Biomass Chemical Engineering ›› 2022, Vol. 56 ›› Issue (3): 39-46.doi: 10.3969/j.issn.1673-5854.2022.03.007
• Review Comment • Previous Articles Next Articles
Jurong REN1, Yunhong SU2, Hao YING1,*(), Yunjuan SUN1, Wei XU1, Hang YIN1
Received:
2021-03-22
Online:
2022-05-30
Published:
2022-05-21
Contact:
Hao YING
E-mail:hy2478@163.com
CLC Number:
Jurong REN, Yunhong SU, Hao YING, Yunjuan SUN, Wei XU, Hang YIN. Research Progress of Biomass Gasification for Hydrogen-rich Syngas[J]. Biomass Chemical Engineering, 2022, 56(3): 39-46.
Table 2
Influence of reaction temperature on H2 volume fraction"
原料 raw material | 最佳温度(范围)/℃ optimum temperature(range) | H2体积分数/% H2volume fraction | 改变量 variable quantity | 反应条件 reaction condition | 参考文献 ref. |
稻壳 | 850(750~850) | 13.1 | H2体积分数较750 ℃时提升 42.4%;碳转化率86.1%,提升21.4% | 空气-蒸汽混合物为气化剂;蒸汽与生物质质量比值为0.8 | [ |
松木屑 | 900(700~950) | 47.7 | 900 ℃之后H2体积分数下降;碳转化率随温度升高而提高 | 水蒸气流量10 mL/min | [ |
玉米秸秆焦 | 950(750~950) | 62.53 | H2体积分数由750 ℃时的37.68 %增加至62.53% | 水蒸气流量5 mL/min | [ |
Table 4
Composite catalyst for hydrogen production from biomass gasification"
催化剂 catalyst | 生物质原料 biomass | 反应条件 reaction condition | 合成气品质 syngas quality | 催化效果 catalytic effect | 参考文献 ref. |
镍-铑/γ-Al2O3 | 绿豆残渣 | 温度650 ℃,碳与蒸气质量比 为0.12 | H2体积分数65%, n(H2)/n(CO)为10.9 | 气化效率为83%,无焦油生成 | [ |
水滑石Ni/Mg/Al | 雪松木 | 温度800 ℃,水蒸气流量0.02 mL/min,反应30 min | — | 较高的抗积碳能力和催化剂稳定性 | [ |
NiO/白云石 | 松木屑 | 900 ℃气化,730 ℃重整 | H2体积分数71.8% | 最高产氢45.8 g/kg | [ |
Ni/CeO2/Al2O3 | 木屑 | 温度900 ℃,反应60 min, 催化剂负载量40% | — | 焦油裂解率比没有催化剂时高196% | [ |
Rh/CeO2/SiO2 | 雪松木 | 空气流量20 mL/min,加热速率15 K/min(27~1 000 ℃) | — | 碳转化率98%~99%,催化剂能够有效促进积碳燃烧 | [ |
Ni-Fe/γ-Al2O3 | 藻类浒苔 | 加热速率为10 K/min,终温850 ℃,保持30 min | H2体积分数74% | 产氢率24.6 g/kg,促进生物质裂解 | [ |
煅烧水泥 (86.44%CaO) | 松木屑 | 温度800 ℃,反应45 min, 水蒸气-空气为气化剂 | H2体积分数50.3% | 焦油产率0.49 g/Nm3,焦油转化效率为71%~83% | [ |
K2CO3/Ca(OH)2 | 纤维素粉 | 温度450~500 ℃,压力 24~26 MPa,反应20 min | 产氢率分别比使用 K2CO3或Ca(OH)2时 高25%和45% | H2产率是无催化剂的2.5倍 | [ |
1 |
OKOLIE J A , PATRA B R , MUKHERJEE A , et al. Futuristic applications of hydrogen in energy, biorefining, aerospace, pharmaceuticals and metallurgy[J]. International Journal of Hydrogen Energy, 2021, 46 (13): 8885- 8905.
