Biomass Chemical Engineering ›› 2023, Vol. 57 ›› Issue (4): 71-78.doi: 10.3969/j.issn.1673-5854.2023.04.009
• Review Comment • Previous Articles
Jian CHEN1, Zhiqiang PANG1, Xianqin LU1,2, Hairui JI1, Cuihua DONG1,*()
Received:
2022-06-08
Online:
2023-07-30
Published:
2023-07-08
Contact:
Cuihua DONG
E-mail:xiaodong771111@163.com
CLC Number:
Jian CHEN, Zhiqiang PANG, Xianqin LU, Hairui JI, Cuihua DONG. Efficient Conversion and Application of Biomass in Lithium Salt System[J]. Biomass Chemical Engineering, 2023, 57(4): 71-78.
Table 1
Conversion of biomass in different lithium salt solvent systems"
锂盐溶剂lithium salt solvent | 原料feedstock | 主要产物main product | 文献reference |
LiCl/DMAC | 纤维素cellulose | 纤维素凝胶cellulose gel | [ |
LiCl/HCl | 纤维素cellulose | 葡萄糖glucose | [ |
LiClO4/NaOH | 纤维素cellulose | 纤维素导电薄膜cellulose electric membrane | [ |
LiSCN·2H2O | 纤维素cellulose | 葡萄糖glucose | [ |
LiBr/H2SO4 | 纤维素cellulose | 葡萄糖glucose | [ |
LiBr | 纤维素cellulose | 杂化纤维素气凝胶hybrid cellulose aerogel | [ |
LiBr/CH3OH | 纤维素cellulose | 纤维素-壳聚糖泡沫cellulose-chitosan foams | [ |
LiBr | 纤维素cellulose | 纤维素薄膜cellulose membrane | [ |
LiCl/DMAC | 玉米秸秆corn stalk | 纤维素薄膜cellulose membrane | [ |
LiCl/DMAC | 玉米秸秆corn stalk | 纳米纤维素nanocellulose | [ |
LiBr/HCl | 木质纤维lignocellulose | 生物炭biochar | [ |
LiBr/HBr | 木质纤维lignocellulose | 糠醛furfural | [ |
1 | AJAV E A , SINGH B , BHATTACHARYA T K , et al. Experimental study of some performance parameters of a constant speed stationary diesel engine using ethanol-diesel blends as fuel[J]. Biomass & Bioenergy, 1999, 17 (4): 357- 365. |
2 | OAFA B, EAAA A, CZA C, et al. Co-pyrolysis of lignocellulosic and macroalgae biomasses for the production of biochar: A review[J/OL]. Bioresource Technology, 2020, 297, 122408[2022-05-24]. https://doi.org/10.1016/j.biortech.2019.122408. |
3 | XU S , HU Y , WANG S , et al. Investigation on the co-pyrolysis mechanism of seaweed and rice husk with multi-method comprehensive study[J]. Renewable Energy, 2018, 132, 266- 277. |
4 | 任普鲜, 蒋剑春, 杨秀山, 等. 木质纤维素快速热解产物生产燃料乙醇研究进展[J]. 生物质化学工程, 2009, 43 (3): 47- 51. |
5 | 邱盼盼, 任天宝, 王风芹, 等. 木质纤维原料蒸汽爆破-生物联合预处理及其生物脱毒研究进展[J]. 生物质化学工程, 2013, 47 (2): 23- 28. |
6 | 张筱仪, 刘慰, 刘华玉, 等. 基于低共熔溶剂的木质纤维生物质预处理及其高值化利用的研究进展[J]. 中国造纸, 2020, 39 (8): 85- 93. |
7 | 段超, 冯文英, 张艳玲. 木质生物质精炼预处理技术研究进展[J]. 中国造纸, 2013, (1): 59- 64. |
8 | 鲁俊良, 郞金燕, 杨鸿燕, 等. 深度共熔溶剂分离生物质资源提取纤维素的研究进展[J]. 中国造纸学报, 2020, 35 (1): 66- 71. |
9 | PAN X, LI S. Saccharification of ligncellulosic biomass: CN103310547A[P]. 2013-09-15. |
10 |
HALDAR D , PURKAIT M K . Lignocellulosic conversion into value-added products: A review[J]. Process Biochemistry, 2020, 89, 110- 133.
doi: 10.1016/j.procbio.2019.10.001 |
11 | 尹崇鑫, 王敏, 程金兰, 等. 助水溶剂应用在生物质精炼领域的研究进展[J]. 林产化学与工业, 2021, 41 (3): 134- 140. |
12 |
FISCHER S , FISCHER W V . The behaviour of cellulose in hydrated melts of the composition LiX·n H2O(X=I—, NO3—, CH3COO—, ClO4—)[J]. Cellulose, 1999, 6, 213- 219.
doi: 10.1023/A:1009269614096 |
13 |
LI N , PAN X , ALEXANDER J . A facile and fast method for quantitating lignin in lignocellulosic biomass using acidic lithium bromide trihydrate(ALBTH)[J]. Green Chemistry, 2016, 18, 5367- 5376.
