剑麻纤维增强热塑性淀粉复合材料的制备及性能研究

doi:10.3969/j.issn.1673-5854.2015.06.001

生物质化学工程 ›› 2015, Vol. 49 ›› Issue (6): 1-5.doi: 10.3969/j.issn.1673-5854.2015.06.001

• 研究报告 • 下一篇

剑麻纤维增强热塑性淀粉复合材料的制备及性能研究

张传伟¹, 李方义¹, 刘鹏¹, 王成钊¹, 李剑峰¹, 郭安福²

1. 山东大学机械工程学院 & 高效洁净机械制造教育部重点实验室, 山东济南 250061;
2. 聊城大学机械与汽车工程学院, 山东聊城 252000

收稿日期:2015-06-30 出版日期:2015-11-30 发布日期:2016-03-17
通讯作者: 李方义,教授,博士生导师,主要从事生物质缓冲包装制品的研究;E-mail:lifangyi2006@qq.com。 E-mail:lifangyi2006@qq.com
作者简介:张传伟(1990-),男,山东济宁人,硕士,主要从事生物质复合材料的研究工作
基金资助:
国家自然科学基金资助项目(51275278);山东大学大学生科技创新基金(201510422042)

Preparation and Properties of Thermopalstic Starch Composites Reinforced with Sisal Fiber

ZHANG Chuan-wei¹, LI Fang-yi¹, LIU Peng¹, WANG Cheng-zhao¹, LI Jian-feng¹, GUO An-fu²

1. School of Mechanical Engineering & Key Laboratory of High Efficiency and Clean Mechanical Manufacture(Ministry of Education), Shandong University, Jinan 250061, China;
2. College of Mechanical & Automobile Engineering, Liaocheng University, Liaocheng 252000, China

Received:2015-06-30 Online:2015-11-30 Published:2016-03-17

摘要/Abstract

摘要： 为研究剑麻纤维增强的热塑性淀粉复合材料的制备工艺及热稳定性,以玉米淀粉为原料,先制得热塑性淀粉,再以剑麻纤维为骨架增强体制备剑麻纤维增强热塑性淀粉复合材料,通过正交试验优化制备工艺,DSC、TG/DTG、SEM分析其热稳定性及结构。正交试验表明,各因素对材料抗拉强度影响的主次顺序为纤维长度 >纤维用量 >模压成型温度 >填料用量;最佳工艺条件为纤维长度15mm、纤维用量35g、模压成型温度200℃、填料用量5g,此时材料的抗拉强度可达到4.45MPa。利用差示扫描量热分析和热重分析分别对热塑性淀粉及剑麻纤维复合材料的热稳定性进行了分析,结果表明,热塑处理提高了淀粉的熔融温度,有利于淀粉与纤维素羟基间的氢键结合,且热塑过程在一定程度上降低了淀粉的热稳定性;剑麻纤维复合材料的热降解过程主要发生在200~400℃温度区间。SEM分析显示最佳工艺条件下得到的复合材料具有较好的泡孔结构。

关键词: 剑麻纤维, 热塑性淀粉复合材料, 热稳定性, 微观形貌

Abstract: In order to further research composition process and the thermal stability of thermoplastic starch composites reinforced with plant fiber, the composites were prepared by reinforcing the thermoplastic starch obtained from corn starch with sisal fiber as skeleton reinforcing agent. The orthogonal test was designed to optimize the preparation process. DSC, TG/DTG and SEM were used to analyze the thermal stability and the structure of the composites. The results showed that the order of the influences of various factors on the tensile strength of the material was fiber length >fiber content >molding temperature >filler content. And the tensile strength of the material was 4.45MPa, when the fiber length was 15mm, the fiber content was 35g, the molding temperature was 200℃ and the filler content was 5g.The thermal stabilities of thermoplastic starch and sisal fiber composite were analyzed. The results showed that the thermoplastic treatment could increase the melting temperature of starch, benefit for the hydrogen-bonding between starch and the hydroxy of cellulose, and decrease the thermal stability of starch. The thermal degradation process of sisal fiber composites mainly occured in the temperature range 200-400℃. SEM images showed that the composites possessed great foam structure under the optimistic process conditions.

Key words: sisal fiber, thermoplastic starch composites, thermal stability, micro-morphology

中图分类号:

TQ35
TB34

张传伟, 李方义, 刘鹏, 王成钊, 李剑峰, 郭安福. 剑麻纤维增强热塑性淀粉复合材料的制备及性能研究[J]. 生物质化学工程, 2015, 49(6): 1-5.

ZHANG Chuan-wei, LI Fang-yi, LIU Peng, WANG Cheng-zhao, LI Jian-feng, GUO An-fu. Preparation and Properties of Thermopalstic Starch Composites Reinforced with Sisal Fiber[J]. bce, 2015, 49(6): 1-5.

参考文献

[1] IMAM S H,CINELLI P,GORDON S H,et al.Characterization of biodegradable composite films prepared from blends of poly(vinyl alcohol),cornstarch,and lignocellulosic fiber[J].Journal of Polymers and the Environment,2005,13(1):47-55.
[2] CINELLI P,CHIELLINI E,LAWTON J W,et al.Properties of injection molded composites containing corn fiber and poly(vinyl alcohol)[J].Journal of Polymers Research,2006,13(2):107-113.
[3] 李刚,李方义,管凯凯,等.生物质缓冲包装材料制备及性能实验研究[J].功能材料,2013,44(13):1969-1973.
[4] LIU Peng,LI Fang-yi,LI Jian-feng,et al.Effect of starch plasticizing fiber processing on the mechanical properties of biomass cushion packaging composites[J].Journal of Biobased Materials and Bioenergy,2014,8(2):214-220.
[5] LI Fang-yi,GUAN Kai-kai,LIU Peng,et al.Ingredient of biomass packaging material and compare study on cushion properties[J].International Journal of Polymer Science,2014,14(45):140-149.
[6] LIU Peng,LI Fang-yi,LI Jian-feng,et al.The micro-mechanism and mechanical properties of the thermoplastic starch compositess reinforced with plant fiber[J].Journal of Functional Materials,2015,46(9):2001-2005.
[7] 冯昊,王丽娟.亚麻的加工利用技术[M].北京:科学出版社,2010.
[8] 徐丽珊,张萍华.松针多糖的提取工艺优化[J].林产化学与工业,2009,29(4):73-76.
[9] LIAO Rui-jin,GONG Jing,SANG Fu-min,et al.Experimental study on the ageing of transformer oil-immersed paper using TGA and DSC[J].High Voltage Engineering,201036(3):572-577.
[10] 邸明伟,高振华.生物质材料现代分析技术[M].北京:化学工业出版社,2010.
[11] LIU Peng,LI Fang-yi,LI Jian-feng,et al.Thermoplastic starch matrix plasticized by single/compound plasticizer in starch-based composites[J].Journal of Functional Materials,2014,14(45):14140-14149.

剑麻纤维增强热塑性淀粉复合材料的制备及性能研究

Preparation and Properties of Thermopalstic Starch Composites Reinforced with Sisal Fiber

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