Biomass Chemical Engineering ›› 2022, Vol. 56 ›› Issue (4): 39-48.doi: 10.3969/j.issn.1673-5854.2022.04.006
• Review Comment • Previous Articles Next Articles
Haihong XIA1,2, Minghao ZHOU1,2,3, Changzhou CHEN1,2, Peng LIU1,2, Jing LI1,2, Jianchun JIANG1,2,*()
Received:
2021-03-30
Online:
2022-07-30
Published:
2022-07-23
Contact:
Jianchun JIANG
E-mail:jiangjc@icifp.cn
CLC Number:
Haihong XIA, Minghao ZHOU, Changzhou CHEN, Peng LIU, Jing LI, Jianchun JIANG. Research Progress on Furfural Hydrogenation Using Metal Catalysis in Aqueous Medium[J]. Biomass Chemical Engineering, 2022, 56(4): 39-48.
Table 1
Catalytic performances of Cu-based catalysts for the conversion of FFR to CPO/CPL"
催化剂 catalyst | 溶剂 solvent | 压力/MPa pressure | 温度/℃ temperature | 时间/h time | 转化率/% conversion | 产物 product | 产率/% yield | 参考文献 reference |
Cu-Ni/SBA-15 | H2O | 4 | 160 | 4 | >99 | CPO | 61 | [ |
CuNiAl氧化物oxidate | H2O | 4 | 130 | 8 | 100 | CPO | 95.8 | [ |
CuZnAl氧化物oxidate | H2O | 4 | 150 | 6 | 97.9 | CPO | 60.3 | [ |
Cu/Co3O4 | H2O | 2 | 170 | 1 | 100 | CPO | 67 | [ |
Cu/Ni@C | H2O | 5 | 130 | 5 | 99.3 | CPO | 96.9 | [ |
Cu-Zn/CNT | H2O | 4 | 140 | 10 | 95.1 | CPO | 85.3 | [ |
Cu/ZnO | H2O | 4 | 140 | 6 | 100 | CPO | 82 | [ |
CuMgAl氧化物oxidate | H2O | 4 | 140 | 10 | 98.5 | CPL | 93.4 | [ |
CuZnAl氧化物oxidate | H2O | 4 | 150 | 10 | 100 | CPL | 84 | [ |
Table 2
Catalytic performances of Ni-based catalysts for the conversion of FFR to CPO/CPL"
催化剂 catalyst | 溶剂 solvent | 压力/MPa pressure | 温度/℃ temperature | 时间/h time | 转化率/% conversion | 产物 product | 产率/% yield | 参考文献 references |
Ni/HY | H2O | 4 | 150 | 9 | 96.4 | CPO | 83.4 | [ |
NiSAT 320 RS | H2O | 8 | 175 | 0.5 | 98.3 | CPO | 61 | [ |
Ni/SiO2-Al2O3 | H2O | 8 | 175 | 0.5 | 100 | CPO | 57.3 | [ |
NiCu/SBA-15 | H2O | 4 | 160 | 4 | 99 | CPO | 62 | [ |
雷尼镍Raney Ni | H2O(MeOH) | 1 | 180 | 4 | 97.8 | CPO | 38.1 | [ |
Ni/CNT | H2O | 5 | 140 | 10 | 96.5 | CPL | 83.6 | [ |
NiMo/CNT | H2O | 5 | 150 | 6 | 100 | CPL | 88.6 | [ |
Table 3
Catalytic performances of Co-based catalysts for the conversion of FFR to CPO/CPL"
催化剂 catalyst | 溶剂 solvent | 压力/MPa pressure | 温度/℃ temperature | 时间/h time | 转化率/% conversion | 产率/% yield | 参考文献 references |
Co/ZrO2 | H2O | 2 | 160 | 4 | 100 | 68(CPL) | [ |
Co/ZrO2-La2O3 | H2O | 2 | 160 | 4 | 100 | 82(CPL) | [ |
Ni-Co/TiO2 | H2O | 150 | 4 | 100 | 75.5(CPL) | [ | |
CuCo@C | H2O | 0.5 | 150 | 9 | 100 | 90.2(CPO) | [ |
Table 5
Catalytic performances of Ru-based catalysts for the conversion of FFR to CPO"
催化剂 catalyst | 溶剂 solvent | 压力/MPa pressure | 温度/℃ temperature | 时间/h time | 转化率/% conversion | 产率/% yield | 参考文献 reference |
5% Ru/C | H2O | 3 | 175 | 1 | 100 | 57.3 | [ |
Ru/MIL-101 | H2O | 4 | 160 | 2.5 | 99 | 95 | [ |
3% Ru/C | H2O | 4 | 160 | 2.5 | 72 | 28.8 | [ |
6% Ru/CNT | H2O | 1 | 160 | 5 | 99 | 90.1 | [ |
1 |
ROBINSON A M , HENSLEY J E , MEDLIN J W . Bifunctional catalysts for upgrading of biomass-derived oxygenates: A review[J]. ACS Catalysis, 2016, 6 (8): 5026- 5043.
