原料复配制备木质素基成型活性炭研究

doi:10.3969/j.issn.1673-5854.2022.06.001

Abstract

Abstract:

Lignin-derived formed activated carbon was prepared from alkali lignin and fir sawdust using phosphoric acid as the activator. The effects of alkali lignin mass fraction, impregnation ratio, activation temperature, and activation time on the properties of activated carbon were investigated. The results showed that the surface wettability of alkali lignin compounded with fir sawdust(alkali lignin mass fraction of 50%) was significantly improved, and the instantaneous water contact angle decreased from 133.2°(alkali lignin) to 86.6°(compound raw materials). The thermal expansion coefficient in the expansion temperature range decreased from 2 365 μm/(m·℃)(alkali lignin)to 45 μm/(m·℃)(compound raw materials). Under optimal technological conditions of alkali lignin mass fraction of 50%, impregnation ratio of 1.5:1(mass ratio of pure phosphoric acid to compound raw materials), activation temperature at 500℃, and activation time for 90 min, the prepared activated carbon had the iodine adsorption value of 1 070 mg/g as well as the methylene blue adsorption value of 255 mg/g. The yield and strength of activated carbon were 41.76% and 90%, respectively. The specific surface area and pore volume were 1 646 m²/g and 0.795 cm³/g respectively, where the pore volume with pore diameter less than 5 nm occupied for 97.2% in the total pore volume.

Key words: alkali lignin, formed activated carbon, phosphoric acid activation, thermal expansion

CLC Number:

TQ35
TQ424

Wei XU, Junli LIU, Kang SUN, Xincheng LU, Ruting XU, Yanping ZHANG. Preparation of Lignin-derived Formed Activated Carbon by Compounding Raw Materials[J]. Biomass Chemical Engineering, 2022, 56(6): 1-7.

