响应面法优化麦芽糖水解制备5-羟甲基糠醛

doi:10.3969/j.issn.1673-5854.2018.06.009

bce ›› 2018, Vol. 52 ›› Issue (6): 57-61.doi: 10.3969/j.issn.1673-5854.2018.06.009

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Optimization of 5-Hydroxymethylfurfural Preparation from Hydrolysis of Maltose Dehydration by Response Surface Methodology

WANG Yonggui¹, REN Shuzhi², GENG Qingbao², ZHANG Weigang¹, GE Xiutao¹

1. School of Materials and Chemical Engineering of Chuzhou University, Chuzhou 239000, China;
2. Anhui Jinhe Industrial co. LTD, Chuzhou 239000, China

Received:2017-11-02 Online:2018-11-30 Published:2018-12-12

Abstract

Abstract: The catalytic effects of phosphate, sulfuric acid, zinc acetate and sodium hydroxide catalysts on the preparation of 5-hydroxymethylfurfural(5-HMF) were investigated with maltose as raw material and water as solvent, and the results showed that the catalytic capacity of sodium hydroxide was much higher than that of other catalysts and the dosage was less. Response surface methodology(RSM) was utilized for optimization the reactive conditions with the yield of 5-HMF as yardstick. The optimum values of these factors were found to be as follows: reaction temperature 95.20 ℃, mass of sodium hydroxide 2.25 g, reaction time 6.17 h. In this case, the yield of 5-hydroxymethylfurfural reached 61.13%.The result of infrared spectrogram analysis was consistent with the standard sample,and 5-HMF was prepared from maltose.

Key words: 5-hydroxymethylfurfural, maltose, response surface methodology(RSM), carbohydrate

CLC Number:

TQ35

WANG Yonggui, REN Shuzhi, GENG Qingbao, ZHANG Weigang, GE Xiutao. Optimization of 5-Hydroxymethylfurfural Preparation from Hydrolysis of Maltose Dehydration by Response Surface Methodology[J]. bce, 2018, 52(6): 57-61.

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Optimization of 5-Hydroxymethylfurfural Preparation from Hydrolysis of Maltose Dehydration by Response Surface Methodology

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