doi: 10.1021/acscatal.6b00923 |
2 |
SETTLE A E , BERSTIS L , RORRER N A , et al. Heterogeneous Diels-Alder catalysis for biomass-derived aromatic compounds[J]. Green Chemistry, 2017, 19, 3468- 3492.
doi: 10.1039/C7GC00992E |
3 |
ZAKZESKI J , BRUIJNINCX P C A , JONGERIUS A L , et al. The catalytic valorization of lignin for the production of renewable chemicals[J]. Chemical Reviews, 2010, 110 (6): 3552- 3599.
doi: 10.1021/cr900354u |
4 |
ZHU R , WANG B , CUI M S , et al. Chemoselective oxidant-free dehydrogenation of alcohols in lignin using Cp*Ir catalysts[J]. Green Chemistry, 2016, 18, 2029- 2036.
doi: 10.1039/C5GC02347E |
5 |
SHUAI L , LUTERBACHER J . Organic solvent effects in biomass conversion reactions[J]. ChemSusChem, 2016, 9 (2): 133- 155.
doi: 10.1002/cssc.201501148 |
6 | KUCHEROV F A , ROMASHOV L V , GALKIN K I , et al. Chemical transformations of biomass-derived C6-furanic platform chemicals for sustainable energy research, materials science, and synthetic building blocks[J]. ACS Sustainable Chemistry & Engineering, 2018, 6 (7): 8064- 8092. |
7 |
GALLEZOT P . Conversion of biomass to selected chemical products[J]. Chemical Society Reviews, 2012, 41, 1538- 1558.
doi: 10.1039/C1CS15147A |
8 |
SUN Z H , FRIDRICH B , DE SANTI A , et al. Bright side of lignin depolymerization: Toward new platform chemicals[J]. Chemical Reviews, 2018, 118 (2): 614- 678.
doi: 10.1021/acs.chemrev.7b00588 |
9 | CLIMENT M J , CORMA A , IBORRA S . Conversion of biomass platform molecules into fuel additives and liquid hydrocarbon fuels[J]. Green Chemistry, 2014, 45 (13): 516- 547. |
10 | HUANG Y B , FU Y . Hydrolysis of cellulose to glucose by solid acid catalysts[J]. Green Chemistry, 2013, 44 (31): 1095- 1111. |
11 | ZHAI Q L , LONG F , HSE C Y , et al. Facile fractionation of bamboo wood toward biomass valorization by p-TsOH-based methanolysis pretreatment[J]. ACS Sustainable Chemistry & Engineering, 2019, 7 (23): 19213- 19224. |
12 | LANGE J P . Lignocellulose conversion: An introduction to chemistry, process and economics[J]. Biofuels Bioproducts & Biorefining, 2007, 1 (1): 39- 48. |
13 | 张展硕, 尹钰, 马春燕, 等. 戊内酯/水体系中磷钨酸铝催化葡萄糖转化制备5-HMF[J]. 林产化学与工业, 2021, 42 (1): 29- 35. |
14 | HU Y S , CHENG Q R , WANG Y , et al. Investigation of biomass gasification potential in syngas production: Characteristics of dried biomass gasification using steam as the gasification agent[J]. Energy & Fuels, 2020, 34 (1): 1033- 1040. |
15 |
吴媛, 王子华, 常春, 等. 醇/水体系中混酸催化葡萄糖醇解制备乙酰丙酸甲酯[J]. 林产化学与工业, 2021, 41 (2): 39- 46.