Figures/Tables 5

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References 25

1	张召慧, 吴朝军, 于冬梅, 等. 木质素基吸附剂的研究进展[J]. 中国造纸, 2021, 40 (1): 106- 117.
2	MU R H , LIU B , CHEN X , et al. Adsorption of Cu(Ⅱ) and Co(Ⅱ) from aqueous solution using lignosulfonate/chitosan adsorbent[J]. International Journal of Biological Macromolecules, 2020, 163, 120- 127. doi: 10.1016/j.ijbiomac.2020.06.260
3	陈宇, 纪红兵. 木质素类生物质催化热解制备精细化学品研究进展[J]. 化工进展, 2019, 38 (1): 626- 638.
4	CHATTERJEE S , SAITO T . Lignin-derived advanced carbon materials[J]. ChemSusChem, 2015, 8 (23): 3941- 3958. doi: 10.1002/cssc.201500692
5	LIU S , WEI W , WU S , et al. Preparation of hierarchical porous activated carbons from different industrial lignin for highly efficient adsorption performance[J]. Journal of Porous Materials, 2020, 27 (5): 1523- 1533. doi: 10.1007/s10934-020-00926-9
6	KUPILA R, LAPPALAINEN K, HU T, et al. Lignin-based activated carbon-supported metal oxide catalysts in lactic acid production from glucose[J/OL]. Applied Catalysis A: General, 2021, 612: 118011[2022-04-10]. https://doi.org/10.1016/j.apcata.2021.118011.
7	TRAN H N , CHAO H P , YOU S J . Activated carbons from golden shower upon different chemical activation methods: Synthesis and characterizations[J]. Adsorption Science and Technology, 2017, 36 (1): 95- 113.
8	JIANG L , MA F , LIANG G B , et al. Preparation of activated carbons from lignin by NaOH activation and processing optimization[J]. New Carbon Materials, 2011, 26 (5): 396- 400.
9	HAYASHI J , KAZEHAYA A , MUROYAMA K , et al. Preparation of activated carbon from lignin by chemical activation[J]. Carbon, 2000, 38 (13): 1873- 1878. doi: 10.1016/S0008-6223(00)00027-0
10	SUHAS , CARROTT P , CARROTT M . Lignin-from natural adsorbent to activated carbon: A review[J]. Bioresource Technology, 2007, 98 (12): 2301- 2312. doi: 10.1016/j.biortech.2006.08.008
11	王晶, 韩巧宁, 雷以廷, 等. 一步法制备富氧木质素活性炭及其亚甲基蓝吸附性能[J]. 化工学报, 2021, 72 (5): 2826- 2836.
12	蒲瀛州, 徐绍平, 王克超, 等. 磷酸法木质素基活性炭活化过程研究[J]. 大连理工大学学报, 2020, 60 (4): 349- 357.
13	孙永昌, 张冰清, 刘力鸣, 等. 木质素基炭材料的制备及其对Cr(VI)的吸附机制研究[J]. 林产化学与工业, 2019, 39 (4): 120- 128.
14	ABDERRAHMANE E K , MOUSTAQIM M E , ELMAROUANI M , et al. Thermal and thermomechanical analyses of lignin[J]. Sustainable Chemistry and Pharmacy, 2018, 9, 63- 68.
15	SHRESTHA B , BRECH L Y , GHISLAIN T , et al. A multitechnique characterization of lignin softening and pyrolysis[J]. ACS Sustainable Chemistry & Engineering, 2017, 5 (8): 6940- 6949.
16	TONG H , NANTA S , AYUMU T , et al. Characterization of lignin at pre-pyrolysis temperature to investigate its melting problem[J]. Fuel, 2018, 235, 1061- 1069.
17	SHUAI Z , BROWN R C , BAI X . The use of calcium hydroxide pretreatment to overcome agglomeration of technical lignin during fast pyrolysis[J]. Green Chemistry, 2015, 17 (10): 4748- 4759.
18	ROSAS J M , RUIZ-ROSAS R , RODRÍGUEZ-MIRASOL J , et al. Kinetic study of the oxidation resistance of phosphorus-containing activated carbons[J]. Carbon, 2012, 50 (4): 1523- 1537.
19	LIU Q S , ZHENG T , WANG P , et al. Preparation and characterization of activated carbon from bamboo by microwave-induced phosphoric acid activation[J]. Industrial Crops & Products, 2010, 31 (2): 233- 238.
20	XU W , LIU J , SUN K , et al. Effect of activation temperature on properties of H₃PO₄-activated carbon[J]. Bioresources, 2021, 16 (2): 4007- 4020.
21	左宋林. 磷酸活化法制备活性炭综述(I)—磷酸的作用机理[J]. 林产化学与工业, 2017, 37 (3): 1- 9.
22	林冠烽. 磷酸法自成型木质颗粒活性炭的制备过程与机理研究[D]. 北京: 中国林业科学研究院, 2013.
23	ZUO S , YANG J , LIU J , et al. Significance of the carbonization of volatile pyrolytic products on the properties of activated carbons from phosphoric acid activation of lignocellulosic material[J]. Fuel Processing Technology, 2009, 90 (7): 994- 1001.
24	THOMMES M , KANEKO K , NEIMARK A V , et al. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution(IUPAC Technical Report)[J]. Pure & Applied Chemistry, 2015, 38 (1): 25- 25.
25	YUN C H , PARK Y H , PARK C R . Effects of pre-carbonization on porosity development of activated carbons from rice straw[J]. Carbon, 2001, 39 (4): 559- 567.

制备条件 preparation conditions		得率/% yield	强度/% strength	亚甲基蓝吸附值/(mg·g^-1) methylene blue adsorption value	碘吸附值/(mg·g^-1) iodine adsorption value
碱木质素质量分数 alkali lignin mass fraction	60%	42.25	92	247.5	1 033
	50%	41.76	90	255	1 070
	40%	40.60	89	255	1 070
	30%	38.21	89	270	1 099
浸渍比 impregnation ratio	1∶1	38.57	91	232.5	973
	1.5∶1	41.76	90	255	1 070
	2∶1	42.25	88	225	932
活化温度 activation temperature	450 ℃	41.92	88	240	1 011
	500 ℃	41.76	90	255	1 070
	550 ℃	42.51	92	232.5	962
活化时间 activation time	60 min	42.30	89	240	995
	90 min	41.76	90	255	1 070
	120 min	40.95	90	255	1 056

