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生物质化学工程 ›› 2010, Vol. 44 ›› Issue (1): 9-13.

• 论文 • 上一篇    下一篇

木质活性炭自燃性质及其影响因素研究

孙康1,2, 蒋剑春1, 戴伟娣1,2, 张燕萍1   

  1. 1. 中国林业科学研究院, 林产化学工业研究所;生物质化学利用国家工程实验室; 国家林业局, 林产化学工程重点开放性实验室;江苏省生物质能源与材料重点实验室, 江苏 南京 210042;2. 中国林业科学研究院, 林业新技术研究所, 北京 100091
  • 收稿日期:2009-09-27 修回日期:1900-01-01 出版日期:2010-01-30 发布日期:2010-01-30
  • 通讯作者: 蒋剑春(1955- ), 男,江苏溧阳人,研究员,博士,博士生导师,主要从事林产化学加工及生物质能源开发技术。

Study on Self-ignition Character and Influence Factors of Woody Activated Carbon

SUN Kang1,2, JIANG Jian-chun1, DAI Wei-di1,2, ZHANG Yan-ping1   

  1. 1. Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab. for Biomass Chemical Utilization; Key and Open Lab. on Forest Chemical Engineering, SFA;Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China;2. Institute of New Technology of Forestry, CAF, Beijing 100091, China
  • Received:2009-09-27 Revised:1900-01-01 Online:2010-01-30 Published:2010-01-30

摘要: 对6种木质活性炭自燃性质的影响因素进行了研究。研究表明活性炭的临界自燃温度与其制造工艺和设备有关。挥发分(碳氢氧化合物)、氧含量、氢含量和表面含氧官能团及粒度是影响活性炭临界自燃温度的主要因素。磷酸法活性炭临界自燃温度最低(180℃),水蒸气法活性炭由于经过1000℃活化过程,在试验范围内无自燃性质。另外,平板炉制造的粉状活性炭比回转炉制造的粉状活性炭的临界自燃温度高。

关键词: 活性炭, 自燃, 元素组成, 挥发分, 表面官能团

Abstract: The influence factors on the self-ignition properties of six kinds of woody powdered activated carbon were studied. The critical self-ignition temperature (CIT) of activated carbon is related to manufacture processes and equipments. Studies have shown that volatile, oxygen, hydrogen and surface oxygen-containing functional groups are main factors that affect the CIT of activated carbon. Activated carbon manufactured by phosphoric acid has the lowest CIT (180℃), but the activated carbon manufactured by steam has the highest CIT since its activation temperature is high as 1000℃ and it has no self-ignition property. In addition, powdered activated carbon manufactured by flat furnace has higher CIT than that manufactured by rotary furnace.

Key words: activated carbon, self-ignition, element composition, volatilite, surface functional group

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