竹材催化转化制备5-羟甲基糠醛的研究进展

doi:10.3969/j.issn.1673-5854.2023.01.009

Abstract

Abstract:

5-Hydroxymethyl furfural(HMF) was a kind of important platform chemical compound, which was a precursor for producing liquid biofuel and many other important fine chemicals. The synthesis of HMF from biomass was one of the hot topics in the comprehensive utilization of biomass resources. Bamboo has the advantages of fast growth, short mature period, high yield and continuous use for years after once planting, and it contains a mass of cellulose. Glucose could be obtained from hydrolysis of the nature abundant cellulose, and HMF could be prepared by dehydration of glucose. Therefore, the catalytic conversion of bamboo to produce HMF had the advantages of abundant raw materials resources and green feasible technical route. In order to realize the efficient conversion of bamboo to HMF, the design and selection of catalytic system were the key factors. In this paper, the research on the preparation of HMF by catalytic conversion of bamboo in recent years was reviewed. Starting from the composition and characteristics of bamboo raw materials, the chemical composition and microstructure of bamboo were analyzed firstly, and then, the catalytic conversion mechanism was further elaborated. In particular, the influence mechanism on the preparation of HMF from bamboo by homogeneous catalyst, heterogeneous catalyst and other catalysts was analyzed in detail. The choice of solvent system was also discussed. Finally, combined with the development trend, the future development direction of its technology was proposed, which provided constructive suggestions for the development and industrial application of bamboo-based HMF technology.

Key words: bamboo, cellulose, 5-hydroxymethyl furfural(HMF), catalytic conversion, catalysts

CLC Number:

TQ35

Meixin WANG, Yawei ZHAN, Tengfei MA, Zhiqiang LI. Catalytic Conversion of Bamboo for 5-Hydroxymethyl Furfural Production: A Review[J]. Biomass Chemical Engineering, 2023, 57(1): 73-83.

Figures/Tables 5

Table 1

Fig.1

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种类 species	纤维素/% cellulose	半纤维素/% hemicellulose	木质素/% lignin	灰分/% ash	参考文献 reference
毛竹Phyllostachys pubescens	48.96	14.52	23.91	1.29	[11]
黄竹Dendrocalamus membranaceus Munro	52.02	18.66	21.85	2.82	[11]
撑绿竹Bambusa pervariabilis×Dendrocalamposis daii Keng f.	45.85	20.08	23.75	2.61	[11]
绵竹Bambusa intermedia Hsueh et Yi.	53.12	19.56	25.23	2.54	[11]
巨竹Gigantochloa levis(Bles) Merr	48.97	20.27	22.73	3.24	[12]
马甲竹Bambusa tulda Roxb	48.53	22.91	23.05	1.38	[13]
硬头黄竹Bambusa rigida Keng et Keng f.	48.62	23.75	23.15	1.31	[13]
梁山慈竹Dendrocalamus farinosus	46.64	21.68	20.28	3.00	[13]
粉单竹Bambusa chungii McClure	48.46	20.82	22.36	1.31	[14]

催化剂类型 type of catalyst	催化剂 catalyst	竹材 bamboo	反应条件 reaction condition	溶剂 solvent	HMF得率/% yield of HMF	参考文献 reference
均相催化剂 homogeneous catalyst	盐酸HCl	金镶玉竹 Phyllostachys aureosulcata	177 ℃，60 min	水/甲基异丁基酮 H₂O/MIBK	42.4	[40]
	四氯化锡SnCl₄	竹bamboo	200 ℃，120 min	水/环丁砜 H₂O/sulfolane	41.2	[41]
	水合氯化铁FeCl₄	笋壳 bamboo shoot shell	89.56 ℃，420 min	1-丁基-3-甲基咪唑盐 [C₄MIM]	35.9	[42]
	氯化铬CrCl₃	竹bamboo	160 ℃，180 min	1-烯丙基-3-甲基咪唑醋酸盐 [AMIM]OAc	56.8	[43]
非均相催化剂 heterogeneous catalyst	氢型丝光沸石 H-MOR	竹bamboo	180 ℃，120 min	水/甲基异丁基酮 H₂O/MIBK	21.0	[34]
非均相催化剂 heterogeneous catalyst	氨基磺酸 NH₂SO₃H	慈竹 Neosinocalamus affinis	180 ℃，40 min	水/四氢呋喃 H₂O/THF	52.2	[44]