doi: 10.3969/j.issn.0253-2417.2021.02.006 |
16 |
BOZELL J J , PETERSEN G R . Technology development for the production of biobased products from biorefinery carbohydrates-the US department of energy's "top 10" revisited[J]. Green Chemistry, 2010, 12, 539- 554.
doi: 10.1039/b922014c |
17 |
ISIKGOR F H , BECER C R . Lignocellulosic biomass: Asustainable platform for the production of bio-based chemicals and polymers[J]. Polymer Chemistry, 2015, 6 (25): 4497- 4559.
doi: 10.1039/C5PY00263J |
18 | WERPY T , PETERSEN G , ADEN A , et al. Top Value Added Chemicals From Biomass.Volume Ⅰ: Results Of Screening For Potential Candidates From Sugars And Synthesis Gas[M]. Oak Ridge: Pacific Northwest National Laboratory/U.S.Department of Energy, 2004. |
19 |
CHEN C Z , LIU P , ZHOU M H , et al. Selective Hydrogenation of phenol to cyclohexanol over Ni/CNT in the absence of external hydrogen[J]. Energies, 2020, 13 (4): 846- 858.
doi: 10.3390/en13040846 |
20 | ZHOU X Y , FENG Z P , GUO W W , et al. Hydrogenation and hydrolysis of furfural to furfuryl alcohol, cyclopentanone, and cyclopentanol with a heterogeneous copper catalyst in water[J]. Industrial & Engineering Chemistry Research, 2019, 58 (10): 3988- 3993. |
21 |
DURNDELL L J , ZOU G C , SHANGGUAN W F , et al. Structure-reactivity relations in ruthenium catalysed furfural hydrogenation[J]. ChemCatChem, 2019, 11 (16): 3927- 3932.
doi: 10.1002/cctc.201900481 |
22 |
CHEN S , WOJCIESZAK R , DUMEIGNIL F , et al. How catalysts and experimental conditions determine the selective hydroconversion of furfural and 5-hydroxymethylfurfural[J]. Chemical Reviews, 2018, 118 (22): 11023- 11117.
doi: 10.1021/acs.chemrev.8b00134 |
23 | DAUTZENBERG G , GERHARDT M , KAMM B . Bio based fuels and fuel additives from lignocellulose feedstock via the production of levulinic acid and furfural[J]. Holzforschung, 2011, 65 (4): 439- 451. |
24 |
LANGE D J P , HEIDE D E , BUIJTENEN D J , et al. Furfural-apromising platform for lignocellulosic biofuels[J]. ChemSusChem, 2012, 5 (1): 150- 166.
doi: 10.1002/cssc.201100648 |
25 |
RAMIREZ-BARRIA C , ISAACS M , WILSON K , et al. Optimization of ruthenium based catalysts for the aqueous phase hydrogenation of furfural to furfuryl alcohol[J]. Applied Catalysis A: General, 2018, 563, 177- 184.
doi: 10.1016/j.apcata.2018.07.010 |
26 | XU L, NIE R F, LYU X L, et al. Selective hydrogenation of furfural to furfuryl alcohol without external hydrogen over N-doped carbon confined Co catalysts[J/OL]. Fuel Processing Technology, 2020, 197: 106205[2021-03-20]. https://doi.org/10.1016/j.fuproc.2019.106205. |
27 | MENG X Y , YANG Y S , CHEN L F , et al. A control over hydrogenation selectivity of furfural via tuning exposed facet of Ni catalysts[J]. ACS Catalysis, 2019, 9 (5): 4226- 4235. |
28 | LI Z X, WEI X Y, YANG Z, et al. Highly selective hydrogenation of furfural to furan-2-ylmethanol over a Cu/C derived from copper-organic frameworks[J/OL]. Catalysis Communications, 2019, 129: 105679[2021-03-20]. https://doi.org/10.1016/j.catcom.2019.04.011. |
29 | 陈成, 施岩, 李亚如, 等. Ni-Co/TiO2对糠醛制环戊酮、环戊醇的催化性能[J]. 化学通报, 2019, 82 (10): 937- 941. |
30 | 李玉娜, 刘自力, 左建良, 等. Ni-Cu-B非晶态合金催化剂的制备及其催化糠醛选择性加氢制备环戊酮[J]. 高校化学工程学报, 2017, 31 (1): 74- 82. |
31 | 王明远, 冷一欣, 黄春香, 等. 磷化镍的制备及其催化糠醛加氢制备环戊酮[J]. 精细化工, 2018, 35 (11): 1893- 1899. |
32 | CAO Y L , ZHANG H P , LIU K K , et al. Biowaste-derived bimetallic Ru-MoOx catalyst for the direct hydrogenation of furfural to tetrahydrofurfuryl alcohol[J]. ACS Sustainable Chemistry & Engineering, 2019, 7 (15): 12858- 12866. |
33 |
LONG Y , SONG S Y , LI J , et al. Pt/CeO2@MOF core@shell nanoreactor for selective hydrogenation of furfural via the channel screening effect[J]. ACS Catalysis, 2018, 8 (9): 8506- 8512.
