蒲草叶基活性炭的制备及性能研究

doi:10.3969/j.issn.1673-5854.2020.03.002

Abstract

Abstract:

Activated carbon(CL-AC) was prepared from cattail leaves(CL) by two-step procedures using CO₂ as activation agent.The structure and morphology of CL-AC were characterized by scanning electron microscopy and nitrogen adsorption.The activated carbon(CL-AC3) obtained under activation temperature 800 ℃ and activation time 20 min had the maximum specific surface area(570.03 m²/g).And CL-AC3 resulted in outstanding capacitance retention of 90.56% over 5 000 cycles.The specific capacitance reached 111 F/g at the current density of 0.5 A/g.The adsorption conditions of methylene blue on CL-AC3 were optimized by single factor test and the optimum conditions were absorbent 12.5 mg, initial mass concentration of methylene blue 50 mg/L, temperature 303.15 K and time 300 min, under these conditions the adsorption capacity reached 199.22 mg/g.The adsorption process and equilibrium of methylene blue on CAC closely obeyed the pseudo-second-order kinetic model and Langmuir isotherm.The adsorption was endothermic, spontaneous, and a physically controlled process.

Key words: cattail-leaf-based activated carbon, electrochemical, adsorption, methylene blue

CLC Number:

TQ35
TQ91

Yao LI,Miao YU,Dong LYU,Lijuan WANG. Preparation and Properties of Cattail-leaf-based Activated Carbon[J]. Biomass Chemical Engineering, 2020, 54(3): 9-17.

Figures/Tables 14

Table 1

Fig.1

Fig.2

Fig.3

Fig.4

Fig.5

Fig.6

Fig.7

Fig.8

Fig.9

Fig.10

Table 2

Fig.11

Table 3

References 21

1	AHMED M.B , JOHIR M A H , ZHOU J L , et al. Activated carbon preparation from biomass feedstock:Clean production and carbon dioxide adsorption[J]. Journal of Cleaner Production, 2019, 225, 405- 413. doi: 10.1016/j.jclepro.2019.03.342
2	BODLEY J W , UPHAM R , CROW F W , et al. Ribosyl-diphthamide:Confirmation of structure by fast atom bombardment mass spectrometry[J]. Archives of Biochemistry and Biophysics, 1984, 230 (2): 590- 593. doi: 10.1016/0003-9861(84)90439-9
3	CAO Z , HE Y H , SUN L X , et al. Study of control for phenol and chlorophenols sudden pollution in drinking water by using PAC adsorption[J]. Advanced Materials Research, 2011, 236/237/238, 2410- 2413.
4	WANG C , WANG J , WU W T , et al. Feasibility of activated carbon derived from anaerobic digester residues for supercapacitors[J]. Journal of Power Sources, 2019, 412, 683- 688. doi: 10.1016/j.jpowsour.2018.11.092
5	MENG L , WU Y H , ZHANG T , et al. Highly conductive NiSe₂ nanostructures for all-solid-state battery-supercapacitor hybrid devices[J]. Journal of Materials Science, 2018, 54 (1): 571- 581.
6	GRANT G.A , FISHER P R , BARRETT J E , et al. Removal of agrichemicals from water using granular activated carbon filtration[J]. Water, Air, & Soil Pollution, 2019, 230, 7.
7	GUPTA H , SINGH S . Kinetics and thermodynamics of phenanthrene adsorption from water on orange rind activated carbon[J]. Environmental Technology & Innovation, 2018, 10, 208- 214.
8	SHAHRAKI Z.H , SHARIFIFARD H , LASHANIZADEGAN A . Grape stalks biomass as raw material for activated carbon production:Synthesis, characterization and adsorption ability[J]. Materials Research Express, 2018, 5 (5): 055603. doi: 10.1088/2053-1591/aac1cd
9	MISNON I I , ZAIN N K M , JOSE R . Conversion of oil palm kernel shell biomass to activated carbon for supercapacitor electrode application[J]. Waste and Biomass Valorization, 2019, 10, 1731- 1740. doi: 10.1007/s12649-018-0196-y
10	LEE K S , PARK C W , KIM J D . Synthesis of ZnO/activated carbon with high surface area for supercapacitor electrodes[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2018, 555, 482- 490. doi: 10.1016/j.colsurfa.2018.06.077
11	LI S Z , WEN J , MO X M , et al. Three-dimensional MnO₂ nanowire/ZnO nanorod arrays hybrid nanostructure for high-performance and flexible supercapacitor electrode[J]. Journal of Power Sources, 2014, 256, 206- 211. doi: 10.1016/j.jpowsour.2014.01.066
12	WEI X J , LI Y B , GAO S Y . Correction:Biomass-derived interconnected carbon nanoring electrochemical capacitors with high performance in both strongly acidic and alkaline electrolytes[J]. Journal of Materials Chemistry A, 2017, 5 (38): 20505. doi: 10.1039/C7TA90196H
13	LIAO H W , WANG Z H . Adsorption removal of amaranth by nanoparticles-composed Cu₂O microspheres[J]. Journal of Alloys and Compounds, 2018, 769, 1088- 1095. doi: 10.1016/j.jallcom.2018.08.088
14	WANG H Y , ZHU T L , FAN X , et al. Adsorption and desorption of small molecule volatile organic compounds over carbide-derived carbon[J]. Carbon, 2014, 67, 712- 720. doi: 10.1016/j.carbon.2013.10.063
15	QU W H , XU Y Y , LU A H , et al. Converting biowaste corncob residue into high value added porous carbon for supercapacitor electrodes[J]. Bioresour Technol, 2015, 189, 285- 291. doi: 10.1016/j.biortech.2015.04.005
16	王迎亚, 施华珍, 张寒冰, 等. 磁性柠檬酸膨润土对六价铬吸附性能的研究[J]. 高等化学工程学报, 2017, 31 (3): 726- 732.
17	ALTINISIK A , GÜR E , SEKI Y . A natural sorbent, Luffa cylindrica for the removal of a model basic dye[J]. Journal of Hazardous Materials, 2010, 179 (1/2/3): 658- 664.
18	DJEDOUANI D , CHABANI M , AMRANE A , et al. Adsorption kinetics of oxytetracycline onto activated carbon in a closed-loop fixed bed reactor[J]. International Journal of Chemical Reactor Engineering, 2013, 11 (1): 569- 576. doi: 10.1515/ijcre-2013-0083
19	HO Y S , MCKAY G . Pseudo-second order model for sorption processes[J]. Process Biochemistry, 1999, 34 (5): 451- 465. doi: 10.1016/S0032-9592(98)00112-5
20	TONG D S , WU C W , ADEBAJOB M O , et al. Adsorption of methylene blue from aqueous solution onto porous cellulose-derived carbon/montmorillonite nanocomposites[J]. Applied Clay Science, 2018, 161, 256- 264. doi: 10.1016/j.clay.2018.02.017
21	HAMEED B H , TAN I A W , AHMAD A L . Adsorption isotherm, kinetic modeling and mechanism of 2, 4, 6-trichlorophenol on coconut husk-based activated carbon[J]. Chemical Engineering Journal, 2008, 144 (2): 235- 244.