原料 material	固体酸催化剂 solid acid catalyst	反应条件 reaction condition	HMF得率/% yield of HMF	参考文献 reference
竹材bamboo	氢型丝光沸石H-MOR	180 ℃，120 min	21	[34]
竹纤维bamboo fiber	氨基磺酸NH₂SO₃H	180 ℃，40 min	52.2	[44]
纤维素cellulose	H型β-分子筛Hβ-zeolite	150 ℃，50 min	46.5	[51]
菊粉inulin	商业酸性树脂Amberlyst A-70	180 ℃，20 min	43	[52]
菊粉inulin	氧化石墨烯GO	120 ℃，100 min	61.2	[53]
纤维素cellulose	磷酸铪基催化剂HfO(PO₄)_2.0	190 ℃，240 min	69.8	[54]
纤维素cellulose	磷酸铁FePO₄	160 ℃，80 min	40	[55]
微晶纤维素microcrystalline cellulose	交联二氧化钛的磺酸树脂微球SMF-TiO₂	180 ℃，240 min	21	[56]
淀粉starch	具有β分子筛拓扑结构含锡分子筛Sn-β	180 ℃，100 min	52	[57]
玉米茎corn stalk	碳质固体酸催化剂HCSS	150 ℃，30 min	44.1	[58]

原料 material	溶剂体系 solvent system	反应条件 reaction condition	HMF得率/% yield of HMF	参考文献 reference
毛竹Phyllostachys pubescens	水/甲基异丁基酮H₂O/MIBK	177 ℃，60 min	42.4	[40]
慈竹Neosinocalamus affinis	水/氯化钠/氨基磺酸/四氢呋喃 H₂O/NaCl/NH₂SO₃H/THF	180 ℃，40 min	52.2	[44]
稻草rice straw	水/甲基异丁基酮H₂O/MIBK	150 ℃，60 min	41	[63]
纤维素cellulose	水/氯化钠/三氯化铟/四氢呋喃 H₂O/NaCl/InCl₃/THF	200 ℃，120 min	39.7	[64]
微晶纤维素 microcrystalline cellulose	盐酸/氯化锌/甲基异丁基酮 HCl/ZnCl₂/MIBK	150 ℃，40 min	81	[65]
微晶纤维素 microcrystalline cellulose	水/氯化钠/三氯化钌/丁醇 H₂O/NaCl/RuCl₃/butanol	220 ℃，30 min	83.3	[66]
微晶纤维素 microcrystalline cellulose	吡咯烷酮类双酸性离子液体[Hnmp]Zn₂Cl₅	130 ℃，360 min	39.29	[67]
淀粉starch	水/氯化钠/氯化铝/四氢呋喃H₂O/NaCl/AlCl₃/THF	160 ℃，10 min	50	[68]
玉米芯corncob	氯化胆碱/水/丙酮ChCl/H₂O/acetone	190 ℃，10 min	64.21	[69]
玉米芯corncob	1-甲基3-正辛基咪唑六氟磷酸盐[MOMIM][PF6]	200 ℃，50 min	66.6	[70]
玉米秸秆corn stover	1-丁基-3-甲基咪唑氯化物/二甲基亚砜 [Bmim]Cl/DMSO	150 ℃，80 min	53.3	[71]
菊粉inulin	低共熔溶剂/乙腈DES/MeCN	100 ℃，240 min	61.5	[72]
菊粉inulin	二氧化碳-水-异丙醇CO₂-H₂O-isopropanol	190 ℃，150 min	46.65	[73]
蔗糖sucrose	二氧化碳-水-异丙醇CO₂-H₂O-isopropanol	200 ℃，150 min	50.52	[74]
甲壳素chitin	二甲基亚砜/水DMSO/H₂O	180 ℃，360 min	33.9	[75]
棕榈叶、松子壳 carnauba leaves, pine nut shell	离子液体/环丁砜ionic liquid/sulfolane	140 ℃，30 min	53.24	[76]

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Catalytic Conversion of Bamboo for 5-Hydroxymethyl Furfural Production: A Review

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