生物基聚氨酯材料的研究进展

doi:10.3969/j.issn.1673-5854.2023.01.001

Abstract

Abstract:

As a kind of polymer material with versatile product forms, polyurethane is widely used in many applications. Developing technologies that can use green and renewable raw materials as feedstock has become a research hotspot, as well as great significance to the polyurethane research in the future. Based on the relevant literatures of the last decade, this paper focuses on the basic methods and research progress for the synthesis of bio-based polyols and isocyanates from common renewable alternatives, such as vegetable oil(castor oil, soybean oil, tung oil, palm oil, etc.), lignocellulose, rosin, natural phenols(cardanol and tannin), sugars and other biomass resources. In addition, the research status of non-isocyanates was mentioned, and the unique advantages of these materials for the preparation of bio-polyurethane were listed. This article also comprehensively examines the future hurdles that hinder the utilization of these materials, and then the development prospects of bio-based polyurethane materials in different fields are outlooked.

Key words: renewable resource, bio-sourced polyurethane, green chemistry, lignin, vegetable oil

CLC Number:

TQ35
TQ43

Yonghong ZHOU, Zheng PAN, Meng ZHANG. Recent Progress in Synthesis and Application of Bio-based Polyurethanes[J]. Biomass Chemical Engineering, 2023, 57(1): 1-12.