doi: 10.1016/j.ijhydene.2021.01.014 |
2 |
SIKARWAR V S , ZHAO M , CLOUGH P , et al. An overview of advances in biomass gasification[J]. Energy and Environmental Science, 2016, 9 (10): 2927- 3304.
doi: 10.1039/C6EE90053D |
3 | Hydrogen Council. Hydrogen, scaling up[EB/OL]. (2017-11-13)[2020-05-15]. http://hydrogencouncil.com/study-hydrogen-scaling-up/. |
4 | LIPMAN T E. Hydrogen Production Science and Technology[M]//MEYERA R A. Encyclopedia of Sustainability Science and Technology, New York: Springer, 2018. |
5 |
KONG M , FEI J H , WANG S , et al. Influence of supports on catalytic behavior of nickel catalysts in carbon dioxide refor ming of toluene as a model compound of tar from biomass gasification[J]. Bioresource Technology, 2011, 102 (2): 2004- 2008.
doi: 10.1016/j.biortech.2010.09.054 |
6 |
EWAN B , ALLEN R . A figure of merit assessment of the routes to hydrogen[J]. International Journal of Hydrogen Energy, 2005, 30 (8): 809- 819.
doi: 10.1016/j.ijhydene.2005.02.003 |
7 | CAO L C, YU I K M, XIONG X N, et al. Biorenewable hydrogen production through biomass gasification: A review and future prospects[J/OL]. Environmental Research, 2020, 186: 109547[2021-03-02]. https://doi.org/10.1016/j.envres.2020.109547. |
8 | COLLOT A . Matching gasification technologies to coal properties[J]. International Journal of Coal Geology, 2006, 65 (314): 191- 212. |
9 |
KANNAH R Y , KAVITHA S , KARTHIKEYAN O P , et al. Techno-economic assessment of various hydrogen production methods: A review[J]. Bioresource Technology, 2021, 319, 124175.
doi: 10.1016/j.biortech.2020.124175 |
10 | WANG Q . Hydrogen Production[M]. Switzerland: Springer International Publishing, 2017. |
11 |
谭静. 煤气化、生物质气化制氢与电解水制氢的技术经济性比较[J]. 东方电气评论, 2020, 34 (3): 28- 31.
doi: 10.3969/j.issn.1001-9006.2020.03.007 |
12 | DIAZ-REY M R , CORTES-REYS M , HERRERA C , et al. Hydrogen-rich gas production from algae-biomass by low temperature catalytic gasification[J]. Catalysis Today, 2015, 257 (2): 177- 184. |
13 | ARGUN H, GOKFILIZ P, KARAPINAR I. Biohydrogen Production Potential of Different Biomass Sources[M]//SINGH A, RATHORE D. Biohydrogen Production: Sustainability of Current Technology and Future Perspective. New Delhi: Springer, 2017. |
14 |
ZHANG Y , GONG X , ZHANG B , et al. Potassium catalytic hydrogen production in sorption enhanced gasification of biomass with steam[J]. International Journal of Hydrogen Energy, 2014, 39 (9): 4234- 4243.
doi: 10.1016/j.ijhydene.2014.01.015 |
15 | BEOHAR H , GUPTA B , SETHI V K , et al. Parametric study of fixed bed biomass gasifier: A review[J]. International Journal of Thermal Technologies, 2012, 2 (1): 2277- 4114. |
16 |
ZHOU J , CHEN Q , ZHAO H , et al. Biomass-oxygen gasification in a high-temperature entrained-flow gasifier[J]. Biotechnology Advances, 2009, 27 (5): 606- 611.
