生物质炭材料活化过硫酸盐降解有机污染物的研究进展

doi:10.3969/j.issn.1673-5854.2024.02.007

Abstract

Abstract:

As an economical and readily available carbon-containing material, carbon derived from biomass had been used in advanced oxidation fields. The advanced oxidation process based on sulfate radical was one of the effective approachs to degrade organic pollutants. In this review, the characteristics of persulfate and the reaction principle of oxidative degradation of organic pollutants were reviewed. The effects of non-metallic modification(nitrogen doping, boron doping and sulfur doping), metal modification and surface modification on the degradation of organic pollutants by persulfate activated by biochar materials were analyzed. The activation properties and mechanism of different kinds of biochar-based materials on persulfate, as well as the degradation effect and mechanism of the carbon-based materials on typical organic pollutants were discussed. Finally, the technical challenges and development prospects of carbon-based materials in the field of activated persulfate degradation of organic pollutants were proposed, in order to provide the reference for the research on persulfate degradation of organic pollutants.

Key words: biomass derived carbon-based materials, activation, persulfate, degradation, organic pollutants

CLC Number:

TQ35

Yanyan LIU, Jianchun JIANG, Baojun LI. Research Progress of Biomass Carbon-based Materials Activating Persulfate to Degrade Organic Pollutants[J]. Biomass Chemical Engineering, 2024, 58(2): 55-63.

Figures/Tables 2

References 54

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原料raw materials	N掺杂方式N doping method	降解物degradants	降解率degradation rate	参考文献reference
大豆秸秆soybean stalk	内源N endogenous N	四环素tetracycline	46.36%	[15]
壳聚糖chitosan	内源N endogenous N	对羟基苯甲酸酯parabens	100%	[16]
玉米芯corncob	外源N exogenous N	磺胺嘧啶sulfadiazine	95.4%	[17]
桑树mulberry	外源N exogenous N	甲氧苄啶trimethoprim	97%	[18]
氮掺杂多孔炭nitrogen-doped porous carbon	内源N endogenous N	磺胺甲恶唑sulfamethoxazole	79.1%	[20]
木浆纤维素wood pulp cellulose	内源N endogenous N	双氯芬酸diclofenac	834.8 mg/g	[21]
牛粪cattle manure	内源N endogenous N	双酚A bisphenol A	502.6 mg/g	[14]
螺旋藻spiral algae	内源N endogenous N	磺胺甲恶唑sulfamethoxazole	97.59%	[22]
麦秸粉wheat straw powder	内源N endogenous N	四环素tetracycline	59%	[23]

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Research Progress of Biomass Carbon-based Materials Activating Persulfate to Degrade Organic Pollutants

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