Figures/Tables 2

References 90

1	MALANI R S , MALSHE V C , THORAT B N . Polyols and polyurethanes from renewable sources: Past, present and future—part 1:Vegetable oils and lignocellulosic biomass[J]. Journal of Coatings Technology and Research, 2022, 19 (1): 201- 222. doi: 10.1007/s11998-021-00490-0
2	PARASKAR P M, PRABHUDESAI M S, HATKAR V M, et al. Vegetable oil based polyurethane coatings—A sustainable approach: A review[J/OL]. Progress in Organic Coatings, 2021, 156(58): 106267[2022-11-10]. https://doi.org/10.1016/j.porgcoat.2021.106267.
3	AKINDOYO J O , BEG M D H , GHAZALI S , et al. Polyurethane types, synthesis and applications: A review[J]. RSC Advances, 2016, 6 (115): 114453- 114482. doi: 10.1039/C6RA14525F
4	PARCHETA P , DATTA J . Environmental impact and industrial development of biorenewable resources for polyurethanes[J]. Critical Reviews in Environmental Science and Technology, 2017, 47 (20): 1986- 2016. doi: 10.1080/10643389.2017.1400861
5	ALINEJAD M, HENRY C, NIKAFSHAR S, et al. Lignin-based polyurethanes: Opportunities for bio-based foams, elastomers, coatings and adhesive[J/OL]. Polymers, 2019, 11(7): 1202[2022-11-10]. https://doi.org/10.3390/polym11071202.
6	IWATA T . Biodegradable and bio-based polymers: Future prospects of eco-friendly plastics[J]. Angewandte Chemie, 2015, 54 (11): 3210- 3215. doi: 10.1002/anie.201410770
7	GROUP C W . Polyurethanes from vegetable oils[J]. Chemical Weekly, 2011, 56 (40): 203- 206.
8	MAISONNEUVE L , LEBARBÉ T , GRAU E , et al. Structure-properties relationship of fatty acid-based thermoplastics as synthetic polymer mimics[J]. Polymer Chemistry, 2013, 4 (22): 5472- 5517. doi: 10.1039/c3py00791j
9	GHASEMLOU M , DAVER F , IVANOVA E P , et al. Polyurethanes from seed oil-based polyols: A review of synthesis, mechanical and thermal properties[J]. Industrial Crops and Products, 2019, 142 (15): 111841- 111849.
10	CHAUDHARI A , GITE V , RAJPUT S , et al. Development of eco-friendly polyurethane coatings based on neem oil polyetheramide[J]. Industrial Crops and Products, 2013, 50 (2): 550- 556.
11	KONG X , LIU G , CURTIS J M . Novel polyurethane produced from canola oil based poly(ether ester) polyols: Synthesis, characterization and properties[J]. European Polymer Journal, 2012, 48 (12): 2097- 2106. doi: 10.1016/j.eurpolymj.2012.08.012
12	STIRNA U , FRIDRIHSONE A , LAZDINA B , et al. Biobased polyurethanes from rapeseed oil polyols: Structure, mechanical and thermal properties[J]. Journal of Polymers and the Environment, 2013, 21 (2): 952- 962.
13	ALAGI P , HONG S C . Vegetable oil-based polyols for sustainable polyurethanes[J]. Macromolecular Research, 2015, 23 (12): 1079- 1086. doi: 10.1007/s13233-015-3154-6
14	ADHVARYU A , LIU Z , ERHAN S Z . Synthesis of novel alkoxylated triacylglycerols and their lubricant base oil properties[J]. Industrial Crops and Products, 2005, 21 (1): 113- 119. doi: 10.1016/j.indcrop.2004.02.001
15	MAYA-VISUET E , GAO T , SOUCEK M , et al. The effect of TiO₂ as a pigment in a polyurethane/polysiloxane hybrid coating/aluminum interface based on damage evolution[J]. Progress in Organic Coatings, 2015, 83 (2): 36- 46.
16	GUO Y , HARDESTY J , MANNARI V , et al. Hydrolysis of epoxidized soybean oil in the presence of phosphoric acid[J]. Journal of the American Oil Chemists' Society, 2007, 84 (10): 929- 935. doi: 10.1007/s11746-007-1126-5
17	MEERA K M S , SANKAR R M , PAUL J , et al. The influence of applied silica nanoparticles on a bio-renewable castor oil based polyurethane nanocomposite and its physicochemical properties[J]. Physical Chemistry Chemical Physics, 2014, 16 (20): 9276- 9288. doi: 10.1039/C4CP00516C
