›› 2013, Vol. 47 ›› Issue (5): 19-22.doi: 10.3969/j.issn.1673-5854.2013.05.004
• 研究报告 • Previous Articles Next Articles
XU Rong-sheng
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Abstract: A novel solid super acid with the composition of S2O82-/ZrO2-TiO2 added with Ce4+ was prepared by precipitation and impregnation. Then, the solid super acid was applied to purify longifolene from heavy turpentine oil via a catalytic conversion reaction. The experimental results showed that the catalyst had high catalytic activity for the isomerization reaction. The optimum conditions for the preparation of the catalyst are as follows: concentration of (NH4)2S2O8 1 mol/L and calcination temperature 600 ℃. With the addition of Ce4+, it can slow the components loss and improve the catalytic stability. Ce-S2O82-/ZrO2-TiO2 has the best catalytic activity when the mass fraction of CeO2 is 2%. The optimum conditions for the conversion of heavy turpentine are as follows: ratio of solid super acid to heavy turpentine in mass 3.5%, conversion temperature 150 ℃ and reaction time 4 h. The conversion ratio of caryophyllene is 99.1%. And from the product, longifolene was prepared through rectification in purities (GC) of 80%, 85% and 90%, respectively.
Key words: solid super acid, heavy turpentine, catalytic conversion, longifolene
CLC Number:
TQ351
TQ651
XU Rong-sheng. Study on Preparing Longifolene from Heavy Turpentine Catalyzed by a New Type of Solid Super Acid[J]. , 2013, 47(5): 19-22.
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URL: http://www.bce.ac.cn/EN/10.3969/j.issn.1673-5854.2013.05.004
http://www.bce.ac.cn/EN/Y2013/V47/I5/19