纳米TiO2光催化降解碱木质素研究

›› 2009, Vol. 43 ›› Issue (6): 31-35.

• 论文 • Previous Articles Next Articles

Research on Degradation of Alkali Lignin by Nano Titanium Dioxide Photocatalysis

CHEN Yun-ping^1,2, FU Yan-bin³, YANG Ping¹, CHEN Li¹, CHENG Xian-su²

1. Department of Chemistry and Chemical Engineering Minjiang University, Fuzhou 350108, China;2. College of Material Science and Engineering Fuzhou University, Fuzhou 350002, China;3. Fujian Environmental Monitoring Central Station, Fuzhou 350003, China

Received:2009-07-08 Revised:1900-01-01 Online:2009-11-30 Published:2009-11-30

Abstract

Abstract: The degradation rate of alkali lignin was over 70% at the condition of lignin 5 g, the dosage of catalyst 0.75 g/L, illumination time 2.5 h and pH value 10 by nano titanium dioxide photocatalysis. The GC-MS analysis results showed the structure of lignin was complex. In the process of degradation of alkali lignin, the aromatic structure and the side chain were preferential oxidized or broken. The degradation products were vanilla, guaiacyl derivative and other small molecula substances.

Key words: alkali lignin, degradation, nano titanium dioxide photocatalyst

CLC Number:

TQ351.013

CHEN Yun-ping;FU Yan-bin;YANG Ping;CHEN Li;CHENG Xian-su. Research on Degradation of Alkali Lignin by Nano Titanium Dioxide Photocatalysis[J]. , 2009, 43(6): 31-35.

[1]	Qian YANG,Guifeng LIU,Guomin WU,Zhenwu KONG. Research Progress of Lignin Chemical Degradation and Its Applications in Polymer Materials [J]. Biomass Chemical Engineering, 2020, 54(2): 40-50.
[2]	Jiaxing ZHOU,Zhiming LIU,Xu LI. Effect of Aluminum Hypophosphite Addition on Flame Retardancy of Alkali Lignin Based Polyurethane Foam [J]. Biomass Chemical Engineering, 2019, 53(2): 1-6.
[3]	Gang WANG,Yi LI,Zhigang LIU,Chengli PEI,Lida WU,Yi TONG. Research Progress of PLA/Cellulose Blend Composites [J]. Biomass Chemical Engineering, 2019, 53(1): 54-60.
[4]	HU Ping, WANG Lifang, JIA Boran, LIU Ying, SHA Xiaoling, REN Shixue. Degradation Performances of Poly(vinylalcohol)/Wheat Straw Alkali Lignin Foaming Material with Formaldehyde Crosslinker [J]. bce, 2018, 52(4): 29-35.
[5]	TAN Yang, MA Chunfu. Mechanism Study of Black Liquor Alkali Lignin Pyrolysis by Using TG-FTIR [J]. bce, 2018, 52(2): 35-41.
[6]	ZHENG Yulong, LI Shuying, PANG Diqiong, YANG Fuyu. Research Progress on Microbial Pretreated Conversion of Energy Grass to Bio-energy [J]. bce, 2018, 52(2): 51-58.
[7]	WANG Ling, ZHOU Jiao, MA Xiaojun. Preparation of Chitosan/Poly(hydroxybutyrate-hydroxyhexanoate) Biodegradable Composite Films [J]. bce, 2017, 51(6): 1-5.
[8]	WEI Wei, CENG Qian, LU Junwei, HAN Hekun, ZHU Jianjun, XIE Jimin. Preparation,Characterization and Photocatalytic Property of Wintermelon-based TiO₂ Carbonaceous Aerogels [J]. bce, 2017, 51(3): 7-13.
[9]	ZHANG Cuimei, CUI Xuejing, SUN Yanni, JIANG Ruiyu, ZHAO Jiruo, FENG Ying. Characteristic of Alkali Lignin Filling Natural Rubber [J]. bce, 2017, 51(3): 33-40.
[10]	YANG Wei, LI Zhui, BI Yan-wen, LU Jin-cheng, GONG Cheng-cheng, CAO Wei-hua, FANG Gui-zhen, MA Yan-li. Preparation Technology of Polyacrylic Acid Grafted Alkali Lignin/ Phenolic Open-cell Absorbent Material [J]. bce, 2015, 49(3): 7-12.
[11]	LUO Hua-chao, CHEN He-mu, CHEN Ying-chao, FENG Wei, WANG Chen, QIN Bi-da, REN Shi-xue. Preparation and Properties of Polyvinyl Alcohol/Modified Alkali Lignin Foaming Materials [J]. bce, 2015, 49(2): 1-6.
[12]	WANG Hui-min, MA Yan-li, FANG Gui-zhen, LI Shu-jun. Properties and Characterization of Alkali Lignin/Poly-acrylonitrile Graft Porous Materials [J]. bce, 2015, 49(1): 13-19.
[13]	XIAO Feng-long, WEI Min, ZHAO Jian. Advance in Research of Polyaspartic Acid [J]. bce, 2014, 48(6): 50-55.
[14]	SU Ling;REN Shi-xue;FANG Gui-zhen. Preparation and Optical Properties of Glutaraldehyde Crosslinked Alkali Lignin/PVA Films [J]. , 2013, 47(3): 1-5.
[15]	HU Li-hong;ZHOU Yong-hong;LIU Rui-jie;ZHANG Meng. Progress of Production of Phenolic Compounds Via Oxidative Degradtion of Lignin [J]. , 2012, 46(1): 23-33.

Research on Degradation of Alkali Lignin by Nano Titanium Dioxide Photocatalysis

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments