固体酸催化淀粉一锅法制备果葡糖浆的研究

doi:10.3969/j.issn.1673-5854.2016.06.004

Abstract

Abstract: The catalytic effects of several supported solid acid catalysts on the direct conversion of starch into high fructose syrup (HFS) in water were studied.Among them, the SO₄^2-/USY solid catalyst,which was prepared by loading sulfuric acid on ultrastable Y zeolite (USY),possessed bifunctional activities for both hydrolysis of starch and isomerization of glucose.It made one-step preparation of HFS from starch into reality and had a good catalytic effect.The preparation conditions of SO₄^2-/USY were optimized.The optimal conditions were 1.5 mol/L H₂SO₄ and 550℃.An optimized HFS yield(86.18%),containing 58.34% glucose and 27.84% fructose(mass fraction),was obtained under the conditions of 5% starch(starch/water),30% catalyst(based on the mass of starch),150℃,1 h and 400 r/min on the catalyst of optimal SO₄^2-/USY.The USY catalyst had high specific surface area and porosity characterized by physical adsorption technique.This enabled the sulfuric acid to be effectively adsorbed on the USY surface by impregnation and calcination.Meanwhile,the catalysts were characterized by NH₃ temperature programmed desorption and elemental analysis to find that the decrease of catalytic activity resulted from carbon deposition on the catalysts and the loss of SO₄^2-.Therefore, the catalytic activity of SO₄^2-/USY could be effectively recovered by calcining (removal carbon on the surface of catalyst) and impregnating in sulfuric acid (increase SO₄^2-).

Key words: starch, high fructose syrup, solid acid, SO₄^2-/USY, hydrolysis, isomerization

CLC Number:

TQ35

CHEN Hui-hui, JIANG Ye-tao, SUN Yong, LIN Lu. One-pot Preparation of High Fructose Syrup Directly from Starch over Solid Acid Catalyst[J]. bce, 2016, 50(6): 23-31.

References

[1] CORMA A,IBORRA S,VELTY A. Chemical routes for the transformation of biomass into chemicals[J]. Chemical Reviews,2007,38(36):2411-2414.
[2] TAKAGAKI A,OHARA M,NISHIMURA S,et al. A one-pot reaction for biorefinery:Combination of solid acid and base catalysts for direct production of 5-hydroxymethylfurfural from saccharides[J]. Chemical Communications,2009,210(41):6276-6278.
[3] TAKAGAKI A,TAKAHASHI M,NISHIMURA S,et al. One-pot synthesis of 2,5-diformylfuran from carbohydrate derivatives by sulfonated resin and hydrotalcite-supported ruthenium catalysts[J]. ACS Catalysis,2011,1(11):1562-1565.
[4] REN Qiu-he,HUANG Yi-zheng,MA Hong,et al. Conversion of glucose to 5-hydroxymethylfurfural catalyzed by metal halide in N,N-dimethylacetamide[J]. BioResources,2013,8(2):1563-1572.
[5] MEHDI H,FABOS V,TUBA R,et al. Integration of homogeneous and heterogeneous catalytic processes for a multi-step conversion of biomass:From sucrose to levulinic acid,γ-valerolactone,1,4-pentanediol,2-methyl-tetrahydrofuran,and alkanes[J]. Topics in Catalysis,2008,48(1/2/3/4):49-54.
[6] ZHANG Jun,WU Shu-bin,LI Bo. Advances in the catalytic production of valuable levulinic acid derivatives[J]. ChemCatChem,2012,4(9):1230-1237.
[7] SON P A,NISHIMURA S,EBITANI K. Synthesis of levulinic acid from fructose using Amberlyst-15 as a solid acid catalyst[J]. Reaction Kinetics,Mechanisms and Catalysis,2012,106(1):185-192.
[8] BUCHHOLZ K,SEIBEL J. Industrial carbohydrate biotransformations[J]. Carbohydrate Research,2008,343(12):1966-1970.
[9] YAN Z,HIDAJAT K,RAY A K. Optimal design and operation of SMB bioreactor:Production of high fructose syrup by isomerization of glucose[J]. Biochemical Engineering Journal,2004,21(2):111-121.
[10] FILHO F F. Handbook of food enzymology[J]. Revista Brasileira De Ciências Farmacêuticas,2004,40(2):269.
[11] ZHAO Jun,WANG Geng-geng,QIN Li-hong,et al. Synthesis and catalytic cracking performance of mesoporous zeolite Y[J]. Catalysis Communications,2016,73(2):98-102.
[12] ZHAO Jun,YIN Yan-chao,LI Yang,et al. Synthesis and characterization of mesoporous zeolite Y by using block copolymers as templates[J]. Chemical Engineering Journal,2016,284(1):405-411.
[13] TESTOVA N V,PAUKSHTIS E A,IONE K G. Some peculiarities in synthesis of nitrogen-containing heterocyclic compounds on zeolite catalysts[J]. Reaction Kinetics & Catalysis Letters,1991,44(1):243-249.
[14] QIAN Xiang-hong. Mechanisms and energetics for brønsted acid-catalyzed glucose condensation,dehydration and isomerization reactions[J]. Topics in Catalysis,2012,55(3/4):218-226.
[15] ANTAL M J,LEESOMBOON T,MOK W S,et al. Mechanism of formation of 2-furaldehyde from D-xylose[J]. Carbohydrate Research,1991,217(2):71-85.
[16] ANTAL M J,MOK W S,RICHARDS G N. Mechanism of formation of 5-(hydroxymethyl)-2-furaldehyde from D-fructose and sucrose[J]. Carbohydrate Research,1990,199(1):91-109.
[17] CHHEDA J N,ROMÁN-LESHKOV Y,DUMESIC J A. Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides[J]. Green Chemistry,2007,9(4):342-350.
[18] 周硼. 硫酸衍生固体酸-负载型硫酸及其盐和磺酸树脂催化性能的研究[D]. 大连:大连理工大学博士学位论文,2003.