doi: 10.1039/C6GC01090C |
14 |
YANG Y J , SHIN J M , KANG T H , et al. Cellulose dissolution in aqueous lithium bromide solutions[J]. Cellulose, 2014, 21 (3): 1175- 1181.
doi: 10.1007/s10570-014-0183-9 |
15 |
YOO C G , ZHANG S , PAN X . Effective conversion of biomass into bromomethylfurfural, furfural, and depolymerized lignin in lithium bromide molten salt hydrate of a biphasic system[J]. RSC Advances, 2017, 7 (1): 300- 308.
doi: 10.1039/C6RA25025D |
16 | LEIPNER H , FISCHER S , BRENDLER E , et al. Structural changes of cellulose dissolved in molten salt hydrates[J]. Macromolecular Chemistry & Physics, 2000, 201 (15): 2041- 2049. |
17 | SEN S , MARTIN J D , ARGYROPOULOS D S . Review of cellulose non-derivatizing solvent interactions with emphasis on activity in inorganic molten salt hydrates[J]. ACS Sustainable Chemistry & Engineering, 2013, 1 (8): 858- 870. |
18 |
DUFFY J A , INGRAM M D . Acidic nature of metal aquo complexes: Proton-transfer equilibriums in concentrated aqueous media[J]. Inorganic Chemistry, 1978, 17 (10): 2798- 2802.
doi: 10.1021/ic50188a023 |
19 | YANG Y J , SHIN J M , KANG T H , et al. Cellulose dissolution in aqueous lithium bromide solutions[J]. Cellulose, 2014, 21 (3): 1175- 1181. |
20 | LI N , LI Y , CHANG G Y , et al. An uncondensed lignin depolymerized in the solid state and isolated from lignocellulosic biomass: A mechanistic study[J]. Green Chemistry, 2018, 20 (18): 4224- 4235. |
21 | YOO C G , LI N , SWANNELL M , et al. Isomerization of glucose to fructose catalyzed by lithium bromide in water[J]. Green Chemistry, 2017, 19, 4402- 4411. |
22 | ZHU J Y, PAN X J. Efficient sugar production from plant biomass: Current status, challenges, and future directions[J/OL]. Renewable and Sustainable Energy Reviews, 2022, 164: 112583[2022-05-24]. https://doi.org/10.1016/j.rser.2022.112583. |
23 | ISHII D , TATSUMI D , MATSUMOTO T , et al. Investigation of the structure of cellulose in LiCl/DMAc solution and its gelation behavior by small-angle X-ray scattering measurements[J]. Macromolecular Bioscience, 2006, 6 (4): 293- 300. |
24 | YU P R , WEI C H , WAN H P . LiCl/HCl ionic solution for efficient conversion of lignocellulose into glucose under mild conditions[J]. Journal of the Taiwan Institute of Chemical Engineers, 2018, 93, 193- 200. |
25 | SUN T, PRAMONO E, WAHYUNINGRUM D, et al. Preparation and characterization of biopolymer blend electrolyte membranes based on derived celluloses for lithium-ion batteries separator[J/OL]. Bulletin of Materials Science, 2021, 44(104): 104[2022-05-24]. https://doi.org/10.1007/s12034-021-02369-7. |
26 | FISCHER S , LEIPNER H , BRENDLER E , et al. Molten Inorganic Salt Hydrates as Cellulose Solvents[M]. Washingto, DC: ACS Symposium Series, 1999: 143- 150. |
27 | FISCHER S, THVMMLER K. Molten Inorganic Salts as Reaction Medium for Cellulose[M]//LIEBERT T F, HEINZE T J, EDGAR K J. Cellulose Solvents: For Analysis, Shaping and Chemical Modification. Washington, DC: ACS Symposium Series. 2010: 91-101. |
28 | WEI X , HUANG T , YANG J H , et al. Green synthesis of hybrid graphene oxide/microcrystalline cellulose aerogels and their use as superabsorbents[J]. Journal of Hazardous Materials, 2017, 335 (5): 28- 38. |
29 | KIM U J , D KIM , YOU J , et al. Preparation of cellulose-chitosan foams using an aqueous lithium bromide solution and their adsorption ability for Congo red[J]. Cellulose, 2018, 25, 2615- 2628. |
30 | ZHANG X, XIAO N, WANG H, et al. Preparation and characterization of regenerated cellulose film from a solution in lithium bromide molten salt hydrate[J/OL]. Polymers, 2018, 10(6): 614[2022-05-24]. https://doi.org/10.3390/polym10060614. |
31 | HAN Q , GAO X , ZHANG H , et al. Preparation and comparative assessment of regenerated cellulose films from corn(Zea mays) stalk pulp fines in DMAc/LiCl solution[J]. Carbohydrate Polymers, 2019, 218, 315- 323. |
32 | YOUSEFI H , FAEZIPOUR M , NISHINO T , et al. All-cellulose composite and nanocomposite made from partially dissolved micro-and nanofibers of canola straw[J]. Polymer Journal, 2011, 43 (6): 559- 564. |
