松木粉制备高比表面积炭基固体酸催化剂

›› 2012, Vol. 46 ›› Issue (1): 15-18.

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Preparation of a Carbon-based Solid Acid Catalyst with High Specific Surface Area from Pine Wood Powder

ZHANG Wen-juan¹, MA Hai-long^2,3, YANG Ya-ti², ZHANG Zeng-qiang², GAO Jin-ming²

1. College of Resources and Environment, Northwest A & F University, Yangling 712100, China;2. Shaanxi Engineering Center of Bioresource Chemistry & Sustainable Utilization; College of Science, Northwest A & F University, Yangling 712100, China;3. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, CAS, Taiyuan 030001, China

Received:2011-08-11 Revised:1900-01-01 Online:2012-01-30 Published:2012-01-30
Contact: MA Hai-long

Abstract

Abstract: A sulfonated (SO₃H-bearing) Carbon-based solid acid catalyst was prepared from pine wood powder — a cheap forest waste. The catalyst was obtained by the carbonization, activation and sulfonation of pine wood powder. The specific surface area and SO₃H density of the carbon catalyst were 1364 m²/g and 1.36 mmol/g, respectively. The catalytic activity of carbon catalyst was investigated on the acetic acid esterification reaction and compared with that of several commercial solid acid catalysts, such as Amberlyst-15, Nafion NR50 and Nafion SAC-13. The results showed that the catalytic activity of carbon catalyst was lower than that of Amberlyst-15, but higher than that of Nafion NR50 and Nafion SAC-13. Its cost is much lower than that of Nafion NR50 and Nafion SAC-13. It also showed that carbon-based solid acid catalyst can be prepared by carbonization, activation and sulfonation of pine wood powder.

Key words: pine wood powder, high specific surface area, carbon-based solid acid, catalyst

CLC Number:

TQ351.2

ZHANG Wen-juan;MA Hai-long;YANG Ya-ti;ZHANG Zeng-qiang;GAO Jin-ming. Preparation of a Carbon-based Solid Acid Catalyst with High Specific Surface Area from Pine Wood Powder[J]. , 2012, 46(1): 15-18.

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Preparation of a Carbon-based Solid Acid Catalyst with High Specific Surface Area from Pine Wood Powder

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