doi: 10.1016/j.biotechadv.2009.04.011 |
17 | 贾爽, 应浩, 孙云娟, 等. 生物质水蒸气气化制取富氢合成气及其应用的研究进展[J]. 化工进展, 2018, 37 (2): 497- 504. |
18 |
WEI L , XU S , ZHANG L , et al. Steam gasification of biomass for hydrogen-rich gas in a free-fall reactor[J]. International Journal of Hydrogen Energy, 2007, 32 (1): 24- 31.
doi: 10.1016/j.ijhydene.2006.06.002 |
19 | LOHA C, CHATTOPADHYAY H, CHATTERJEE P K. Energy generation from fluidized bed gasification of rice husk[J/OL]. Journal of Renewable and Sustainable Energy, 2013, 5(4): 43111[2021-03-02]. https://doi.org/10.1063/1.4816496. |
20 |
NIU Y H , HAN F T , CHEN Y S , et al. Experimental study on steam gasification of pine particles for hydrogen-rich gas[J]. Journal of the Energy Institute, 2017, 90 (5): 715- 724.
doi: 10.1016/j.joei.2016.07.006 |
21 | 庞赟佶, 殷吾真, 陈义胜, 等. 玉米秸秆焦炭水蒸气强化气化制取富氢气体实验研究[J]. 太阳能学报, 2020, 41 (8): 351- 356. |
22 |
FRANCO C , PINTO F , GULYURTLU I , et al. The study of reactions influencing the biomass steam gasification process[J]. Fuel, 2003, 82 (7): 835- 842.
doi: 10.1016/S0016-2361(02)00313-7 |
23 |
SUTTON D , KELLEHER B , ROSS J R H . Review of literature on catalysts for biomass gasification[J]. Fuel Processing Technology, 2001, 73 (3): 155- 173.
doi: 10.1016/S0378-3820(01)00208-9 |
24 |
TAN R S , ABDULLAH T A T , JOHARI A , et al. Catalytic steam refor ming of tar for enhancing hydrogen production from biomass gasification: A review[J]. Frontiers in Energy, 2020, 14 (3): 545- 569.
doi: 10.1007/s11708-020-0800-2 |
25 | TAN R S, TUAN ABDULLAH T A, RIPIN A, et al. Hydrogen-rich gas production by steam refor ming of gasified biomass tar over Ni/dolomite/La2O3 catalyst[J/OL]. Journal of Environmental Chemical Engineering, 2019, 7(6): 103490[2021-03-02]. https://doi.org/10.1016/j.jece.2019.103490. |
26 |
GAO N B , WANG X , LI A M , et al. Hydrogen production from catalytic steam reforming of benzene as tar model compound of biomass gasification[J]. Fuel Processing Technology, 2016, 148, 380- 387.
doi: 10.1016/j.fuproc.2016.03.019 |
27 |
MA X , ZHAO X , GU J , et al. Co-gasification of coal and biomass blends using dolomite and olivine as catalysts[J]. Renewable Energy, 2019, 132, 509- 514.
doi: 10.1016/j.renene.2018.07.077 |
28 |
邹金鑫, 宁斌. 国外生物质催化气化催化剂的研究进展[J]. 贵州化工, 2011, 36 (4): 9- 11.
doi: 10.3969/j.issn.1008-9411.2011.04.005 |
29 | ISLAM M W. A review of dolomite catalyst for biomass gasification tarremoval[J/OL]. Fuel, 2020, 267: 117095[2021-03-02]. https://doi.org/10.1016/j.fuel.2020.117095. |
30 | SAID M , CASSAYRE L , DIRION J , et al. Influence of nickel on biomass pyro-gasification: Coupled thermodynamic and experimental investigations[J]. Industrial & Engineering Chemistry Research, 2018, 57 (30): 9788- 9797. |
31 |
CHEN G , LI J , LIU C , et al. Low-temperature catalytic cracking of biomass gasification tar over Ni/HZSM-5[J]. Waste and Biomass Valorization, 2019, 10 (4): 1013- 1020.