doi: 10.1021/acscatal.8b01851 |
34 | 洪海梅. Pd负载双金属氰化物高收率催化糠醛转化为环戊酮[J]. 江西化工, 2019, (2): 18- 23. |
35 | LIU L , CONCEPCION P , CORMA A . Non-noble metal catalysts for hydrogenation: A facile method for preparing Co nanoparticles covered with thin layered carbon[J]. Journal of Catalysis, 2016, 340, 1- 9. |
36 | RYABCHUK P, AGOSTINI G, POHL M M, et al. Intermetallic nickel silicide nanocatalyst: A non-noble metal-based general hydrogenation catalyst[J/OL]. Science Advances, 2018, 4(6): eaat0761[2021-03-20]. https://doi.org/10.1126/sciadv.aat0761. |
37 | FILONENKO G A , PUTTEN R , HENSEN E J M , et al. Catalytic(de)hydrogenation promoted by non-precious metals - Co, Fe and Mn: recent advances in an emerging field[J]. Chemical Society Reviews, 2018, 47 (4): 1459- 1483. |
38 | DAILLARD S , RENAUD J L . Iron-catalyzed hydrogenation, hydride transfer, and hydrosilylation: An alternative to precious-metal complexes?[J]. ChemSusChem, 2008, 1 (6): 505- 509. |
39 | TAN J J , CUI J L , ZHU Y L , et al. Complete aqueous hydrogenation of 5-hydroxymethylfurfural at room temperature over bimetallic RuPd/graphene catalyst[J]. ACS Sustainable Chemistry & Engineering, 2019, 7 (12): 10670- 10678. |
40 | LIU Y , LI Y , ANDERSON J A , et al. Comparison of Pd and Pd 4 S based catalysts for partial hydrogenation of external and internal butynes[J]. Journal of Catalysis, 2020, 383, 51- 59. |
41 | VERMA D , INSYANI R , CAHYADI H S , et al. Ga-doped Cu/H-nanozeolite-Y catalyst for selective hydrogenation and hydrodeoxygenation of lignin-derived chemicals[J]. Green Chemistry, 2018, 20 (14): 3253- 3270. |
42 | YANG Y L , DU Z T , HUANG Y Z , et al. Conversion of furfural into cyclopentanone over Ni-Cu bimetallic catalysts[J]. Green Chemistry, 2013, 15 (7): 1932- 1940. |
43 | ZHU H Y , ZHOU M H , ZENG Z , et al. Selective hydrogenation of furfural to cyclopentanone over Cu-Ni-Al hydrotalcite-based catalysts[J]. Korean Journal of Chemical Engineering, 2014, 31 (4): 593- 597. |
44 | GUO J H , XU G Y , HAN Z , et al. Selective conversion of furfural to cyclopentanone with CuZnAl catalysts[J]. Acs Sustainable Chemistry & Engineering, 2014, 2 (10): 2259- 2266. |
45 | LI X L , DENG J , SHI J , et al. Selective conversion of furfural to cyclopentanone or cyclopentanol using different preparation methods of Cu-Co catalysts[J]. Green Chemistry, 2015, 17 (2): 1038- 1046. |
46 | WANG Y , SANG S Y , ZHU W , et al. CuNi@C catalysts with high activity derived from metal-organic frameworks precursor for conversion of furfural to cyclopentanone[J]. Chemical Engineering Journal, 2016, 299, 104- 111. |
47 | ZHOU M H , LI J , WANG K , et al. Selective conversion of furfural to cyclopentanone over CNT-supported Cu based catalysts: Model reaction for upgrading of bio-oil[J]. Fuel, 2017, 202, 1- 11. |
48 | WANG Y , ZHU W , SANG S Y , et al. Supported Cu catalysts for the hydrogenation of furfural in aqueous phase: Effect of support[J]. Asia-Pacific Journal of Chemical Engineering, 2017, 12 (3): 422- 431. |
