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bce ›› 2016, Vol. 50 ›› Issue (5): 39-44.doi: 10.3969/j.issn.1673-5854.2016.05.008

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Pollution Characteristics and Loads in Wastewater of Chemimechanical Pulp of Wheat Straw by Two-stage Impregnated Process

ZHANG Hua-lan1, FANG Gui-gan1,2, SHI Ying-qiao1, SHEN Kui-zhong1,2, RAN Miao1, HAN Shan-ming1, DING Lai-bao1,2, PAN Ai-xiang1,2   

  1. 1. Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab. for Biomass Chemical Utilization;Key and Open Lab. of Forest Chemical Engineering, SFA;Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China;
    2. Research Institute of Forestry New Technology, CAF, Beijing 100091, China
  • Received:2016-01-06 Online:2016-09-30 Published:2016-12-03

Abstract: The pollution characteristics of wastewater from the two-stage impregnated process of wheat straw chemimechanical pulp(CTMP) with different alkali charges were analyzed comprehensively.The relationships of the pulp yield and pollution load were discussed.The results showed that good pulp properties could be obtained at low refining energy consumption with two-stage NaOH impregnation process while the total alkali charges in the whole pulping process were 3%-5% with the pulp yields of 73.1%-78.9%.Meanwhile,the produced wastewater had the chemical oxygen demand(COD) pollution load of 270.5-446.0 kg/t,the five days' biochemical oxygen demand(BOD5) pollution load of 181.3-228.2 kg/t and the suspended solid(SS) pollution load of 47.62-124.30 kg/t. The BOD5/COD ratios of 0.422-0.466 meaned that the wastewater was easy to be treated by the biochemical treatment process.By the suitable ratio of mBOD5:mN:mP of the wastewater,its N and P element were enough to meet the needs of microorganism in the anaerobic-aerobic biochemical treatment.With the increase of the alkali charge,the yield of wheat straw CMP pulps declined,while the corresponding pollution loads increased.The relation formula of the pulping yield(Y) and COD pollution loads(L) was L=5 884-11 670Y+5 800Y2,R2=0.995 with the total alkali charge of 0-8%.

Key words: wheat straw, chemical impregnated, CTMP pulping wastewater, pollution characteristics, pulping yield

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