33 | LU X, CHEN J, LU J, et al. Monosaccharides and carbon nanosphere obtained by acidic concentrated LiBr treatment of raw crop residues via optimizing the synthesis process[J/OL]. Bioresource Technology, 2020, 310: 123522[2022-05-24]. https://doi.org/10.1016/j.biortech.2020.123522. |
34 | MCCORMICK C L , CALLAIS P A , HUTCHINSON B H . Solution studies of cellulose in lithium chloride and N, N-dimethylacetamide[J]. Macromolecules, 1985, 27 (12): 91- 92. |
35 | 王刚, 李义, 刘志刚, 等. 聚乳酸/纤维素共混复合材料的研究进展[J]. 生物质化学工程, 2019, 53 (1): 54- 60. |
36 | HUANG Z L, YU G, LIU C, et al. Ultrafast improvement of cellulose accessibility via non-dissolving pretreatment with LiBr·3H2O under room temperature[J/OL]. Carbohydrate Polymers, 2022, 284: 119180[2022-05-24]. https://doi.org/10.1016/j.carbpol.2022.119180. |
37 | KIM U J, KIMURA S, WADA M. Facile preparation of cellulose-SiO2 composite aerogels with high SiO2 contents using a LiBr aqueous solution[J/OL]. Carbohydrate Polymers, 2019, 222: 114975[2022-05-24]. https://doi.org/10.1016/j.carbpol.2019.114975. |
38 | AHMAD G, AHMAD M, OKI M, et al. Conversion of cellulose to glucose and further transformation into fuels over solid acid catalysts: A mini review[J/OL]. Microporous and Mesoporous Materials, 2022, 336: 111846[2022-05-24]. https://doi.org/10.1016/j.micromeso.2022.111846. |
39 | 张阳, 胡斌, 陆强, 等. 纤维素快速热解生成左旋葡聚糖的机理研究进展[J]. 生物质化学工程, 2014, 48 (3): 53- 59. |
40 | DANIELE F, ALLAN H F, MARCOS F S, et al. New biotechnological opportunities for C5 sugars from lignocellulosic materials[J/OL]. Bioresource Technology Reports, 2022, 17: 100956[2022-05-24]. https://doi.org/10.1016/j.biteb.2022.100956. |
41 | SARAVANAN P , JOSEPHRAJ J , THILLAINAYAGAM B P , et al. Biochar for removal of dyes in contaminated water: An overview[J]. Biochar, 2022, 4 (1): 135- 150. |
42 | YU P R , HUNG W C , WAN H P . LiCl/HCl ionic solution for efficient conversion of lignocellulose into glucose under mild conditions[J]. Journal of the Taiwan Institute of Chemical Engineers, 2018, 93, 193- 200. |
43 | DENG W , KENNEDY J R , TSILOMELEKIS G , et al. Cellulose hydrolysis in acidified libr molten salt hydrate media[J]. Industrial & Engineering Chemistry Research, 2015, 54 (19): 5226- 5236. |
44 | LI N , WANG Z , QU T , et al. High-yield synthesis of glucooligosaccharides(GlOS) as potential prebiotics from glucosevianon-enzymatic glycosylation[J]. Green Chemistry, 2019, 21 (10): 2686- 2698. |
45 | JI H , ZHU J Y , GLEISNER R . Integrated production of furfural and levulinic acid from corncob in a one-pot batch reaction incorporating distillation using step temperature profiling[J]. RSC Advances, 2017, 7 (73): 46208- 46214. |
46 | WANG J H, CUI H Y, WANG J G, et al. Kinetic insight into glucose conversion to 5-hydroxymethyl furfural and levulinic acid in LiCl·3H2O without additional catalyst[J/OL]. Chemical Engineering Journal, 2021, 415: 128922[2022-05-24]. https://doi.org/10.1016/j.cej.2021.128922. |
47 | BHAUMIK P , CHOU H J , LEE L C , et al. Chemical transformation for 5-hydroxymethylfurfural production from saccharides using molten salt system[J]. ACS Sustainable Chemistry & Engineering, 2018, 6 (5): 5712- 5717. |
48 | MIKOLA M , AHOLA J , TANSKANEN J . Production of levulinic acid from glucose in sulfolane/water mixtures[J]. Chemical Engineering Research and Design, 2019, 148, 291- 297. |
49 | CHEN J, PANG Z, ZHANG Y, et al. Efficiently conversion of raw lignocellulose to levulinic acid and lignin nano-spheres in acidic lithium bromide-water system by two-step process[J/OL]. Bioresource Technology, 2022, 343: 126130[2022-05-24]. https://doi.org/10.1016/j.biortech.2021.126130. |
50 | LU X, LIU X, ZHANG W, et al. The residue from the acidic concentrated lithium bromide treated crop residue as biochar to remove Cr(Ⅵ)[J/OL]. Bioresource Technology, 2020, 296: 122348[2022-05-24]. https://doi.org/10.1016/j.biortech.2019.122348. |
51 | ZHU Y C, WANG X, LI Z L, et al. Husbandry waste derived coralline-like composite biomass material for efficient heavy metal ions removal[J/OL]. Bioresource Technology, 2021, 337: 125408[2022-05-24]. https://doi.org/10.1016/j.biortech.2021.125408. |
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