49 | ZHOU M H , ZENG Z , ZHU H Y , et al. Aqueous-phase catalytic hydrogenation of furfural to cyclopentanol over Cu-Mg-Al hydrotalcites derived catalysts: Model reaction for upgrading of bio-oil[J]. Journal of Energy Chemistry, 2014, 23 (1): 91- 96. |
50 | WANG Y , ZHOU M H , WANG T Z , et al. Conversion of furfural to cyclopentanol on Cu/Zn/Al catalysts derived from hydrotalcite-like materials[J]. Catalysis Letters, 2015, 145 (8): 1557- 1565. |
51 | LIU C Y , WEI R P , GENG G L , et al. Aqueous-phase catalytic hydrogenation of furfural over Ni-bearing hierarchical Y zeolite catalysts synthesized by a facile route[J]. Fuel Processing Technology, 2015, 134, 168- 174. |
52 | HRONEC M , FULAJTAROVA K , LIPTAJ T . Effect of catalyst and solvent on the furan ring rearrangement to cyclopentanone[J]. Applied Catalysis A: General, 2012, 437/438, 104- 111. |
53 | XU Y , QIU S B , LONG J X , et al. In situ hydrogenation of furfural with additives over a RANEY(R) Ni catalyst[J]. RSC Advances, 2015, 5 (111): 91190- 91195. |
54 | ZHOU M H , TIAN L F , NIU L , et al. Upgrading of liquid fuel from fast pyrolysis of biomass over modified Ni/CNT catalysts[J]. Fuel Processing Technology, 2014, 126, 12- 18. |
55 | ZHOU M H , ZHU H Y , NIU L , et al. Catalytic hydroprocessing of furfural to cyclopentanol over Ni/CNTs catalysts: Model reaction for upgrading of bio-oil[J]. Catalysis Letters, 2014, 144 (2): 235- 241. |
56 | MA Y F , WANG H , XU G Y , et al. Selective conversion of furfural to cyclopentanol over cobalt catalysts in one step[J]. Chinese Chemical Letters, 2017, 28 (6): 1153- 1158. |
57 | 陈成, 鲍伟, 兰奕, 等. 镍-钴/二氧化钛催化剂制备及糠醛水相加氢反应中的催化性能[J]. 精细石油化工, 2019, 36 (5): 17- 21. |
58 | GONG W B , CHEN C , ZHANG H M , et al. In situ synthesis of highly dispersed Cu-Co bimetallic nanoparticles for tandem hydrogenation/rearrangement of bioderived furfural in aqueous-phase[J]. ACS Sustainable Chemistry & Engineering, 2018, 6 (11): 14919- 14925. |
59 | HRONEC M , FULAJTAROVA K . Selective transformation of furfural to cyclopentanone[J]. Catalysis Communications, 2012, 24, 100- 104. |
60 | HRONEC M , FULAJTAROVA K , VAVRA I , et al. Carbon supported Pd-Cu catalysts for highly selective rearrangement of furfural to cyclopentanone[J]. Applied Catalysis B: Environmental, 2016, 181, 210- 219. |
61 | FANG R Q , LIU H L , LUQUE R , et al. Efficient and selective hydrogenation of biomass-derived furfural to cyclopentanone using Ru catalysts[J]. Green Chemistry, 2015, 17 (8): 4183- 4188. |
62 | LIU Y H , CHEN Z H , WANG X F , et al. Highly selective and efficient rearrangement of biomass-derived furfural to cyclopentanone over interface-active Ru/carbon nanotubes catalyst in water[J]. ACS Sustainable Chemistry & Engineering, 2017, 5 (1): 744- 751. |
63 | HRONEC M , FULAJTAROVA K , MICUSIK M . Influence of furanic polymers on selectivity of furfural rearrangement to cyclopentanone[J]. Applied Catalysis A, General, 2013, 468, 426- 431. |
64 | ZHANG G S , ZHU M M , ZHANG Q , et al. Towards quantitative and scalable transformation of furfural to cyclopentanone with supported gold catalysts[J]. Green Chemistry, 2016, 18 (7): 2155- 2164. |
[1] | Jifeng BAI, Hongzhu LU, Yu YANG, Manfang CHENG, Jingyun WANG. Research Progress in the Synthesis of 2, 5-Furandicarboxylic Acid from 5-Hydroxymethylfural Catalyzed by Transition Metals [J]. Biomass Chemical Engineering, 2022, 56(2): 49-59. |
[2] | Yongzhao ZHANG, Jiajia JI, Yang WANG, Hongwei LI, Songhui LIU, Wende WANG. Catalytic Characteristics of Metal Ions for Glucose Isomerization and Dehydration [J]. Biomass Chemical Engineering, 2022, 56(1): 7-12. |
[3] | Yanchun FU, Tengfei GAO, Liping ZHANG, Ruihong MENG, Yang YANG, Xiongwei LI. Advance on Bio-refining for the Production of Furfural [J]. Biomass Chemical Engineering, 2021, 55(6): 59-66. |
[4] | Hongbo SHEN, Xinglong LI, Yao FU. Recent Advances in Synthesis of Alkoxymethylfuran Ether from Biomass Resources [J]. Biomass Chemical Engineering, 2021, 55(4): 43-58. |
[5] | Song KU, Xuesong TAN, Rundong LI, Xinshu ZHUANG, Zhenhong YUAN. Preparation of Furfural and Levulinic Acid from Hybrid Pennisetum Hydrolysis in Biphasic Hydrated Molten Salt System [J]. Biomass Chemical Engineering, 2021, 55(3): 29-34. |
[6] | Quan CHEN, Hongying XIA, Wei ZHANG, Libo ZHANG. Research Progress on Influence Factors of Biomass Microwave Pyrolysis for Bio-oil [J]. Biomass Chemical Engineering, 2020, 54(6): 83-90. |
[7] | Ronghui XU,Guosheng WANG. Research Progress in Synthesis and Application of δ-Valerolactone Base on Furfural [J]. Biomass Chemical Engineering, 2020, 54(1): 60-66. |
[8] | Xinjun HE,Jiao MA,Kangjun WANG,Zhanwei XU,Songyan JIA. Catalytic Synthesis of 5-Hydroxymethylfurfural and Levulinic Acid from Agarose with ZrOCl2 as Catalyst [J]. Biomass Chemical Engineering, 2019, 53(5): 15-20. |
[9] | WANG Yonggui, REN Shuzhi, GENG Qingbao, ZHANG Weigang, GE Xiutao. Optimization of 5-Hydroxymethylfurfural Preparation from Hydrolysis of Maltose Dehydration by Response Surface Methodology [J]. bce, 2018, 52(6): 57-61. |
[10] | YANG Yan-ping, SHEN Ming-gui, SHANG Shi-bin, SONG Zhan-qian. Research Progress of Cellulose Catalytic Conversion for Preparation of 5-HMF in Different Solvents [J]. bce, 2016, 50(4): 47-52. |
[11] | ZHU Shi-lin, LI Jing-dan, JIANG Xiao-xiang, YANG Hong-min, JIANG Jian-chun, ZHANG Ai-ling. Process of Conversion of 5-Hydroxymethylfurfural and Levulinic Acid to Biomass-based Chemicals [J]. bce, 2016, 50(4): 53-59. |
[12] | WANG Kai, CHENG Yi, XU Lan-shu, LI Rui. Measurement of Vapor-Liquid Equilibrium Data in Furfural-Cyclohexanol-Camphene Ternary System [J]. bce, 2016, 50(1): 29-34. |
[13] | JI Li, WANG Yong-miao, TANG Yong, LIU Zhi-ping, JIANG Jian-xin. Comparative Study on Conversion Process of Furfural Residue for Ethanol Production by Simultaneous Saccharification and Fermentation [J]. bce, 2015, 49(6): 6-10. |
[14] | DONG Xiao-chen, YE Xiao-ning, JIANG Xiao-yan, HU Bin, LU Qiang, DONG Chang-qing. Review on Experimental and Theoretical Study of Furfural Production from Fast Pyrolysis of Biomass [J]. bce, 2015, 49(5): 39-46. |
[15] | YANG Qiao-wen, CHEN Si, LI Peng-fei. Preparation of Activated Carbon from Furfural Residues by Phosphoric Acid Activation [J]. bce, 2015, 49(3): 23-26. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||