doi: 10.1007/s12649-017-0107-7 |
32 |
PINTO F , ANDRÉ R N , CAROLINO C , et al. Effects of experimental conditions and of addition of natural minerals on syngas production from lignin by oxy-gasification: Comparison of bench and pilot scale gasification[J]. Fuel, 2015, 140, 62- 72.
doi: 10.1016/j.fuel.2014.09.045 |
33 | DELGADO J , AZNAR M P . Biomass gasification with steam in fluidized bed: Effectiveness of CaO, MgO and CaO-MgO for hot raw gas cleaning[J]. Industrial & Engineering Chemistry Research, 1997, 36, 1535- 1543. |
34 |
BERRUECO C , MONTANÉ D , MATAS GVELL B , et al. Effect of temperature and dolomite on tar formation during gasification of torrefied biomass in a pressurized fluidized bed[J]. Energy, 2014, 66, 849- 859.
doi: 10.1016/j.energy.2013.12.035 |
35 |
DONG J , NZIHOU A , CHI Y , et al. Hydrogen-rich gas production from steam gasification of bio-char in the presence of CaO[J]. Waste and Biomass Valorization, 2017, 8 (8): 2735- 2746.
doi: 10.1007/s12649-016-9784-x |
36 | 孙宁, 应浩, 徐卫, 等. CaO对木屑水蒸气气化制取富氢燃气的影响[J]. 林产化学与工业, 2017, 37 (2): 141- 147. |
37 | 吕鹏梅, 熊祖鸿, 常杰, 等. 生物质催化气化制取富氢燃气的研究[J]. 环境污染治理技术与设备, 2003, 4 (11): 31- 34. |
38 |
SISINNI M , CARLO A D , BOCCI E , et al. Hydrogen-rich gas production by sorption enhanced steam refor ming of wood gas containing TAR over a commercial Ni catalyst and calcined dolomite as CO2 sorbent[J]. Energies, 2013, 6 (7): 3167- 3181.
doi: 10.3390/en6073167 |
39 | 张晓东. 生物质热解气化及热解焦油催化裂化机理研究[D]. 杭州: 浙江大学, 2003. |
40 |
武宏香, 赵增立, 张伟, 等. 碱/碱土金属对纤维素热解特性的影响[J]. 农业工程学报, 2012, 28 (4): 215- 220.
doi: 10.3969/j.issn.1002-6819.2012.04.036 |
41 |
NING S Y , JIA S , YING H , et al. Hydrogen-rich syngas produced by catalytic steam gasification of corncob char[J]. Biomass and Bioenergy, 2018, 117, 131- 136.
doi: 10.1016/j.biombioe.2018.07.003 |
42 |
PERANDER M , DEMARTINI N , BRINK A , et al. Catalytic effect of Ca and K on CO2 gasification of spruce wood char[J]. Fuel, 2015, 150, 464- 472.
doi: 10.1016/j.fuel.2015.02.062 |
43 | 曾志伟. 碱金属K对生物质水蒸气催化气化增强制氢特性影响研究[D]. 武汉: 华中科技大学, 2016. |
44 | 宁思云, 应浩, 徐卫, 等. 木炭水蒸气催化气化制取合成气[J]. 化工进展, 2019, 38 (3): 1308- 1315. |
45 | UMEKI K , HÄGGSTRÖM G , BACH-OLLER A , et al. Reduction of tar and soot formation from entrained-flow gasification of woody biomass by alkali impregnation[J]. Energy & Fuels, 2017, 31 (5): 5104- 5110. |
46 |
STONOR M R , CHEN J G , PARK A A . Bio-energy with carbon capture and storage(BECCS) potential: Production of high purity H2 from cellulose via alkaline thermal treatment with gas phase reforming of hydrocarbons over various metal catalysts[J]. International Journal of Hydrogen Energy, 2017, 42 (41): 25903- 25913.
