›› 2010, Vol. 44 ›› Issue (6): 18-22.
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CHEN Yan-ping, WANG Bi-yu, HUANG Zhi-xian, WU Yan-xiang
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Abstract: The hydration kinetics of lyral synthesis using myrac aldehyde as raw materials was studied. Reaction conditions on reaction rate constant were investigated. The optimum conditions were identified:reaction temperature 338 K, initial concentration of myrac aldehyde 0.5346mol/L and the flow rate 3.58×10-3 m/s. Kinetic data of myrac aldehyde synthesis lyral were fitted based on homogeneous reaction model. A kinetics model was gained, -rA=1.26×107CACH2Oexp(-66670/RT)-3.68×106CBexp(-57939/RT). Activation energy of the positive reaction is Ea+ 66.670 kJ/mol, and the reverse reaction is Ea- 57.939 kJ/mol. Relative deviations between the calculated values and the experimental values were all below 5%, which showed that the kinetic model could preferably describe the hydration of lyral.
Key words: myrac aldehyde, lyral, hydration, kinetics model
CLC Number:
TQ224.6
CHEN Yan-ping;WANG Bi-yu;HUANG Zhi-xian;WU Yan-xiang. Study on Kinetics Model of Synthesis of Lyral from Myrac Aldehyde[J]. , 2010, 44(6): 18-22.
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http://www.bce.ac.cn/EN/Y2010/V44/I6/18