草酸葑醇酯的合成及其表征

doi:10.3969/j.issn.1673-5854.2016.04.001

bce ›› 2016, Vol. 50 ›› Issue (4): 1-5.doi: 10.3969/j.issn.1673-5854.2016.04.001

Synthesis and Characterization of Fenchyl Oxalate

YUAN Xiao-min¹, ZHAO Zhen-dong^1,2, XU Shi-chao^1,2, LU Yan-ju^1,2, ZHU Shou-ji¹

1. Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab. for Biomass Chemical Utilization;Key and Open Lab. of Forest Chemical Engineering, SFA;Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China;
2. Research Institute of Forestry New Technology, CAF, Beijing 100091, China

Received:2015-12-18 Online:2016-07-31 Published:2016-10-08

Abstract

Abstract: Fenchyl oxalate was synthesized by the reaction of α-fenchyl alcohol and oxalyl chloride.The influences of reaction conditions on the esterification were studied.The optimum conditions of the esterification were the molar ratio of oxalyl chloride and fenchyl alcohol 0.6:1.0, reaction temperature 55℃ and reaction time 10h.Under these conditions, the yield of fenchyl oxalate was 93.9%.After recrystallization, the purity could be 99.9%.And the structure of fenchyl oxalate was characterized by GC-MS, IR, ¹H NMR and ¹³C NMR.

Key words: fenchyl alcohol, oxalyl chloride, fenchyl oxalate, characterization

CLC Number:

TQ351.4

YUAN Xiao-min, ZHAO Zhen-dong, XU Shi-chao, LU Yan-ju, ZHU Shou-ji. Synthesis and Characterization of Fenchyl Oxalate[J]. bce, 2016, 50(4): 1-5.

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Synthesis and Characterization of Fenchyl Oxalate

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