Biomass Chemical Engineering ›› 2021, Vol. 55 ›› Issue (5): 8-14.doi: 10.3969/j.issn.1673-5854.2021.05.002
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Hengyi SHU1,3, Zhifeng ZHENG3,4, Shuirong LI4, Shouqing LIU1,3, Hongzhou HE2, Yuanbo HUANG2,3,*()
Received:
2020-07-29
Online:
2021-09-30
Published:
2021-09-13
Contact:
Yuanbo HUANG
E-mail:youthshow@163.com
CLC Number:
Hengyi SHU, Zhifeng ZHENG, Shuirong LI, Shouqing LIU, Hongzhou HE, Yuanbo HUANG. Process Optimization of Synthesis of 1-Decene by Olefin Metathesis of Methyl Oleate[J]. Biomass Chemical Engineering, 2021, 55(5): 8-14.
Table 1
Screening of olefin subtracts by cross-metathesis of MO"
烯烃底物 olefin substrate | MO转化率/% MO conversion | 1-癸烯得率/% 1-decene yield |
乙酸烯丙酯allyl acetate | 2 | 1 |
烯丙基缩水甘油醚allyl glycidyl ether | 27 | 8 |
丙烯酸甲酯methyl acrylate | 93 | 16 |
2-甲氧基丙烯2-methoxypropylene | 61 | 0 |
丙烯腈acrylonitrile | 21 | 6 |
苯乙烯styrene | 59 | 21 |
丁香酚eugenol | 93 | 14 |
烯丙基三甲基硅烷allyltrimethylsilane | 96 | 17 |
氯丙烯allyl chloride | 44 | 16 |
丙烯醇allyl alcohol | 40 | 9 |
Table 2
The orthogonal experiment design and results analysis"
序号 No. | A 反应温度/ ℃ reaction temperature | B 反应时间/min reaction time | C 催化剂用量/% amount of catalyst | D n(MO)∶n(丁香酚) n(MO)∶n(eugenol) | MO转化率/% MO conversion | 1-癸烯得率/% 1-decene yield |
1 | 0 | 20 | 0.5 | 1∶3 | 91 | 50 |
2 | 0 | 40 | 1 | 1∶10 | 96 | 78 |
3 | 0 | 60 | 3 | 1∶20 | 99 | 77 |
4 | 20 | 20 | 1 | 1∶20 | 99 | 6 |
5 | 20 | 40 | 3 | 1∶3 | 99 | 17 |
6 | 20 | 60 | 0.5 | 1∶10 | 92 | 46 |
7 | 40 | 20 | 3 | 1∶10 | 96 | 14 |
8 | 40 | 40 | 0.5 | 1∶20 | 95 | 34 |
9 | 40 | 60 | 1 | 1∶3 | 78 | 9 |
k′1 | 95.3 | 95.3 | 92.7 | 89.3 | ||
k′2 | 96.7 | 96.7 | 91 | 94.7 | ||
k′3 | 89.7 | 89.7 | 98 | 97.7 | ||
R′ | 7 | 7 | 7 | 8.4 | ||
k1″ | 68.3 | 23.3 | 43.3 | 25.3 | ||
k2″ | 23 | 43 | 31 | 46 | ||
k3″ | 19 | 44 | 36 | 39 | ||
R″ | 49.3 | 20.7 | 12.3 | 20.7 |
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