间硝基苯磺酸钠助催化硫酸水解制备芦苇浆纳米纤维素

›› 2012, Vol. 46 ›› Issue (5): 1-6.

• 研究报告 • Next Articles

Preparation of Reed Pulp Nanocrystalline Cellulose by Sulfuric Acid Hydrolysis with Sodium m-Nitrobenzene Sulfonate as Cocatalyst

LIU Zhi-ming, XIE Cheng, WU Peng, LIU Li-yang

Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, College of Material Science and Engineering, Northeast Forestry University, Harbin 150040, China

Received:2012-03-12 Revised:1900-01-01 Online:2012-09-30 Published:2012-09-30

Abstract

Abstract: Nanocrystalline cellulose (NCC) was prepared from reed pulp with 55% (by mass fraction) sulfuric acid and using sodium m-nitrobenzene sulfonate (SMS) as cocatalyst. The effects of reaction temperature and time, the addition of SMS on the yield and the mean size of NCC were studied. The results show that the optimal reaction temperature and time are 50℃ and 3.0 h, respectively, and the additon of sodium m-nitrobenzene sulfonate is 10%(based on mass of reed pulp). Analysis of fourier transform infrared(FT-IR) spectroscopy show that the prepared NCC with optimal condition is cellulosic substance. Analysis of transmission electron microscopy(TEM) and scanning electron microscopy(SEM) show that the morphology of NCC prepared by adding SMS as cocatalyst appears more regular and rod-like. The yield of NCC with addition of SMS as cocatalyst is the highest under the same preparation technology which is compared with the cocatalyst of sodium dodecyl benzene sulfonate(SDBS) and copper sulfate(CuSO₄).

Key words: sodium m-nitrobenzene sulfonate, cocatalyst, reed pulp nanocrystalline cellulose

CLC Number:

TQ35

LIU Zhi-ming;XIE Cheng;WU Peng;LIU Li-yang. Preparation of Reed Pulp Nanocrystalline Cellulose by Sulfuric Acid Hydrolysis with Sodium m-Nitrobenzene Sulfonate as Cocatalyst[J]. , 2012, 46(5): 1-6.

[1]	Xiaopeng JIAN,Wei XU,Xinglong HOU,Shicai LIU. Research Progress on Activated Carbon Modification Technology [J]. Biomass Chemical Engineering, 2020, 54(5): 66-72.
[2]	Xue LIU,Shujun LI,Shouxin LIU,Jian LI,Zhijun CHEN. Research Progress in Preparation and Functional Application of Lignin-based Nanoparticles [J]. Biomass Chemical Engineering, 2020, 54(5): 53-65.
[3]	Weixing ZENG,Xian CHENG,Zuohui ZHANG,Liangwu BI,Zhendong ZHAO. Application Research Progress of Biological Pretreatment Technology in Extraction of Natural Products [J]. Biomass Chemical Engineering, 2020, 54(5): 45-52.
[4]	Xiaomeng QU,Ge YANG,Zehao ZHANG,Lan ZHANG. Preparation of High Purity Yacon Fructo-oligosaccharides by Nanofiltration and Its Characterization [J]. Biomass Chemical Engineering, 2020, 54(5): 37-44.
[5]	Guoqiang SONG,Huan LI,Yinmei CAO,Long TANG. Industrial Refining Process of MES Surfactant [J]. Biomass Chemical Engineering, 2020, 54(5): 33-36.
[6]	Mengmeng WANG,Lequn LIU,Zhentao LIU,Ying ZHAO. Flame Retardant Modification of Bamboo Liquefied Wall Foam Materials [J]. Biomass Chemical Engineering, 2020, 54(5): 25-32.
[7]	Peng LYU,Guanghui WANG,Bing WANG,Deyu HU. Effect of Pyrolysis Temperature and Biomass Type on Adsorption of U(Ⅵ) by Biochar [J]. Biomass Chemical Engineering, 2020, 54(5): 15-24.
[8]	Chunpo YUE,Zhiling YU,Qianhui YU,Tao WANG,Pengbo WANG,Mingwei DI. Effect of Jet Plasma Discharge in Different Atmosphere on Surface Properties of Wood-plastic Composites [J]. Biomass Chemical Engineering, 2020, 54(5): 8-14.
[9]	Zhaolan ZHAI,Pu LYU,Ping ZHAO,Zhanqian SONG,Shibin SHANG,Xiaoping RAO. Antibacterial Activity of Dehydroabietyl Nitrogen Derivatives [J]. Biomass Chemical Engineering, 2020, 54(5): 1-7.
[10]	Qiqi DAI,Xiaocui WEI,Hongbiao TANG,Jin LI,Jinjing WANG. Optimization of Microwave Assisted Pyrolysis of Coconut Clothes by Response Surface Method and Analysis of Liquid Product Composition [J]. Biomass Chemical Engineering, 2020, 54(4): 42-48.
[11]	Lin SUN,Huayu LIU,Kun LIU,Xiaoyi ZHANG,Hongxiang XIE,Rui ZHANG,Haiming LI,Chuanling SI. Research Progress in Nanocellulose Hydrophobic Modification and Applications [J]. Biomass Chemical Engineering, 2020, 54(4): 57-66.
[12]	Weijiao SHANG,Lu WANG. Status and Analysis of Nanocellulose Technology Based on Patents [J]. Biomass Chemical Engineering, 2020, 54(4): 49-56.
[13]	Ruting XU,Wei XU,Xincheng LU,Kang SUN. Novel Demineralization Technology of Phosphate-activated Carbon [J]. Biomass Chemical Engineering, 2020, 54(4): 37-41.
[14]	Yongxu LIU,Dawei ZHANG. Preparation and Properties of Bacteriostatic Chitosan/PVA/Chitosan Oligosaccharide Nanofibrous Membranes [J]. Biomass Chemical Engineering, 2020, 54(4): 30-36.
[15]	Feifei LIU,Lan WANG,Zuohu LI,Hongzhang CHEN. Dissolving Effect of Steam Exploded Corn Stalk on Phosphate Rock Powder and Influence of Its Residual on Wheat Growth [J]. Biomass Chemical Engineering, 2020, 54(4): 23-29.

Preparation of Reed Pulp Nanocrystalline Cellulose by Sulfuric Acid Hydrolysis with Sodium m-Nitrobenzene Sulfonate as Cocatalyst

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments