Biomass Chemical Engineering ›› 2020, Vol. 54 ›› Issue (4): 57-66.doi: 10.3969/j.issn.1673-5854.2020.04.009
• Review Comment • Previous Articles
Lin SUN1,Huayu LIU1,Kun LIU1,Xiaoyi ZHANG1,Hongxiang XIE1,Rui ZHANG2,Haiming LI3,Chuanling SI1,*()
Received:
2020-03-30
Online:
2020-07-30
Published:
2020-08-06
Contact:
Chuanling SI
E-mail:sichli@tust.edu.cn
CLC Number:
Lin SUN,Huayu LIU,Kun LIU,Xiaoyi ZHANG,Hongxiang XIE,Rui ZHANG,Haiming LI,Chuanling SI. Research Progress in Nanocellulose Hydrophobic Modification and Applications[J]. Biomass Chemical Engineering, 2020, 54(4): 57-66.
Table 1
Summary of nanocellulose hydrophobic modification methods"
改性方法 modification method | 改性剂 modifier | 疏水效果 hydrophobic result | 参考文献 references | |
物理吸附法 physical adsorption | 吸附阳离子表面活性剂 adsorbing cationic surfactant | 十六烷基三甲基溴化铵 cetyltrimethylammonium bromide | 在CNC表面产生疏水结构域,疏水性增加 generating hydrophobic domains on the surface of CNC, increasing hydrophobicity | [ |
(1H,1H,2H,2H-十七氟癸基)三氯硅烷 (1H, 1H, 2H, 2H-heptadecafluoro decyl) trichlorosilane | 接触角超过155° contact angle over 155° | [ | ||
吸附季铵盐 adsorbing quaternary ammonium salt | 硬脂基三甲基氯化铵 stearyl trimethyl ammonium chloride | 接触角由35.8°增大到54.6° increasing contact angle from 35.8° to 54.6° | [ | |
二烯丙基二甲基氯化铵 diallyldimethylammonium chloride | 接触角由35.8°增大到48° increasing contact angle from 35.8° to 48° | [ | ||
苄基三甲基氯化铵 benzyltrimethylammonium chloride | 接触角由35.8°增大到46° increasing contact angle from 35.8° to 46° | [ | ||
季烷基铵 quaternary alkylammonium | 接触角由50°增大到100° increasing contact angle from 50° to 100° | [ | ||
季铵盐水溶液 quaternary ammonium salt solution | 接触角由17°增大到71° increasing contact angle from 17° to 71° | [ | ||
吸附二嵌段共聚物分散剂 adsorbing diblock copolymer dispersant | 聚甲基丙烯酸-2-羟乙酯 poly 2-hydroxyethyl methacrylate | 接触角由48°增大到101° increasing contact angle from 48° to 101° | [ | |
化学法 chemical | 甲硅烷基化 silylation | 三甲基氯硅烷 trimethylchlorosilane | 接触角由0°增大到138° increasing contact angle from 0° to 138° | [ |
甲基三甲氧基硅烷 methyltrimethoxysilane | 接触角最高达到160° contact angle up to 160 ° | [ | ||
三甲基氯硅烷 trimethylchlorosilane | 接触角由0°增大到117° increasing contact angle from 0° to 117° | [ | ||
甲基三甲氧基硅烷 methyltrimethoxysilane | 接触角最高达到157° contact angle up to 157° | [ | ||
烷酰化 alkanoylation | 丁酰氯 butyryl chloride | 表面羟基部分被丁酰基基团取代,在低极性体系丙酮中分散性好,疏水性能提高replacing hydroxyl groups on the surface by butyryl groups, good dispersibility in low-polarity acetone and better hydrophobic properties | [ | |
10-十一碳烯酰氯 10-undecenoyl chloride | 疏水性能提高 hydrophobic properties increased | [ | ||
酯化 esterification | 乳酸 lactic acid | CNF的羟基与乳酸的羧基之间发生酯化反应,疏水性能提高 occuring esterification reaction between the hydroxyl group of cnf and the carboxyl group of lactic acid, better hydrophobic properties | [ | |
醋酸 acetic acid | 接触角由23°增大到45° increasing contact angle from 23° to 45° | [ | ||
聚合物接枝法 polymer graft | 2-(二甲基氨基)甲基丙烯酸乙酯 2-(dimethylamino) ethyl methacrylate | 接触角从70°增大到140° increasing contact angle from 70° to 140° | [ | |
聚己内酯二醇 polycaprolactone diol | 改性后的复合材料在水中聚集并漂浮在水面上,在疏水性氯仿中分散性好,疏水性能提高the modified composite material aggregating and floating in water, and good dispersion in hydrophobic chloroform, better hydrophobic properties | [ | ||
N, N-二甲基氨基-2-甲基丙烯酸甲酯 N, N-dimethylamino-2-ethyl methacrylate | 接触角最高达到130° contact angle up to 130° | [ | ||
聚甲基丙烯酸甲酯 polymethylmethacrylate | 接触角最高达到96° contact angle up to 96° | [ | ||
聚丙烯酸甲酯 polymethyl acrylate | 接枝后纳米纤维素的分散程度比接枝前纳米纤维素的好,疏水性能提高 increasing the degree of dispersion of nanocellulose after grafting, better hydrophobic properties | [ |
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