N-甲基-N, N-二烯丙基-N-(3-脱氢枞酰氧基)丙基溴化铵的合成及其自聚动力学分析

doi:10.3969/j.issn.1673-5854.2019.01.001

Abstract

Abstract:

Water-soluble rosin monomer N-methyl-N, N-divinyl-3-dehydroabietoyloxypropan-1-ammonium bromide(DMDHAE) was prepared from dehydroabietic acid, 3-bromopropanol and methyldiallylamine, and its structure was characterized by nuclear magnetic resonance(NMR), gas chromatography(GC), elemental analysis, FT-IR, mass spectrometry(MS) and melting point instrument. The results indicated that the purity of monomer was 91%, melting point was 127-131 ℃, and solubility was 1.50-1.60 g/mL; characteristic group peaks were appeared in the NMR and FT-IR spectra, and the mass spectrometry and elemental analysis results were consistent with the theoretical value. The self-polymerization parameter was measured by differential scanning calorimeter(DSC), and self-polymerization kinetics was analyzed with autocatalytic model. The results showed that DMDHAE was polymerizability, the activation energy(E_a) was 124.336 kJ/mol, and mechanism function f(α) was SB(m, n) model.

Key words: N-methyl-N, N-divinyl-3-dehydroabietoyloxypropan-1-ammonium bromide, rosin, synthesis, polymerization kinetics

CLC Number:

TQ35

Haibo ZHANG,Jianxin JIANG,Shibin SHANG,Zhanqian SONG. Preparation and Self-polymerization Kinetics of N-methyl-N, N-divinyl-3-dehydroabietoyloxypropan-1-ammonium Bromide[J]. Biomass Chemical Engineering, 2019, 53(1): 1-7.

Figures/Tables 17

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Table 1

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Table 2

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References 16

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反应程度(α) conversion	5 K/min		10 K/min		15 K/min
反应程度(α) conversion	温度/℃ temperature	反应速率(dα/dt) reaction rate	温度/℃ temperature	反应速率(dα/dt) reaction rate	温度/℃ temperature	反应速率(dα/dt) reaction rate
0.1	104.98	11.688	113.64	23.463	119.20	44.518
0.2	108.58	16.026	117.00	37.023	121.82	67.818
0.3	111.40	19.523	119.33	47.839	123.86	77.236
0.4	113.75	23.026	121.28	53.366	125.76	79.686
0.5	115.79	25.522	123.13	54.025	127.65	78.417
0.6	117.73	25.393	125.02	50.664	129.60	74.055
0.7	119.78	22.797	127.10	45.188	131.74	65.880
0.8	120.19	18.583	129.51	36.839	134.24	53.455
0.9	125.43	12.223	132.78	24.381	137.63	34.953

β/(K·min^-1)	A/min^-1	m	n
5	2.589×10¹⁸	0.1051	1.0034
10	4.584×10¹⁸	0.4809	1.2984
15	3.894×10¹⁸	0.3277	1.2594
平均值average	3.689×10¹⁸	0.3046	1.1870

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Preparation and Self-polymerization Kinetics of N-methyl-N, N-divinyl-3-dehydroabietoyloxypropan-1-ammonium Bromide

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