无患子皂苷的复配及其在构筑Ni(OH)2/NiOOH复合材料中的应用

doi:10.3969/j.issn.1673-5854.2021.05.003

Abstract

Abstract:

The natural surfactant sapindus-saponin was extracted from Sapindus mukorossi. The composite properties of sapindus-saponin and cationic surfactant cetyltrimethylamine bromide(CTAB) were studied. Sapindus-saponin and composite surfactants were used to prepare nickel hydroxide composite materials by solvothermal method. The effects of solvents, temperatures, and surfactants on the morphology of the materials were investigated. It was revealed that the compound system had obvious synergistic effect. In detail, the CMC and γ_CMC of sapindus-saponin were 1 g/L and 41.97 mN/m; when the mass ratio of sapindus-saponin to CTAB was 50:50, the CMC and γ_CMC of systems decreased drastically to 0.18 g/L and 24.63 mN/m, respectively. The morphology analysis and XRD analysis of Ni(OH)₂ composites showed that, when sapindus-saponin was used as surfactant in ethanol system under 180℃, the composite materials with uniform pore flower spherical microsphere structures were obtained, which possessed many thick nanosheets. On the other hand, when sapindus-saponin/CTAB compounded system was used as surfactant in ethanol system under 140℃, spherical coral composite micro-nano materials with uniform morphology were prepared. The two different kinds of composite materials were both Ni(OH)₂/NiOOH composites.

Key words: sapindus-saponin, compound system, soft template, nickel hydroxide

CLC Number:

TQ35

Bing HAN, Fei WANG, Zexue LIU, Haixia LIN, Shuhui ZHAN, Chunrui HAN. Compounding of Sapindus-saponin and Its Application for Synthesis of Ni(OH)₂/NiOOH Composite Materials[J]. Biomass Chemical Engineering, 2021, 55(5): 15-20.

Figures/Tables 6

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Table 1

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References 21

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无患子皂苷的质量分数/% mass fraction of sapindus-saponin	γ_CMC/(mN·m^-1)	CMC_理论/(g·L^-1)	CMC₁₂/(g·L^-1)	(CMC_理论-CMC₁₂)/ CMC_理论
100	41.97	1	1	0
95	40.02	0.96	0.62	0.35
80	38.08	0.82	0.36	0.56
65	28.08	0.69	0.27	0.61
50	24.63	0.55	0.18	0.67
0	28.62	0.1	0.1	0

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Compounding of Sapindus-saponin and Its Application for Synthesis of Ni(OH)₂/NiOOH Composite Materials

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Compounding of Sapindus-saponin and Its Application for Synthesis of Ni(OH)2/NiOOH Composite Materials

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Compounding of Sapindus-saponin and Its Application for Synthesis of Ni(OH)₂/NiOOH Composite Materials