羟基香茅醛肟及其烷基醚的合成与除草活性

doi:10.3969/j.issn.1673-5854.2021.02.009

Abstract

Abstract:

Hydroxycitronellal oxime(2) was synthesized from hydroxycitronellal(1) and hydroxylammonium chloride, and then reacted with bromoalkanes to give 4 hydroxycitronellal oxime alkyl ethers(3a-3d). The structures of the products were characterized by GC-MS, IR and NMR.The inhibitory effect of oxime and its alkyl ethers on the growth of annual ryegrass in different concentrations were determined by the plate method. The results showed that when the concentration of 3b was 0.31 mmol/L, the concentration of 3c was 0.63 mmol/L and the concentration of 3d was 2.50 mmol/L, the growth inhibition rate of the annual ryegrass roots were higher than that of diuronat the concentration of 10 mmol/L(94.1%). When the concentration of 3b and 3d were 0.31 mmol/L and the concentration of 3c was 0.63 mmol/L, the inhibitory rate on the growth of annual ryegrass stemswere higher than that of diuron at the concentration of 10 mmol/L(88.10%).

Key words: hydroxycitronellal, hydroxycitronellaloxime, oxime ether, synthesis, herbicidal activity

CLC Number:

TQ35

Yun PENG, Zhuanquan XIAO, Shengliang LIAO, Guorong FAN, Shangxing CHEN, Zongde WANG. Synthesis and Herbicidal Activity of Hydroxycitronellal Oxime and Its Alkyl Ethers[J]. Biomass Chemical Engineering, 2021, 55(2): 55-59.

Figures/Tables 2

References 15

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化合物 compound	不同浓度(mmol/L)时的根生长抑制率/% inhibition rate of root growth at different concentration (mmol/L)							不同浓度(mmol/L)时的茎生长抑制率/% inhibition rate of stem growth at different concentration (mmol/L)
化合物 compound	10	5.00	2.50	1.25	0.63	0.31	0.16	10	5.00	2.50	1.25	0.63	0.31	0.16
2	99.68	96.45	84.86	62.70	53.39	37.30	26.26	99.58	85.71	66.05	49.50	44.55	14.71	1.41
3a	100	100	100	89.90	74.96	58.71	46.41	100	100	98.22	80.78	46.26	18.86	0
3b	100	100	100	99.78	98.40	94.24	75.15	100	100	100	100	98.29	92.04	72.83
3c	99.56	98.98	100	99.00	95.90	85.50	63.70	100	100	100	99.30	93.31	85.21	63.20
3d	94.10	89.69	96.93	93.71	89.33	80.85	78.65	99.03	98.64	96.89	93.20	93.40	90.10	85.63
敌草隆diuron	94.10	92.78	91.94	89.69	87.72	85.19	85.10	88.10	75.0	73.27	71.65	63.31	57.30	49.13

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Synthesis and Herbicidal Activity of Hydroxycitronellal Oxime and Its Alkyl Ethers

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