Biomass Chemical Engineering ›› 2019, Vol. 53 ›› Issue (6): 51-58.doi: 10.3969/j.issn.1673-5854.2019.06.009
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Ze XIAO1,2,Chun CHANG1,2,*(),Jing BAI1,2,Junying CHEN1,2,Pan LI1,2,Xiuli HAN1,2
Received:
2018-11-19
Online:
2019-11-30
Published:
2019-12-10
Contact:
Chun CHANG
E-mail:chunchang@zzu.edu.cn
Supported by:
CLC Number:
Ze XIAO,Chun CHANG,Jing BAI,Junying CHEN,Pan LI,Xiuli HAN. Progress in the Synthesis of Biomass-based Glycerol Acetals and Ketals[J]. Biomass Chemical Engineering, 2019, 53(6): 51-58.
Table 1
Catalysts and reaction parameters for the reaction of glycerol with aldehydes and ketones"
催化剂catalyst | 原料及比例 raw material and ratio | 反应条件 reaction condition | 结果 result | 参考文献 reference | |
液体酸 liquid acid | H2SO4 | n(乙酰丙酸乙酯)/n(甘油)5:1 n(ethyl levulinate)/n(glycerol)5:1 | 4 kPa, 110 ℃, 26 min | 甘油转化率>99%,五元环选择性100% glycerol conversion rate 99%, five-membered ring selectivity 100% | [ |
对甲苯磺酸 p-toluene sulphonic acid | n(丙酮)/n(甘油)3:1 n(acetone)/n(glycerol)3:1 | 2 h | 甘油转化率85%,五元环选择性97% glycerol conversion 85%, five-membered ring selectivity 97% | [ | |
固体酸 solid acid | β沸石 β-zeolite | n(丙酮)/n(甘油)6:1 n(acetone)/n(glycerol)6:1 | 60 ℃, 4 h | 甘油转化率94.26% glycerol conversion 94.26% | [ |
木质素磺酸基质子酸 lignosulfonate-based protonic acid | n(乙酰丙酸甲酯)/n(甘油)4:1 n(methyl levulinate)/n(glycerol)4:1 | 100 ℃, 1 h | 甘油转化率100% glycerol conversion 100% | [ | |
磷钨酸活性炭 phosphotungstic acid activated carbon | n(甘油)/n(苯甲醛)1.1:1 n(glycerol)/n(benzaldehyde) 1.1:1 | 2 h | 六元环缩醛产率96.4% five-membered ring acetal yield 96.4% | [ | |
Cs2.5H0.5PW12O40 | n(甲醛)/n(甘油)1.2:1 n(formaldehyde)/n(glycerin) 1.2:1 | 70 ℃ | 甘油转化率90% glycerol conversion 90% | [ | |
Amberlyst-15树脂 Amberlyst-15 resin | n(丙酮)/n(甘油)2:1 n(acetone)/n(glycerol)2:1 | 70 ℃, 1 h | 甘油转化率95% glycerol conversion 95% | [ | |
蒙脱石K10-H+ montmorillonite K10-H+ | n(甘油)/n(环戊酮)1:10 n(glycerol)/n(cyclopentanone) 1:10 | 60 ℃, 2 h | 五元环缩酮产率81.4% five-membered ring ketal yield 81.4% | [ | |
SO4/SnO2 | n(环己酮)/n(甘油)1.05:1 n(cyclohexanone)/n(glycerol)1.05:1 | 90~130 ℃, 1 h | 五元环缩酮产率97.5% five-membered ring ketal yield 97.5% | [ |
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