[1]	Ruting XU, Xincheng LU, Kang SUN, Chang TAN, Yanping ZHANG. Effects of Torrefaction Pretreatment on the Preparation and Properties of Activated Carbon from Corn Straw by Phosphoric Acid Activation [J]. Biomass Chemical Engineering, 2022, 56(4): 1-8.
[2]	Jiaxing ZHOU,Zhiming LIU,Xu LI. Effect of Aluminum Hypophosphite Addition on Flame Retardancy of Alkali Lignin Based Polyurethane Foam [J]. Biomass Chemical Engineering, 2019, 53(2): 1-6.
[3]	HU Ping, WANG Lifang, JIA Boran, LIU Ying, SHA Xiaoling, REN Shixue. Degradation Performances of Poly(vinylalcohol)/Wheat Straw Alkali Lignin Foaming Material with Formaldehyde Crosslinker [J]. bce, 2018, 52(4): 29-35.
[4]	TAN Yang, MA Chunfu. Mechanism Study of Black Liquor Alkali Lignin Pyrolysis by Using TG-FTIR [J]. bce, 2018, 52(2): 35-41.
[5]	ZHANG Cuimei, CUI Xuejing, SUN Yanni, JIANG Ruiyu, ZHAO Jiruo, FENG Ying. Characteristic of Alkali Lignin Filling Natural Rubber [J]. bce, 2017, 51(3): 33-40.
[6]	YANG Wei, LI Zhui, BI Yan-wen, LU Jin-cheng, GONG Cheng-cheng, CAO Wei-hua, FANG Gui-zhen, MA Yan-li. Preparation Technology of Polyacrylic Acid Grafted Alkali Lignin/ Phenolic Open-cell Absorbent Material [J]. bce, 2015, 49(3): 7-12.
[7]	YANG Qiao-wen, CHEN Si, LI Peng-fei. Preparation of Activated Carbon from Furfural Residues by Phosphoric Acid Activation [J]. bce, 2015, 49(3): 23-26.
[8]	LIN Guan-feng, WU Kai-jin, CHANG Ying-cui, CHEN Han, YU Jin. Preparation of Unshaped Granular Activated Carbon from Coconut Shell by Phosphoric Acid Activation [J]. bce, 2015, 49(3): 49-51.
[9]	LUO Hua-chao, CHEN He-mu, CHEN Ying-chao, FENG Wei, WANG Chen, QIN Bi-da, REN Shi-xue. Preparation and Properties of Polyvinyl Alcohol/Modified Alkali Lignin Foaming Materials [J]. bce, 2015, 49(2): 1-6.
[10]	WANG Hui-min, MA Yan-li, FANG Gui-zhen, LI Shu-jun. Properties and Characterization of Alkali Lignin/Poly-acrylonitrile Graft Porous Materials [J]. bce, 2015, 49(1): 13-19.
[11]	SU Ling;REN Shi-xue;FANG Gui-zhen. Preparation and Optical Properties of Glutaraldehyde Crosslinked Alkali Lignin/PVA Films [J]. , 2013, 47(3): 1-5.
[12]	LIN Guan-feng;JIANG Jian-chun;WU Kai-jin. Preparation of Hemi-cellulose-based Granular Activated Carbon by Phosphoric Acid Activation [J]. , 2013, 47(3): 6-10.
[13]	ZHUANG Xiao-wei;MU You-bing;PAN Xin;ZHANG Jiang-li;WANG Chun-peng;ZHAO Lin-wu. Applications of Alkali Lignin/Phenol-formaldehyde Resin in Bamboo Plywood [J]. , 2011, 45(5): 17-20.
[14]	CHEN Yun-ping;FU Yan-bin;YANG Ping;CHEN Li;CHENG Xian-su. Research on Degradation of Alkali Lignin by Nano Titanium Dioxide Photocatalysis [J]. , 2009, 43(6): 31-35.
[15]	JIN Fan;LIU Zhi-ming;FANG Gui-zhen;LI Shan-shan;HUANG Huan-ling. Synthetic Conditions and Performance of Lignin Based Polyurethane Film [J]. , 2007, 41(4): 27-30.

Preparation of Lignin-derived Formed Activated Carbon by Compounding Raw Materials

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