过渡金属改性氮掺杂多孔碳负载Pt催化甘油氧化制备甘油酸

doi:10.3969/j.issn.1673-5854.2023.02.004

Abstract

Abstract:

After doping different transition metals into metal-organic framework compounds, transition metal modified nitrogen-doped porous carbon material(M@NHC) was obtained by high temperature calcination. Then, Pt/M@NHC catalyst was prepared by colloidal deposition method and evaluated for catalytic oxidation of glycerol to glyceric acid under alkaline conditions. The result showed that the types of transition metals had a great influence on the conversion of glycerol and the glyceric acid selectivity, and the Ni-doped Pt/Ni@NHC catalyst exhibited the best catalytic activity. Combined with the characterization results of N₂ physical adsorption, X-ray diffraction, X-ray photoelectron spectroscopy, and CO₂ temperature programmed desorption, it was found that the introduction of Ni not only changed the surface electronic structure of Pt, but also increased the antioxidant capacity of Pt nanoparticles via Ni-Pt synergies between metals. At the same time, the doping of surface nitrogen atoms increased the electrons on the Pt and adsorption oxygen surfaces, which would rapidly activate molecular oxygen and produce more active sites. In addition, Pt nanoparticles of Pt/Ni@NHC had the smallest particle size in all catalysts, which was conducive to the improvement of catalytic performance. The catalytic performance of Pt/Ni@NHC catalysts under different preparation conditions was investigated. The catalyst of Pt/Ni@NHC prepared under the conditions of 3% Ni content, calcination temperature of 800 ℃, the reaction pressure of 1 MPa and the reaction time of 6 h had the best catalytic performance. At this time, the conversion rate of glycerol was 63% and the selectivity of glyceric acid was 77.4%.

Key words: glycerol, glyceric acid, catalysis, oxidation, supported Pt catalysts

CLC Number:

TQ35
O643

Yihu KE, Chunmei ZHU, Jingyun LI, Hai LIU, Hong YUAN. Catalytic Oxidation of Glycerol to Glyceric Acid over Transition Metal Modified Nitrogened-doped Porous Carbon Supported Pt Catalyst[J]. Biomass Chemical Engineering, 2023, 57(2): 29-40.

Figures/Tables 17

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References 41

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催化剂 catalyst	S_BET/(m²·g^-1)	V_p/(m³·g^-1)	D_p/nm	C/%	O/%	Pt/%	N/%	M/%
Pt/Zn@NHC	465	0.25	2.16	69.00	11.49	0.05	3.75	4.17
Pt/Ni@NHC	430	0.44	4.41	83.63	6.80	0.07	7.17	2.34
Pt/Co@NHC	273	0.31	4.55	80.54	11.49	0.05	3.75	4.17
Pt/Zr@NHC	22	0.17	29.77	19.45	56.74	0.18	1.30	22.34
Pt/Cu@NHC	6	0.02	17.23	61.27	15.12	0.52	12.62	10.47
Pt/Fe@NHC	5	0.02	15.87	22.06	55.47	0.42	1.01	21.04
Pt/Ce@NHC	4	0.01	12.46	16.28	59.53	4.27	1.46	18.46

催化剂 catalyst	转化率/% conversion	选择性selectivity/%
催化剂 catalyst	转化率/% conversion	OA	LA	GLYA	DHA	TA	GLYD
Ni@NHC	4.79	0	1.17	0	8.53	0.38	89.91
Pt/Ni@NHC	62.53	0.16	7.29	75.23	16.70	0.62	—
Pt/Co@NHC	37.88	0.02	34.83	25.15	40.00	—	—
Pt/Ce@NHC	35.84	0.17	4.82	75.40	18.46	1.15	—
Pt/Zr@NHC	35.45	0.22	5.29	72.69	18.31	3.49	—
Pt/Cu@NHC	7.00	4.68	12.87	11.84	70.61	—	—
Pt/Fe@NHC	5.32	1.54	21.33	41.14	35.99	—	—
Pt/Zn@NHC	—	—	—	—	—	—

催化剂 catalyst	S_BET/(m²·g^-1)	V_p/(m³·g^-1)	D_p/nm	转化率/% conversion	选择性selectivity/%
催化剂 catalyst	S_BET/(m²·g^-1)	V_p/(m³·g^-1)	D_p/nm	转化率/% conversion	OA	LA	GLYA	DHA	TA
Pt/Ni@NHC-600	349	0.36	4.18	26.64	—	3.84	72.28	23.62	0.26
Pt/Ni@NHC-700	395	0.35	4.10	42.99	0.10	4.05	76.67	18.19	0.99
Pt/Ni@NHC-800	430	0.44	4.09	62.58	0.06	5.39	77.40	16.23	0.95
Pt/Ni@NHC-900	300	0.33	4.44	59.17	0.17	5.94	77.60	14.43	1.86

催化剂 catalyst	S_BET/(cm²·g^-1)	V_p/(m³·g^-1)	D_p/nm	转化率/% conversion	选择性selectivity/%
催化剂 catalyst	S_BET/(cm²·g^-1)	V_p/(m³·g^-1)	D_p/nm	转化率/% conversion	OA	LA	GLYA	DHA	TA
Pt/Ni@NHC-2%	314	0.36	4.19	40.00	0.47	4.69	72.10	22.17	0.57
Pt/Ni@NHC-3%	430	0.35	4.09	62.53	0.16	7.29	75.23	16.70	0.62
Pt/Ni@NHC-5%	315	0.44	4.18	42.13	0.01	3.68	77.05	18.86	0.40
Pt/Ni@NHC-7%	305	0.33	4.80	42.79	0.03	3.39	77.54	18.24	0.80

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Catalytic Oxidation of Glycerol to Glyceric Acid over Transition Metal Modified Nitrogened-doped Porous Carbon Supported Pt Catalyst

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