18	LIANG B , LI R , ZHANG C , et al. Synthesis and characterization of a novel tri-functional bio-based methacrylate prepolymer from castor oil and its application in UV-curable coatings[J]. Industrial Crops and Products, 2019, 135 (1): 170- 178.
19	PARASKAR P M, PRABHUDESAI M S, KULKARNI R D. Synthesis and characterizations of air-cured polyurethane coatings from vegetable oils and itaconic acid[J/OL]. Reactive and Functional Polymers, 2020, 156(2): 104734[2022-11-10]. https://doi.org/10.1016/j.reactfunctpolym.2020.104734.
20	ZHANG M , PAN H , ZHANG Q , et al. Study of the mechanical, thermal properties and flame retardancy of rigid polyurethane foams prepared from modified castor-oil-based polyols[J]. Industrial Crops and Products, 2014, 59 (1): 135- 143.
21	HUSI S , JAVNI I , PETROVI Z S . Thermal and mechanical properties of glass reinforced soy-based polyurethane composites[J]. Composites Science and Technology, 2005, 65 (1): 19- 25. doi: 10.1016/j.compscitech.2004.05.020
22	BAILOSKY L C , BENDER L M , BODE D , et al. Synthesis of polyether polyols with epoxidized soy bean oil[J]. Progress in Organic Coatings, 2013, 76 (12): 1712- 1719. doi: 10.1016/j.porgcoat.2013.05.005
23	JI D , FANG Z , HE W , et al. Polyurethane rigid foams formed from different soy-based polyols by the ring opening of epoxidised soybean oil with methanol, phenol, and cyclohexanol[J]. Industrial Crops and Products, 2015, 74 (1): 76- 82.
24	MCCLEMENTS D , WEISS J . Bailey's industrial oil and fat products[J]. Lipid Emulsions, 2005, 8 (1): 457- 502.
25	GANDINI A, LACERDA T M. The prospering of macromolecular materials based on plant oils within the blooming field of polymers from renewable resources[J/OL]. Proceedings, 2021, 69(1): 26[2022-11-10]. https://doi.org/10.3390/CGPM2020-07202.
26	JIANG L, REN Z, LIU W, et al. Synthesis and molecular interaction of tung oil-based anionic waterborne polyurethane dispersion[J/OL]. Journal of Applied Polymer Science, 2020, 137(45): 49383[2022-11-10]. https://doi.org/10.1002/app.49383.
27	郑敏睿, 薄采颖, 胡立红, 等. 桐油基阻燃多元醇制备及其在硬质聚氨酯泡沫中应用[J]. 工程塑料应用, 2017, 45 (7): 129- 133.
28	周威, 郑开梅, 周永红, 等. 新型含磷阻燃型桐油基聚氨酯硬泡的制备及性能表征[J]. 化工进展, 2019, 38 (7): 3285- 3290.
29	ARNIZA M Z , HOONG S S , IDRIS Z , et al. Synthesis of transesterified palm olein-based polyol and rigid polyurethanes from this polyol[J]. Journal of the American Oil Chemists' Society, 2015, 92 (2): 243- 255. doi: 10.1007/s11746-015-2592-9
30	HU S J , LUO X L , LI Y B . Polyols and polyurethanes from the liquefaction of lignocellulosic biomass[J]. Chemsuschem, 2014, 7 (1): 66- 72. doi: 10.1002/cssc.201300760
31	GARCÍA J L , PANS G , PHANOPOULOS C . Use of lignin in polyurethane-based structural wood adhesives[J]. The Journal of Adhesion, 2018, 94 (10): 814- 828. doi: 10.1080/00218464.2017.1385458
32	CHAHAR S , DASTIDAR M G , CHOUDHARY V , et al. Synthesis and characterisation of polyurethanes derived from waste black liquor lignin[J]. Journal of Adhesion Science & Technology, 2004, 18 (2): 169- 179.
33	GADHAVE R V, SANJIVKASBE P, MAHANWAR P A, et al. Synthesis and characterization of lignin-polyurethane based wood adhesive[J/OL]. International Journal of Adhesion and Adhesives, 2019, 95(1): 102427[2022-11-10]. https://doi.org/10.1016/j.ijadhadh.2019.102427.
34	ARAÚJO R C S , PASA V M D . Mechanical and thermal properties of polyurethane elastomers based on hydroxyl-terminated polybutadienes and biopitch[J]. Journal of Applied Polymer Science, 2003, 88 (3): 759- 766. doi: 10.1002/app.11526
