Biomass Chemical Engineering ›› 2021, Vol. 55 ›› Issue (1): 91-100.doi: 10.3969/j.issn.1673-5854.2021.01.013
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Jie ZHANG1, Rongshuai DUAN1, Zijiang LI1, Hui WANG2, Ning ZHANG2, Shuya ZHANG2, Chuanling SI2,*()
Received:
2020-06-22
Online:
2021-01-30
Published:
2021-01-25
Contact:
Chuanling SI
E-mail:sichli@tust.edu.cn
CLC Number:
Jie ZHANG, Rongshuai DUAN, Zijiang LI, Hui WANG, Ning ZHANG, Shuya ZHANG, Chuanling SI. Research Advances on Biomass Derived Carbon Aerogel[J]. Biomass Chemical Engineering, 2021, 55(1): 91-100.
Table 1
Preparation process and mechanism of carbon aerogel"
过程 | 机理 | |
溶胶-凝胶化 | 不同的有机小分子通过缩聚反应生成聚合物或者离子簇, 随后互相交联形成三维网状结构 | |
超临界干燥 | 将干燥介质转变为超临界态, 将表面张力降低为零, 从而使气凝胶结构得以完整保存 | |
干燥方法 | 冷冻干燥 | 将溶剂和凝胶先进行冷冻再进行升华处理, 避免气-液界面的产生 |
常压干燥 | 将湿凝胶或前驱体溶液置于常压条件下, 使液态溶剂蒸干 | |
炭化 | 将气凝胶在惰性气体中进行热裂解, 以除去其中的含氧、含氢官能团, 在完整保存气凝胶三维网状骨架结构的同时, 对气凝胶表面进行化学和结构改性, 使之转化成相对应的碳气凝胶 |
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