样品 sample	活化温度/ ℃ activated temperaure	活化时间/ min activated time	比表面积/ (m²· g ^{- 1}) specific surface area	Langmuir面积/ (m²· g ^{- 1}) Langmuir area	微孔面积/ (m²· g ^{- 1}) micropore area	总体积/ (cm³· g ^{- 1}) total volume	微孔体积/ (cm³· g ^{- 1}) micropore volume	孔径/ nm pore size
CL-AC1	750	20	464.88	685.13	356.44	0.2487	0.1873	2.1399
CL-AC2	750	40	466.05	689.01	337.03	0.2636	0.1772	2.2624
CL-AC3	800	20	570.03	844.31	396.12	0.3308	0.2082	2.3215
CL-AC4	800	40	115.25	171.34	72.90	0.0667	0.0389	2.3148

温度/ K temperature	Langmuir			Freundlich
温度/ K temperature	K_L / (L· mg ^{- 1})	q_m / (mg· g ^{- 1})	R²	K_F / (L· g ^{- 1})	1 / n	R²
303.15	0.630	255.0669	0.99198	205.7621	0.04294	0.78567
313.15	0.492	334.1031	0.99581	232.9911	0.07375	0.95257
323.15	0.405	406.8166	0.96516	278.8405	0.06529	0.77889

温度/ K temperature	准一级动力学 pseudo-first-order			准二级动力学 pseudo-second-order			颗粒内扩散 intraparticle diffusion
温度/ K temperature	K₁ / min ^{- 1}	q_{e, cal} / (mg· g ^{- 1})	R²	K₂ /(mq· g ^{- 1}·min ^{- 1})	q_{e, cal} / (mg· g ^{- 1})	R²	K_i1 /(mg· g ^{- 1}· min ^{- 0.5}	R²	K_i2 /(mg· g ^{- 1}· min ^{- 0.5}	R²	K_i3 /(mg· g ^{- 1}· min ^{- 0.5}	R²
303.15	0.00815	39.98	0.964	0.000479	202.43	0.999	8.306	0.933	4.492	0.961	1.795	0.926
313.15	0.0321	82.14	0.961	0.001167	202.84	1.000	8.553	0.940	3.149	0.900	0.209	0.895
323.15	0.0289	16.24	0.967	0.004477	200.80	1.000	9.220	0.937	0.578	0.970	0.059	0.851