35	FURTWENGLER P , AVÉROUS L . Renewable polyols for advanced polyurethane foams from diverse biomass resources[J]. Polymer Chemistry, 2018, 9 (32): 4258- 4287. doi: 10.1039/C8PY00827B
36	XUE B L , HUANG P L , SUN Y C , et al. Hydrolytic depolymerization of corncob lignin in the view of a bio-based rigid polyurethane foam synthesis[J]. RSC Advances, 2017, 7 (10): 6123- 6130. doi: 10.1039/C6RA26318F
37	HAKIM A , NASSAR M , EMAM A , et al. Preparation and characterization of rigid polyurethane foam prepared from sugar-cane bagasse polyol[J]. Materials Chemistry and Physics, 2011, 129 (1/2): 301- 307.
38	D'SOUZA J, CAMARGO R, YAN N. Polyurethane foams made from liquefied bark-based polyols[J/OL]. Journal of Applied Polymer Science, 2014, 131(16): 40599[2022-11-10]. https://doi.org/10.1002/app.40599.
39	LI H Q, SHAO Q, LUO H, et al. Polyurethane foams from alkaline lignin-based polyether polyol[J/OL]. Journal of Applied Polymer Science, 2016, 133(14): 43261[2022-11-10]. https://doi.org/10.1002/app.43261.
40	LIU J , CHEN F , QIU M . Liquefaction of bagasse and preparation of rigid polyurethane foam from liquefaction products[J]. Journal of Biobased Materials and Bioenergy, 2009, 3 (4): 401- 407. doi: 10.1166/jbmb.2009.1050
41	KIM K H , YU J H , LEE E Y . Crude glycerol-mediated liquefaction of saccharification residues of sunflower stalks for production of lignin biopolyols[J]. Journal of Industrial and Engineering Chemistry, 2016, 38 (2): 175- 180.
42	LEE J H , LEE J H , KIM D K , et al. Crude glycerol-mediated liquefaction of empty fruit bunches saccharification residues for preparation of biopolyurethane[J]. Journal of Industrial and Engineering Chemistry, 2016, 34 (2): 157- 164.
43	LADERO M , GRACIA M D , TRUJILLO F , et al. Phenomenological kinetic modelling of the esterification of rosin and polyols[J]. Chemical Engineering Journal, 2012, 197 (15): 387- 397.
44	邵金涛, 余彩莉, 张发爱. 松香基聚氨酯的研究进展[J]. 生物质化学工程, 2019, 53 (6): 59- 66.
45	LIU B H , NIE J , HE Y . From rosin to high adhesive polyurethane acrylate: Synthesis and properties[J]. International Journal of Adhesion and Adhesives, 2016, 66 (1): 99- 103.
46	张伟, 储富祥, 王春鹏. 生物质泡沫材料的研究进展[J]. 高分子材料科学与工程, 2010, 26 (8): 157- 160.
47	边峰, 余彩莉, 陈勇, 等. 丙烯酸改性松香基TDI型聚氨酯的制备及表征[J]. 高分子材料科学与工程, 2019, 35 (1): 25- 30.
48	SI H , LIU H , SHANG S , et al. Preparation and properties of maleopimaric acid-based polyester polyol dispersion for two-component waterborne polyurethane coating[J]. Progress in Organic Coatings, 2016, 90 (2): 309- 316.
49	ZHANG L Q , ZHOU Y H . Preparation and characterization of polyurethane foams from modified rosin-based polyether polyol[J]. ADV Mater Res-Switz, 2014, 887/888 (1): 727- 730.
50	BIMLESH L, SWAPNIL S, VARMA I K. Naturally occurring phenolic sources: monomers and polymers[J]. RSC Advances, 4(42): 21712-21752.
51	AQDAS N , MAHMOOD Z K , MOHAMMAD Z , et al. Bio-based polyurethane: An efficient and environment friendly coating systems: A review[J]. Progress in Organic Coatings: An International Review Journal, 2016, 91 (1): 25- 32.
52	MISHRA V , DESAI J , PATEL K I J I C , et al. (UV/Oxidative) dual curing polyurethane dispersion from cardanol based polyol: Synthesis and characterization[J]. Industrial Crops and Prodycts, 2018, 111 (2): 165- 178.
53	KATHALEWAR M , SABNIS A , D'MELO D J P I O C . Polyurethane coatings prepared from CNSL based polyols: Synthesis, characterization and properties[J]. Progress in Organic Coatings, 2014, 77 (3): 616- 626. doi: 10.1016/j.porgcoat.2013.11.028
54	SHRESTHAM L, IONESCUM, WANX, 等. Biobased aromatic-aliphatic polyols from cardanol by photochemical thiol-ene reaction[J]. 可再生材料杂志(英文), 2018, 6 (1): 87- 101.
