诺卜二烯的合成及应用研究进展

›› 2009, Vol. 43 ›› Issue (6): 55-59.

• 论文 • Previous Articles

Research Progress on Synthesis and Application of Nopadiene

SUI Guan-hua, ZHAO Zhen-dong, BI Liang-wu, LI Dong-mei, WANG Jing

Institute of Chemical Industry of Forest Products CAF;National Engineering Lab. for Biomass Chemical Utilization;Key and Open Lab. on Forest Chemical Engineering SFA, Nanjing 210042, China

Received:2009-08-02 Revised:1900-01-01 Online:2009-11-30 Published:2009-11-30

Abstract

Abstract: The synthesis and application of nopadiene in fine chemicals as well as in organic synthesis were reviewed. Nopadiene could be synthesized by the direct dehydration of nopol, the elimination of nopyl ethers or nopyl tosylate, the photo-degradation of nopyl thiobenzoic acid o-esters, and the reaction of nopinone with Grignard reagent, etc. Nopadiene with two conjugated double bonds can be applied as a fine chemical composition. However, the more nopadiene is applied to synthesize perfume, chiral ligand compounds through Diels-Alder reactions, or to synthesize some other related compounds through reactions with electrophilic groups, or to be polymerized as a monomer.

Key words: nopadiene, synthesis, application, Diels-Alder reaction

CLC Number:

TQ351.4

SUI Guan-hua;ZHAO Zhen-dong;BI Liang-wu;LI Dong-mei;WANG Jing. Research Progress on Synthesis and Application of Nopadiene[J]. , 2009, 43(6): 55-59.

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Research Progress on Synthesis and Application of Nopadiene

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