One-pot Preparation of High Fructose Syrup Directly from Starch over Solid Acid Catalyst

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Haimei LIU,Si ZHAO,Nianjie FENG. Regulation Effect of P Factor on Mass Concentration of Chemical Composition in Prehydrolysis Liquor of Poplar [J]. Biomass Chemical Engineering, 2020, 54(1): 49-54.
[2]	Chenggong XU,Jinlong CUI,Zhiwei CHEN,Guibao GUO. Research Progress on Hemicellulose and Its Reducing Sugar Extraction by Hot-water Prehydrolysis [J]. Biomass Chemical Engineering, 2019, 53(3): 59-66.
[3]	Min DUAN,Tao LIN,Xuefeng YIN,Jing LI. Optimization of Preparation Process of Cellulose Nanocrystals [J]. Biomass Chemical Engineering, 2019, 53(2): 47-53.
[4]	ZHOU Xiaoming, SHENG Jie, LIU Xu, YANG Rendang. Preparation and Characterization of Pea Starch/Polylactic Acid Double Layer Film [J]. bce, 2018, 52(2): 18-22.
[5]	WU Kai, YING Wenjun, ZHENG Zhifeng, SHI Zhengjun, YANG Haiyan, YANG Jing. Effect of Two Kinds of Lignin on Enzymatic Hydrolysis of Cellulose [J]. bce, 2018, 52(2): 29-34.
[6]	YANG Yanping, LUO Yunlong, SHEN Minggui, SHANG Shibin, SONG Zhanqian. Ionic Liquid Modified Magnetic Nanoparticle:An Recyclable Magnetic Catalyst for Cellulose Hydrolysis [J]. bce, 2017, 51(6): 6-10.
[7]	LIU Wenwen, LIANG Long, SHEN Kuizhong, FANG Guigan, TIAN Qingwen. Effects of NaOH/AQ Pretreatment on Delignification and Enzymatic Digestibility of Corn Stover [J]. bce, 2017, 51(4): 39-46.
[8]	LIU Quanzu, YANG Rendang, HUA Feiguo. Effect of Nanocellulose Additives on Oxidation of Potato Starch [J]. bce, 2017, 51(1): 13-19.
[9]	WANG Yan-yun, WU Kai, LEI Fu-hou, YANG Jing. Process Resrarch of Multi-stage Enzymatic Hydrolysis of NaOH-Fenton Pretreated Mulberry Wood [J]. bce, 2016, 50(4): 31-36.
[10]	YANG Shu-juan, YOU Yan-zhi, BU Ling-xi, LI Xiao-li, JIANG Jian-xin. Pretreatment of Waste Paper Pulp and Enzymatic Hydrolysis Properties [J]. bce, 2016, 50(4): 37-41.
[11]	ZHANG Chuan-wei, LI Fang-yi, LIU Peng, WANG Cheng-zhao, LI Jian-feng, GUO An-fu. Preparation and Properties of Thermopalstic Starch Composites Reinforced with Sisal Fiber [J]. bce, 2015, 49(6): 1-5.
[12]	WANG Yan-yun, YANG Jing. Influence of Alkaline-Fenton Pretreatment on the Enzymatic Hydrolysis Yield of Yunnan Bamboo [J]. bce, 2015, 49(5): 17-22.
[13]	ZHANG Wei, ZHANG Qi, RUAN Xin-yi, WANG Xin-ze, KONG Hai-nan, LIN Yan. Optimization of Enzymatic Hydrolysis of Wheat Straw by Using Response Surface Methodology [J]. bce, 2015, 49(2): 39-46,52.
[14]	LI Shou-hai, WANG Chun-peng, YANG Xue-juan, XIA Jian-ling, XU Yu-zhi. Preparation and Structural Properties of Acorn Starch/ Poly (Lactic Acid) Composites [J]. bce, 2015, 49(1): 20-25.
[15]	HUANG Cao-xing, XIE Yi-hui, LI Xin, YONG Qiang, YU Shi-yuan. Effect of Cooking Additives on Moso Bamboo Residues Pretreated by Kraft Pulping with Low Alkali Dosage [J]. bce, 2015, 49(1): 33-38.