55	WANG H , ZHOU Q , ENGINEERING . Synthesis of cardanol-based polyols via thiol-ene/thiol-epoxy dual click-reactions and thermosetting polyurethanes therefrom[J]. ACS Sustainable Chemistry & Engineering, 2018, 6 (9): 12088- 12095.
56	ZHANG M , ZHANG J , CHEN S , et al. Synthesis and fire properties of rigid polyurethane foams made from a polyol derived from melamine and cardanol[J]. Polymer Degradation and Stability, 2014, 110 (5): 27- 34.
57	ISWANTO A H . Recent developments in lignin- and tannin-based non-isocyanate polyurethane resins for wood adhesives: A review[J]. Journal of Applied Polymer Science, 2021, 11 (9): 4242- 4261.
58	CHEN X, LI J, XI X, et al.Condensed tannin-glucose-based NIPU bio-foams of improved fire retardancy[J/OL]. Polymer Degradation and Stability, 2020, 175(2): 109121[2022-11-10]. https://doi.org/10.1016/j.polymdegradstab.2020.109121.
59	DÍAZ-GOMEZ A , GODOY M , BERRIO M E , et al. Evaluation of the mechanical and fire resistance properties of rigid tannin polyurethane foams with copper oxide nanoparticles[J]. Fibers and Polymers, 2022, 23 (7): 1797- 806.
60	ARBENZ A , AVEROUS L . Chemical modification of tannins to elaborate aromatic biobased macromolecular architectures[J]. Green Chemistry, 2015, 46 (29): 2626- 2646.
61	ARBENZ A , AVÉROUS L . Oxyalkylation of gambier tannin: Synthesis and characterization of ensuing biobased polyols[J]. Industrial Crops and Products, 2015, 67 (12): 295- 304.
62	TONDI G , ZHAO W , PIZZI A , et al. Tannin-based rigid foams: A survey of chemical and physical properties[J]. Bioresource Technology, 2009, 100 (21): 5162- 5169.
63	BASSO M C , PIZZI A , LACOSTE C , et al. MALDI-TOF and ¹³C NMR analysis of tannin-furanic-polyurethane foams adapted for industrial continuous lines application[J]. Polymers, 2014, 6 (12): 2985- 3004.
64	PIZZI A J F.Bio-based polyurethane resins derived from tannin: Source, synthesis, characterisation, and application[J/OL]. Forests, 2021, 12(11): 1516[2022-11-10]. https://doi.org/10.3390/f12111516.
65	FRASER-REID B O, TATSUTA K, THIEM J, et al.Glycoscience.chemistry and chemical biology[J/OL]. Biochemistry, 2009, 11(74): 1289[2022-11-10]. https://doi.org/10.1134/S0006297909110170.
66	HATAKEYAMA H , NAKAYACHI A , HATAKEYAMA T , et al. Thermal and mechanical properties of polyurethane-based geocomposites derived from lignin and molasses[J]. Composites Part A: Applied Science, 2005, 36 (5): 698- 704.
67	ANAND A , KULKARNI R D , PATIL C K , et al. Utilization of renewable bio-based resources, viz.sorbitol, diol, and diacid, in the preparation of two pack PU anticorrosive coatings[J]. RSC Advances, 2016, 6 (12): 9843- 9850.
68	MAISONNEUVE L , LAMARZELLE O , RIX E , et al. Isocyanate-free routes to polyurethanes and poly(hydroxy urethane)s[J]. Chemical Reviews, 2015, 115 (22): 12407- 12439.
69	XIANG J , YANG S , ZHANG J , et al. The preparation of sorbitol and its application in polyurethane: A review[J]. Polymer Bulletin, 2022, 79 (4): 2667- 2684.
70	BȽAEK K , DATTA J . Renewable natural resources as green alternative substrates to obtain bio-based non-isocyanate polyurethanes-review[J]. Critical Reviews in Environmental Science and Technology, 2019, 49 (3): 173- 211.
71	ANAND A , KULKARNI R D , GITE V V . Preparation and properties of eco-friendly two pack PU coatings based on renewable source(sorbitol) and its property improvement by nano ZnO[J]. Progress in Organic Coatings, 2012, 74 (4): 764- 767.
72	KHANDERAY J C , GITE V V . Fully biobased polyester polyols derived from renewable resources toward preparation of polyurethane and their application for coatings[J]. Journal of Applied Polymer Science, 2019, 136 (22): 47558- 47566.
