HPMo/SBA-15催化β-蒎烯二聚反应制备高密度燃料

doi:10.3969/j.issn.1673-5854.2021.01.011

Abstract

Abstract:

The catalyst HPMo/SBA-15 was prepared by loading the phosphomolybdic acid(HPMo) on the SBA-15, which was prepared by tetraethyl orthosilicate and triblock copolymer(P123).The dimerization of β-pinene was catalyzed by HPMo/SBA-15, and then the dimer product was hydrogenated by Pd/C catalysis to produce high density fuel. The structure of HPMo/SBA-15 was characterized by FT-IR, XRD and N₂ adsorption-desorption analysis. The catalytic performance of HPMo/SBA-15 catalysts with different loading amount for β-pinene dimerization was also studied. The results showed that the prepared HPMo/SBA-15 catalyst had mesoporous characteristics.HPMo dispersed evenly in the SBA-15 when the loading amount of HPMo ≤ 80%; when the loading amount was 100%, the HPMo was unevently distributed, aggregated on the surface of molecular sieves and blocked the hole, which resulted in the decrease of HPMo/SBA-15 surface area. The catalytic activity of 80% HPMo/SBA-15 was the highest, and the yield of dimer reached 63.3% after 4 h reaction at 150℃.The density and volume calorific value of high density fuel obtained from hydrogenated dimer product were similar to those of JP-10. However, the large viscosity, the high density fuel could not be used as fuel alone, could only be used as additives with other fuels.

Key words: HPMo/SBA-15, β-pinene, mesoporous material, dimer reaction, high density fuel

CLC Number:

TQ35

Fenghong XIANG, Ping ZHU, Xiaoqin YANG, Ying HOU, Xiangyi LIU, Juan XU. Preparation of High Density Fuel Through Dimerization of β-Pinene Catalyzed by HPMo/SBA-15[J]. Biomass Chemical Engineering, 2021, 55(1): 77-82.

Figures/Tables 6

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References 19

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催化剂 catalyst	比表面积/(m²·g^-1) BET surface area	孔容/(cm³·g^-1) pore volume	孔径/nm pore size
SBA-15	738.2	1.12	6.18
40%HPMo/SBA-15	603.5	0.67	6.71
60%HPMo/SBA-15	553.3	0.65	6.76
80%HPMo/SBA-15	521.4	0.63	6.77
100%HPMo/SBA-15	309.7	0.52	7.01

催化剂 catalyst	转化率/% conversion	二聚体得率/% yield of dimers	多聚体得率/% yield of polymers	反应时间 time	反应温度/℃ temperature	参考文献 references
80%HPMo/SBA-15	96	20.6	2.5	4 h	125	本研究this research
Amberlyst-15	69.2	12.1	4.3	—	125	^[18]
MMT-K10	10	41.5	11.6	—	125	^[18]
Nafion SAC-13	94	1.4	0.3	—	125	^[18]

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Preparation of High Density Fuel Through Dimerization of β-Pinene Catalyzed by HPMo/SBA-15

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