介孔氧化硅固载Yb(OTf)3的制备及催化葡萄糖生产乳酸

doi:10.3969/j.issn.1673-5854.2019.03.003

Abstract

Abstract:

Two kinds of SBA-15 and MCM-41 mesoporous silica were prepared by solvent and calcination method, and they were used as the carrier of the supported ytterbium triflate(Yb(OTf)₃) catalysts. The carriers and catalysts were characterized by small angle X-ray diffraction(SAXD), nitrogen adsorption/desorption, ²⁹Si solid state nuclear magnetic resonance spectroscopy(NMR), transmission electron microscope(TEM) and thermogravimetric analysis(TG), and the catalytic performances of these catalysts in the preparation of lactic acid from glucose were evaluated. The experimental results showed that the amount of hydroxyl group of mesoporous silica by solvent method was higher than that of mesoporous silica by calcination method, so its catalytic activity was higher. The average pore size of SBA-15 was about 3 nm larger than that of MCM-41, which led to better mass transfer performance of SBA-15 and better catalytic performance of Yb(OTf)₂-SBA-15. The yield of lactic acid could reach 42.35% when it reacted at 2 MPa N₂ pressure and 190 ℃ for 60 min with Yb(OTf)₂-SBA-15-S as catalyst.

Key words: mesoporous silica, ytterbium triflate, glucose, lactic acid

CLC Number:

TQ35

Shiwei WANG,Qibao WANG. Preparation of Yb(OTf)₃ Immobilized on Mesoporous Silica and Its Catalytic Activity for Lactic Acid Productionfrom Glucose[J]. Biomass Chemical Engineering, 2019, 53(3): 15-23.

Figures/Tables 10

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References 29

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样品 sample	晶面间距interplanar spacing/nm			晶胞参数/nm crystal cell parameters	S_BET/ (m²·g^-1)	孔体积/(cm³·g^-1) pore volume	孔径/nm pore size
样品 sample	d₁₀₀	d₁₁₀	d₂₀₀	晶胞参数/nm crystal cell parameters	S_BET/ (m²·g^-1)	孔体积/(cm³·g^-1) pore volume	孔径/nm pore size
SBA-15-C	105.10	61.31	53.18	12.14	650.81	0.92	7.4
SBA-15-S	110.35	62.17	53.18	12.74	623.48	0.77	5.9
MCM-41-C	40.50	23.61	20.92	4.68	883.00	0.97	3.8
MCM-41-S	41.64	24.53	21.43	4.81	794.28	0.89	3.4

样品 samples	峰面积peak area			质量分数mass fraction/%
样品 samples	A₁	A₂	A₃	w_Q₁	w_Q₂
MCM-41-C	241.9	1512.1	1199.7	4.2	13.2
MCM-41-S	341.9	1672.6	824.2	6.1	14.8
SBA-15-C	192.1	1395.8	1166.5	3.6	13.1
SBA-15-S	332.1	1628.7	801.7	6.1	14.9

催化剂catalysts	n(S)/n(Si)	S/ (mmol·g^-1)	Yb/ (mmol·g^-1)
Yb(OTf)₂-SBA-15-C	21%	1.21	0.234
Yb(OTf)₂-SBA-15-S	21%	1.51	0.286
Yb(OTf)₂-MCM-41-C	21%	0.63	0.119
Yb(OTf)₂-MCM-41-S	21%	0.91	0.169

催化剂 catalysts	葡萄糖转化率/% conversation rate of glucose	收率yield/%
催化剂 catalysts	葡萄糖转化率/% conversation rate of glucose	HMF	乳酸lactic acid
Yb(OTf)₂-SBA-15-C	63.14	3.67	38.22
Yb(OTf)₂-SBA-15-S	65.29	3.24	42.35
Yb(OTf)₂-MCM-41-C	30.64	3.15	14.86
Yb(OTf)₂-MCM-41-S	34.03	3.53	16.41

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Preparation of Yb(OTf)₃ Immobilized on Mesoporous Silica and Its Catalytic Activity for Lactic Acid Productionfrom Glucose

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Preparation of Yb(OTf)3 Immobilized on Mesoporous Silica and Its Catalytic Activity for Lactic Acid Productionfrom Glucose

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Preparation of Yb(OTf)₃ Immobilized on Mesoporous Silica and Its Catalytic Activity for Lactic Acid Productionfrom Glucose