[1]	Peng LYU,Guanghui WANG,Bing WANG,Deyu HU. Effect of Pyrolysis Temperature and Biomass Type on Adsorption of U(Ⅵ) by Biochar [J]. Biomass Chemical Engineering, 2020, 54(5): 15-24.
[2]	Jie REN,Li WAN,Nanwei CHEN,Fan YANG,Shuiyu SUN,Suizhou REN. Preparation and Characterization of Activated Carbon from Coffee Grounds and Its Adsorption Mechanism for Cr(Ⅵ) [J]. Biomass Chemical Engineering, 2020, 54(4): 1-8.
[3]	Shuaishuai CHANG,Xueyang ZHANG,Hongbo WANG,Mei LI,Zhenzhen TAN. Preparation of Biochar from Sawdust and It's Adsorption Property on Pb²⁺ [J]. Biomass Chemical Engineering, 2020, 54(3): 37-44.
[4]	Jianan WANG,Ying YI,Yongjun BIAN,Yuanyuan MA,Zhiming LIU. Preparation, Characterization and Adsorption Performance of Hydroxymethylated Lignin/Cellulose Aerogel Particles [J]. Biomass Chemical Engineering, 2020, 54(1): 16-22.
[5]	Congjing DENG,Huanhuan MA,Jianbin ZHOU. Characterization of Modified Apricot Shell Activated Carbon and Its Adsorption Properties on Ethylene [J]. Biomass Chemical Engineering, 2019, 53(5): 1-8.
[6]	Xuemei LIU,Chuang MA,Jiaxi TAO. Preparation of Oxalic Acid Modified Bagasse Carbon and Its Adsorption Characteristics for Cr(Ⅵ) [J]. Biomass Chemical Engineering, 2019, 53(4): 37-44.
[7]	Kechun LI,Jianfang LU,Fuhou LEI,Juying ZHOU,Haitang XU,Yanzhi ZHAO. Structural Characterization of Rosin-based Magnetic Microspheres and Their Adsorption Properties of Cr(Ⅵ) [J]. Biomass Chemical Engineering, 2019, 53(1): 17-24.
[8]	YANG Xinzhou, TIAN Xianjiao, MA Yanfen, YANG Qi. Adsorptive Performance of Mikania micrantha Powder on Methylene Blue and Basic Fuchsin [J]. bce, 2018, 52(6): 45-50.
[9]	MA Yu, LI Hui, HE Wen, YU Jintao, XIAO Shuning, TAN Wenying. Adsorption Properties of Cr(Ⅵ) on Modified Chestnut Envelope Split [J]. bce, 2018, 52(4): 23-28.
[10]	LI Man, CAI Zhaosheng, FANG Guigan, LIANG Long, ZHOU Jing. Preparation and Adsorption of Methyl Orange Imprinted Magnetic Chitosan Polymer [J]. bce, 2018, 52(3): 1-8.
[11]	LIN Xing, YANG Xuan, CAI Zhenghan, LIN Guanfeng, LI Yuhua, HUANG Biao. Activated Carbon Prepared with Phosphoric Acid Activation by Mechanical Force Pretreatment Method and Conventional Method [J]. bce, 2018, 52(3): 29-34.
[12]	LI Xin, ZHOU Jin, LAI Chenhuan, YONG Qiang. Selective Adsorption of Native Inulinase by Jerusalem Artichoke Residue and Preparation of Short-chain Fructooligosaccharides [J]. bce, 2017, 51(6): 33-37.
[13]	HUANG Li, YANG Hua, SUN Kang, LIU Shicai. Kinetics of Butanone Adsorption on Activated Carbon [J]. bce, 2017, 51(5): 29-35.
[14]	YU Ying, SUN Xiantao, CHEN Jianqiu, MING Guangqi, SHANG Jingge. Adsorption of Cefradine on Activated Carbon Prepared from Chinese Medicine Residue [J]. bce, 2017, 51(4): 25-32.
[15]	ZHU Xuehuan, YANG Rendang, LIU Xiao. Synthesis of Sulfur-modified Chitosan Aerogel and Its Adsorption Properties for Cu²⁺ [J]. bce, 2017, 51(3): 1-6.

Preparation and Properties of Cattail-leaf-based Activated Carbon

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 14

References 21

Related Articles 15

Recommended Articles

Metrics

Comments