Biomass Chemical Engineering ›› 2021, Vol. 55 ›› Issue (6): 59-66.doi: 10.3969/j.issn.1673-5854.2021.06.007
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Yanchun FU(), Tengfei GAO, Liping ZHANG, Ruihong MENG, Yang YANG, Xiongwei LI
Received:
2020-12-14
Online:
2021-11-30
Published:
2021-10-29
CLC Number:
Yanchun FU, Tengfei GAO, Liping ZHANG, Ruihong MENG, Yang YANG, Xiongwei LI. Advance on Bio-refining for the Production of Furfural[J]. Biomass Chemical Engineering, 2021, 55(6): 59-66.
Table 1
Typical furfural preparation process"
工艺名称 processes | 原料 raw materials | 催化剂 catalysts | 温度/℃ temperature | 糠醛得率/% yield of furfural | 优缺点 advantages and disadvantages | 文献 ref. |
Quakers Oats | 燕麦壳 | 硫酸 | 153 | 40~52 | 温度低,停留时间和较高较长;硫酸浓度较高 | [ |
Suprayield | 硬木 | 硫酸 | 230~250 | 50~70 | 反应器体积小;停留时间短;糠醛得率高和酸循环利用;投资和维护成本高昂 | [ |
Westpro | 玉米芯 | 硫酸 | 160~165 | 55 | 副产物量少,糠醛纯度高,生产成本低 | [ |
Table 2
Typical technology for preparing furfural by chemical conversion"
原料 raw materials | 技术要点 technical points | 糠醛得率% yield of furfural/% | 文献 ref. |
软木半纤维素 | SAPO-44固体催化剂 | 63 | [ |
玉米秸秆 | NbP固体酸 | 23 | [ |
玉米芯 | SO42-/SiO2-Al2O3/La3+固体酸 | 21 | [ |
玉米秸秆预水解液 | 水-甲苯双相体系,H2SO4催化 | 76.3 | [ |
玉米秸秆预水解液 | 水-甲基异丁基酮双相体系,H2SO4催化 | 80.1 | [ |
甘蔗渣 | 水-丙酮双相体系,H3PO4催化 | 45.8 | [ |
木聚糖 | [BMIM]Cl/AlCl3离子液体催化体系 | 77 | [ |
棕榈叶 | 草酸-氯化胆碱低共熔溶剂 | 26.34 | [ |
木糖 | 草酸-氯化胆碱低共熔溶剂,AlCl3催化 | 39.8 | [ |
木糖 | PAL-SO3H固体催化剂,γ-戊二醛内酯-水双相体系 | 87 | [ |
阿拉伯糖 | [BMIM]Cl/AlCl3离子液体催化剂,水-丁酮双相体系 | 60 | [ |
Table 3
Technology for the selective preparation of furfural by rapid catalytic pyrolysis of biomass"
原料 raw materials | 技术要点 technical points | 转化率/% conversion rate/% | 糠醛得率/% yield of furfural/% | 文献 ref. |
玉米芯 | ZnCl2浸渍催化热解 | — | 8.0 | [ |
玉米芯 | ZnCl2浸渍催化热解 | — | 5.79 | [ |
玉米芯 | Fe2(SO4)3浸渍催化热解 | — | 4.62 | [ |
玉米芯 | H2SO4浸渍催化热解 | — | 5.11 | [ |
纤维素 | ZrCu-SAPO-18原位催化 | 27.5 | — | [ |
纤维素 | TiN非原位催化 | — | 15.3 | [ |
纤维素 | CaN非原位催化 | — | 23.0 | [ |
纤维素 | Na/Fe固体酸非原位催化 | 64.7 | — | [ |
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