doi: 10.1016/j.ijhydene.2017.08.059 |
47 | LI D , WANG L , KOIKE M , et al. Steam refor ming of tar from pyrolysis of biomass over Ni/Mg/Al catalysts prepared from hydrotalcite-like precursors[J]. Applied Catalysis B: Environmental, 2011, 102 (314): 528- 538. |
48 |
ZHANG B , ZHANG L , YANG Z , et al. An experiment study of biomass steam gasification over NiO/Dolomite for hydrogen-rich gas production[J]. International Journal of Hydrogen Energy, 2017, 42 (1): 76- 85.
doi: 10.1016/j.ijhydene.2016.10.044 |
49 |
PENG W X , WANG L S , MIRZAEE M , et al. Hydrogen and syngas production by catalytic biomass gasification[J]. Energy Conversion and Management, 2017, 135, 270- 273.
doi: 10.1016/j.enconman.2016.12.056 |
50 |
ASADULLAH M . Demonstration of real biomass gasification drastically promoted by effective catalyst[J]. Applied Catalysis A: General, 2003, 246 (1): 103- 116.
doi: 10.1016/S0926-860X(03)00047-4 |
51 |
NOROUZI O , SAFARI F , JAFARIAN S , et al. Hydrothermal gasification performance of Enteromorpha intestinalis as an algal biomass for hydrogen-rich gas production using Ru promoted Fe-Ni/γ-Al2O3 nanocatalysts[J]. Energy Conversion and Management, 2017, 141, 63- 71.
doi: 10.1016/j.enconman.2016.04.083 |
52 |
SUI M , LI G , GUAN Y , et al. Hydrogen and syngas production from steam gasification of biomass using cement as catalyst[J]. Biomass Conversion and Biorefinery, 2020, 10 (1): 119- 124.
doi: 10.1007/s13399-019-00404-6 |
53 | 吕潇. 生物质低温气化实验及其机理研究[D]. 南京: 东南大学, 2016. |
54 | 孙宁, 应浩, 徐卫, 等. 松木屑催化气化制取富氢燃气[J]. 化工进展, 2017, 36 (6): 2158- 2163. |
55 | ROZAS R , ESCALONA N , SEPÚLVEDA C , et al. Catalytic gasification of pine-sawdust: Effect of primary and secondary catalysts[J]. Journal of the Energy Institute, 2019, 92 (6): 1727- 1735. |
56 | 贾秀荣. 天然气催化制氢气的研究进展[J]. 河南化工, 2010, 27 (15): 17- 21. |
57 | HUANG B , CHEN H , CHUANG K , et al. Hydrogen production by biomass gasification in a fluidized-bed reactor promoted by an Fe/CaO catalyst[J]. International Journal of Hydrogen Energy, 2012, 37 (8): 6511- 6518. |
58 | 刘琨琨. 基于白云石负载铁铈催化剂生物质催化气化实验研究[D]. 包头: 内蒙古科技大学, 2020. |
59 | WEI H Y , WU Y S , LUN N , et al. Preparation and photocatalysis of TiO2 nanoparticles co-doped with nitrogen and lanthanum[J]. Journal of Materials Science, 2004, 39 (4): 1305- 1308. |
60 | GUAN Y , PEI A , GUO L . Hydrogen production by catalytic gasification of cellulose in supercritical water[J]. Frontiers of Chemical Engineering in China, 2008, 2 (2): 176- 180. |
[1] | LIN Qixuan, LIU Xinxin, LI Libo, PENG Feng, REN Junli. Research Progress of Molecular Simulation Application of Biomass Hemicellulose [J]. Biomass Chemical Engineering, 2022, 56(3): 47-58. |
[2] | Hao SUN, Yunjuan SUN, Mingzhe MA, Kang SUN, Jianchun JIANG. Development Trend and Strategic Countermeasures of Forestry Resources Gasification, Heat Supply and Power Generation Industry [J]. Biomass Chemical Engineering, 2022, 56(2): 40-48. |
