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生物质化学工程 ›› 2018, Vol. 52 ›› Issue (5): 55-61.doi: 10.3969/j.issn.1673-5854.2018.05.010

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生物质热解制生物油及其提质研究现状

牛淼淼, 杨佳耀, 李尚, 孙可, 曹坚, 李欣阳   

  1. 南京工程学院 能源与动力工程学院, 江苏 南京 211167
  • 收稿日期:2017-05-26 出版日期:2018-09-30 发布日期:2018-10-15
  • 通讯作者: 杨佳耀,研究方向:热工自动化;E-mail:3387695590@qq.com。 E-mail:3387695590@qq.com
  • 作者简介:牛淼淼(1988-),女,山东济宁人,讲师,博士,研究方向:固体废弃物的高值化能源转化利用;E-mail:niumiao8899@163.com
  • 基金资助:
    国家国际科技合作专项项目(2014DFE0150);江苏省大学生创新训练计划项目(201611276047X);南京工程学院引进人才科研启动基金(YKJ201609)

Review on Biomass Pyrolysis for Bio-oil and Upgrading Research

NIU Miaomiao, YANG Jiayao, LI Shang, SUN Ke, CAO Jian, LI Xinyang   

  1. School of Energy and Power Engineering, Nanjing Institute of Technology, Nanjing 211167, China
  • Received:2017-05-26 Online:2018-09-30 Published:2018-10-15

摘要: 生物质能源作为可再生能源的重要组成部分,其综合高效利用在能源替代与补充、保护生态环境等方面具有重要的战略意义。生物油是生物质通过热裂解技术获得的液体产物,具有能量密度较高、环境友好、可再生及可直接输送等优点,可替代传统化石燃料推广使用,解决日益严重的能源紧缺与环境污染等问题。生物质热解制油技术的开发与利用,已成为新世纪可持续能源研究领域的重要课题之一。总结了近年来生物质热解制油技术的主要研究进展,重点关注热解反应器、催化热解技术与生物油的提质利用方面的研究,介绍了碱金属、氧化物和分子筛3种生物质热解催化剂,以及乳化、催化加氢、催化裂解、催化酯化和重整制氢5种生物质提质方法,最后对生物质热解技术的现状及发展趋势进行了总结和概括。

关键词: 生物质, 生物油, 热解, 反应器, 提质, 催化

Abstract: As an important part of renewable energy, biomass energy shows strategic importance in the substitution and supplementation of energy and protection of environment. Biomass pyrolysis oil is the liquid product obtained by biomass pyrolysis and has the advantages of high energy density, environmental friendliness, renewable utilization and convenient transportation, making it possible for replacing fossil fuels and solving energy shortage and environmental pollution. The development and utilization of biomass pyrolysis oil technology has become one of the most important topics of sustainable energy research in this century. In this study, the main research of biomass pyrolysis oil production in recent years were reviewed, focusing on the improvement of pyrolysis reactor, catalytic pyrolysis and the upgrading of bio-oil. Three kinds of biomass pyrolysis catalysts including alkali metal, oxide and molecular sieve were introduced and five kinds of biomass upgrading methods including emulsification,catalytic hydrogenation,catalytic cracking,catalytic esterification and reforming hydrogen production were presented.The current status and development trend of biomass pyrolysis technology were summarized.

Key words: biomass, bio-oil, pyrolysis, reactor, upgrading, catalyze

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