纳米微晶纤维素热稳定性的研究进展

doi:10.3969/j.issn.1673-5854.2014.05.009

生物质化学工程 ›› 2014, Vol. 48 ›› Issue (5): 47-51.doi: 10.3969/j.issn.1673-5854.2014.05.009

纳米微晶纤维素热稳定性的研究进展

王钱钱^1,2,3, 朱倩倩¹, 孙建中¹, 许家兴²

1. 江苏大学环境与安全工程学院; 生物质能源研究所, 江苏镇江 212013;
2. 淮阴师范学院江苏省生物质能与酶技术重点实验室, 江苏淮安 223300;
3. 农业部农村可再生能源开发利用重点实验室, 四川成都 610041

收稿日期:2014-04-02 出版日期:2014-09-30 发布日期:2014-09-30
作者简介:王钱钱（1983-），男，山东济宁人，助理研究员，博士，研究方向为生物质材料及制浆造纸；E-mail：qianqian.wz@gmail.com。
基金资助:
国家自然科学基金项目资助（31300493）；江苏省生物质能与酶技术重点实验室开放基金（JSBEET1305）；农业部农村可再生能源开放利用重点实验室开放基金（2013007）；江苏大学高级人才启动基金（13JDG018）

Research Progress on Thermal Stability of Nanocrystalline Cellulose

WANG Qian-qian^1,2,3, ZHU Qian-qian¹, SUN Jian-zhong¹, XU Jia-xing²

1. School of the Environment, Jiangsu University; Biofuels Institute; Zhenjiang 212013, China;
2. Huaiyin Normal University, Jiangsu Key Laboratory for Biomass-based Energy and Enzyme Technology, Huai'an 223300, China;
3. Laboratory of Development and Application of Rural Renewable Energy, Ministry of Agriculture, Chengdu 610041, China

Received:2014-04-02 Online:2014-09-30 Published:2014-09-30

摘要/Abstract

摘要： 纳米微晶纤维素来自天然高分子聚合物，具有成本低、强度高、轻便等特点，并可循环利用或者生物降解。纳米微晶纤维素研究倍受关注，但纳米微晶纤维素存在一些实用方面的困难。制备过程复杂、热稳定性差等是限制纳米微晶纤维素大规模商业化应用的主要的因素。本文综述了纳米微晶纤维素的热降解机理及其热稳定性影响因素，探讨了提高其热稳定性的途径。

关键词: 纳米微晶纤维素, 热稳定性, 磺酸基团

Abstract: Nanocrystalline cellulose (NCC) isolated from biomass has attracted great attention as a novel nanostructure material due to its low cost,excellent mechanical properties,biodegradability and renewability.However,there are still many challenges that need to be overcome in the application of nanocrystalline cellulose,including large-scale production of nanocrystalline cellulose and improvement of its thermal stability.This paper reviewed the mechanism of nanocrystalline cellulose thermal degradation and summarized the factors which affected its thermal stability.The progress of the methods in improving thermal stability was discussed.

Key words: nanocrystalline cellulose, thermal stability, sulfate group

中图分类号:

TQ35
TS7

王钱钱, 朱倩倩, 孙建中, 许家兴. 纳米微晶纤维素热稳定性的研究进展[J]. 生物质化学工程, 2014, 48(5): 47-51.

WANG Qian-qian, ZHU Qian-qian, SUN Jian-zhong, XU Jia-xing. Research Progress on Thermal Stability of Nanocrystalline Cellulose[J]. bce, 2014, 48(5): 47-51.