[3] | Haodong FAN, Dongwang ZHANG, Bin ZHAO, Man ZHANG, Yan JIN. Summary of Corrosion Characteristics and Inhibition Methods of Biomass Fluidized Bed [J]. Biomass Chemical Engineering, 2022, 56(1): 30-36. |
[4] | Meiling XIA, Yunpu WANG, Shumei ZHANG, Yuan ZENG, Yuhuan LIU, Roger RUAN. Research Progress on Comprehensive Utilization of Camellia oleifera Abel Shell [J]. Biomass Chemical Engineering, 2021, 55(6): 26-38. |
[5] | Yang LI, Kai LI, Zhenxi ZHANG, Shiyu FENG, Bin HU, Qiang LU. Research Progress on Catalytic Pyrolysis of Biomass with Alkaline Earth Metal Oxide-based Catalysts [J]. Biomass Chemical Engineering, 2021, 55(6): 39-48. |
[6] | Yanchun FU, Tengfei GAO, Liping ZHANG, Ruihong MENG, Yang YANG, Xiongwei LI. Advance on Bio-refining for the Production of Furfural [J]. Biomass Chemical Engineering, 2021, 55(6): 59-66. |
[7] | Junna BIAN, Jian CHEN, Guomin WU, Zhenwu KONG. Progress of Itaconic Acid Light Curable Resins [J]. Biomass Chemical Engineering, 2021, 55(5): 53-59. |
[8] | Xiaolu WANG, Xuefeng YAO, Yuxin CHEN, Huacong ZHOU, Quansheng LIU. Research Progress on Zirconium/Hafnium Based Hydrogen Transfer Catalyst [J]. Biomass Chemical Engineering, 2021, 55(4): 66-76. |
[9] | Dongyang HE, Guowei LIANG, Xinyang LI, Shuangyi WU, Miaomiao NIU. Research Review on Cracking and Removal of Tar Catalyzed by Biomass Coke [J]. Biomass Chemical Engineering, 2021, 55(4): 77-84. |
[10] | Xiaojin HU, Tao YANG, Sanju LIU, Jun LIU, Shoujun ZHANG, Yirui LI. Effect of Gasification Temperature of Circulating Fluidized Bed on Solid Product Feature of Rice Husk Gasification [J]. Biomass Chemical Engineering, 2021, 55(3): 23-28. |
[11] | Shaohua LIANG, Taiyan ZHANG, Yongling YAO, Chengbin LU, Bin XU, Miaomiao NIU. Simulation Study of Biomass Two-stage Enriched Air Gasification-Gas Turbine Combustion for Power Generation [J]. Biomass Chemical Engineering, 2021, 55(3): 47-54. |
[12] | Ruifan LI, Yubao CHEN, Yongyan ZHAO, Shiyun ZHUANG, Wenjie ZHANG. Response Surface Optimization of Preparation of Aviation Kerosene from Jatropha Oil Catalyzed by Pd-Al2O3-BEA [J]. Biomass Chemical Engineering, 2021, 55(3): 55-61. |
[13] | Xiangwen CHENG, Lizhi LIU, Rong WEI. Analysis of Gasification Process and Gasification Characteristics of Downdraft Fixed Bed Gasifier [J]. Biomass Chemical Engineering, 2021, 55(2): 9-15. |
[14] | Jie ZHANG, Rongshuai DUAN, Zijiang LI, Hui WANG, Ning ZHANG, Shuya ZHANG, Chuanling SI. Research Advances on Biomass Derived Carbon Aerogel [J]. Biomass Chemical Engineering, 2021, 55(1): 91-100. |
[15] | Shuang SHANG, Kui LAN, Yan WANG, Juanjuan ZHANG, Zhenhua QIN, Jianfen LI. Research Progress on Catalyst for Tar Reforming in Biomass Gasification [J]. Biomass Chemical Engineering, 2020, 54(6): 65-73. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||