SUN,Huayu LIU,Kun LIU,Xiaoyi ZHANG,Hongxiang XIE,Rui ZHANG,Haiming LI,Chuanling SI. Research Progress in Nanocellulose Hydrophobic Modification and Applications [J]. Biomass Chemical Engineering, 2020, 54(4): 57-66.
[12]	Weijiao SHANG,Lu WANG. Status and Analysis of Nanocellulose Technology Based on Patents [J]. Biomass Chemical Engineering, 2020, 54(4): 49-56.
[13]	Ruting XU,Wei XU,Xincheng LU,Kang SUN. Novel Demineralization Technology of Phosphate-activated Carbon [J]. Biomass Chemical Engineering, 2020, 54(4): 37-41.
[14]	Yongxu LIU,Dawei ZHANG. Preparation and Properties of Bacteriostatic Chitosan/PVA/Chitosan Oligosaccharide Nanofibrous Membranes [J]. Biomass Chemical Engineering, 2020, 54(4): 30-36.
[15]	Feifei LIU,Lan WANG,Zuohu LI,Hongzhang CHEN. Dissolving Effect of Steam Exploded Corn Stalk on Phosphate Rock Powder and Influence of Its Residual on Wheat Growth [J]. Biomass Chemical Engineering, 2020, 54(4): 23-29.