参考文献

[1] LUCIA L A,ROJAS O J.The nanoscience and technology of renewable biomaterials [M].Wiley Online Library,2009:1-41.
[2] HABIBI Y,LUCIA L A,ROJAS O J.Cellulose nanocrystals:chemistry,self-assembly,and applications[J].Chemical Reviews,2010,110(6):3479-3500.
[3] 唐丽荣,欧文,林雯怡,等.酸水解制备纳米纤维素工艺条件的响应面优化[J].林产化学与工业,2011,31(6):61-65.
[4] 刘志明,谢成,方桂珍,等.芦苇浆纳米纤维素的制备工艺条件优化及形貌分析[J].林产化学与工业,2011,31(6):87-90.
[5] MOON R J,MARTINI A,NAIRN J,et al.Cellulose nanomaterials review:Structure,properties and nanocomposites[J].Chemical Society Reviews,2011,40(7):3941-3994.
[6] KLEMM D,KRAMER F,MORITZ S,et al.Nanocelluloses:A new family of nature-based materials[J].Angewandte Chemie International Edition,2011,50(24):5438-5466.
[7] GLASSER W G,TAIB R,JAIN R K,et al.Fiber-reinforced cellulosic thermoplastic composites[J].Journal of Applied Polymer Science,1999,73(7):1329-1340.
[8] PENG Y,GARDNER D J,HAN Y,et al.Influence of drying method on the material properties of nanocellulose (I):Thermostability and crystallinity[J].Cellulose,2013,20(5):2379-2392.
[9] EMSLEY A M,STEVENS G C.Kinetics and mechanisms of the low-temperature degradation of cellulose[J].Cellulose,1994,1(1):26-56.
[10] SHEN D K,GU S.The mechanism for thermal decomposition of cellulose and its main products[J].Bioresour Technol,2009,100(24):6496-6504.
[11] WANG N,DING E,CHENG R.Thermal degradation behaviors of spherical cellulose nanocrystals with sulfate groups[J].Polymer,2007,48(12):3486-3493.
[12] 李金玲,陈广祥,叶代勇.纳米纤维素晶须的制备及应用的研究进展[J].林产化学与工业,2010,30(2):121-125.
[13] DONG X M,REVOL J,GRAY D G.Effect of microcrystallite preparation conditions on the formation of colloid crystals of cellulose[J].Cellulose,1998,5(1):19-32.
[14] ZHU J,ZHANG X,PAN X.Sustainable production of fuels,chemicals,and fibers from forest biomass [J].American Chemical Society,2011:301-321.
[15] ROMAN M,WINTER W T.Effect of sulfate groups from sulfuric acid hydrolysis on the thermal degradation behavior of bacterial cellulose[J].Biomacromolecules,2004,5(5):1671-1677.
[16] BECK-CANDANEDO S,ROMAN M,GRAY D G.Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions.[J].Biomacromolecules,2005,6(2):1048-1054.
[17] BONDESON D,MATHEW A,OKSMAN K.Optimization of the isolation of nanocrystals from microcrystalline cellulose by acid hydrolysis[J].Cellulose,2006,13(2):171-180.
[18] PENG Y,GARDNER D J,HAN Y.Drying cellulose nanofibrils:in search of a suitable method[J].Cellulose,2012,19(1):91-102.
[19] 王能,丁恩勇.酸碱处理后纳米微晶纤维素的热行为分析[J].高分子学报,2004,(6):925-928.
[20] HOEGER I,ROJAS O J,EFIMENKO K,et al.Ultrathin film coatings of aligned cellulose nanocrystals from a convective-shear assembly system and their surface mechanical properties[J].Soft Matter,2011,7(5):1957-1967.
[21] REISING A B,MOON R J,YOUNGBLOOD J P.Effect of particle Alignment on mechanical properties of neat cellulose nanocrystal films[J].Journal of Science & Technology for Forest Products and Processes,2012,2(6):32-41.
[22] WANG Q Q,ZHU J Y,REINER R S,et al.Approaching zero cellulose loss in cellulose nanocrystal (CNC) production:Recovery and characterization of cellulosic solid residues (CSR) and CNC[J].Cellulose,2012,19(6):2033-2047.
[23] YU H,QIN Z,LIANG B,et al.Facile extraction of thermally stable cellulose nanocrystals with a high yield of93% through hydrochloric acid hydrolysis under hydrothermal conditions[J].Journal of Materials Chemistry (A),2013,1:3938-3944.
[24] CAMARERO ESPINOSA S,KUHNT T,FOSTER E J,et al.Isolation of thermally stable cellulose nanocrystals by phosphoric acid hydrolysis[J].Biomacromolecules,2013,14(4):1223-1230.
[25] MAO J,OSORIO-MADRAZO A,LABORIE M-P.Preparation of cellulose I nanowhiskers with a mildly acidic aqueous ionic liquid:Reaction efficiency and whiskers attributes[J].Cellulose,2013,20(4):1829-1840.
[26] GEORGE J,RAMANA K V,BAWA A S,et al.Bacterial cellulose nanocrystals exhibiting high thermal stability and their polymer nanocomposites[J].International Journal of Biological Macromolecules,2011,48(1):50-57.
[27] LIN N,HUANG J,CHANG P R,et al.Surface acetylation of cellulose nanocrystal and its reinforcing function in poly(lactic acid)[J].Carbohydrate Polymers,2011,83(4):1834-1842.
[28] XU Q,YI J,ZHANG X,et al.A novel amphotropic polymer based on cellulose nanocrystals grafted with azo polymers[J].European Polymer Journal,2008,44(9):2830-2837.
[29] 王能,丁恩勇,程镕时.纳米微晶纤维素表面改性研究[J].高分子学报,2006,11(8):982-987.
[30] BARUD H S,DE ARAUJO A M,SANTOS D B,et al.Thermal behavior of cellulose acetate produced from homogeneous acetylation of bacterial cellulose[J].Thermochimica Acta,2008,471(1/2):61-69.
[31] ROSA M F,MEDEIROS E S,MALMONGE J A,et al.Cellulose nanowhiskers from coconut husk fibers:Effect of preparation conditions on their thermal and morphological behavior[J].Carbohydrate Polymers,2010,81(1):83-92.
[32] LIN N,DUFRESNE A.Physical and/or chemical compatibilization of extruded cellulose nanocrystal reinforced polystyrene nanocomposites[J].Macromolecules,2013,46(14):5570-5583.
[33] BEN AZOUZ K,RAMIRES E C,VAN DEN FONTEYNE W,et al.Simple method for the melt extrusion of a cellulose nanocrystal reinforced hydrophobic polymer[J].ACS Macro Letters,2011,1(1):236-240.
[34] AZIZI S,AHMAD M B,HUSSEIN M Z,et al.Synthesis,antibacterial and thermal studies of cellulose nanocrystal stabilized ZnO-Ag heterostructure nanoparticles[J].Molecules,2013,18(6):6269-6280.

纳米微晶纤维素热稳定性的研究进展

Research Progress on Thermal Stability of Nanocrystalline Cellulose

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