73	SAXON D J , NASIRI M , MANDAL M , et al. Architectural control of isosorbide-based polyethers via ring-opening polymerization[J]. Journal of the American Chemical Society, 2019, 141 (13): 5107- 5111.
74	JIANG T , WANG W , YU D , et al. Synthesis and characterization of polyurethane rigid foams from polyether polyols with isosorbide as the biobased starting agent[J]. Journal of Polymer Research, 2018, 25 (6): 140- 150.
75	COGGIO W D , HEVUS I , WEBSTER D C . Bio-based succinic acid polyester polyols[J]. Adhesives & Sealants Industry, 2015, 22 (6): 36- 42.
76	PARCHETA P , DATTA J . Structure analysis and thermal degradation characteristics of bio-based poly(propylene succinate)s obtained by using different catalyst amounts[J]. Journal of Thermal Analysis and Calorimetry, 2017, 130 (1): 197- 206.
77	ECKERT H , FORSTER B . Triphosgene, a crystalline phosgene substitute[J]. Angewandte Chemie International Edition in English, 1987, 26 (9): 894- 895.
78	WALDMAN T E , MCGHEE W D . Isocyanates from primary amines and carbon dioxide: 'Dehydration' of carbamate anions[J]. Journal of the Chemical Society Chemical Communications, 1994, 10 (8): 957- 958.
79	HOJABRI L , KONG X , NARINE S S . Fatty acid-derived diisocyanate and biobased polyurethane produced from vegetable oil: Synthesis, polymerization, and characterization[J]. Biomacromolecules, 2009, 10 (4): 884- 891.
80	MORE A S , LEBARBÉ T , MAISONNEUVE L , et al. Novel fatty acid based di-isocyanates towards the synthesis of thermoplastic polyurethanes[J]. European Polymer Journal, 2013, 49 (4): 823- 833.
81	DATTA J , KASPRZYK P . Thermoplastic polyurethanes derived from petrochemical or renewable resources: A comprehensive review[J]. Polymer Engineering and Science, 2018, 58 (S1): 14- 35.
82	DATTA J , WOCH M . Progress in non-isocyanate polyurethanes synthesized from cyclic carbonate intermediates and di- or polyamines in the context of structure-properties relationship and from an environmental point of view[J]. Polymer Bulletin, 2016, 73 (5): 1459- 1496.
83	CORNILLE A , AUVERGNE R , FIGOVSKY O , et al. A perspective approach to sustainable routes for non-isocyanate polyurethanes[J]. European Polymer Journal, 2016, 87 (7): 535- 552.
84	HIBERT G , LAMARZELLE O , MAISONNEUVE L , et al. Bio-based aliphatic primary amines from alcohols through the 'Nitrile route' towards non-isocyanate polyurethanes[J]. European Polymer Journal, 2016, 82 (6): 114- 121.
85	GUAN J , SONG Y , LIN Y , et al. Progress in study of non-isocyanate polyurethane[J]. Industrial & Engineering Chemistry Research, 2011, 50 (11): 6517- 6527.
86	MT A , AW A , OT B , et al. Facile route to multigram synthesis of environmentally friendly non-isocyanate polyurethanes[J]. Polymer, 2015, 80 (3): 228- 236.
87	BESSE V , BOUTEVIN G , AUVERGNE R , et al. Reactivity of secondary amines for the synthesis of non-isocyanate polyurethanes[J]. European Polymer Journal, 2014, 55, 17- 26.
88	SCHMIDT S , GÖPPERT N E , BRUCHMANN B , et al. Liquid sorbitol ether carbonate as intermediate for rigid and segmented non-isocyanate polyhydroxyurethane thermosets[J]. European Polymer Journal, 2017, 94 (10): 136- 142.
89	KATHALEWAR M , SABNIS A , D'MELLO D . Isocyanate free polyurethanes from new CNSL based bis-cyclic carbonate and its application in coatings[J]. European Polymer Journal, 2014, 57 (7): 99- 108.
90	THÉBAULT M , PIZZI A , DUMARAY S , et al. Polyurethanes from hydrolysable tannins obtained without using isocyanates[J]. Industrial Crops & Products, 2014, 59 (9): 329- 336.

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